propineb
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Names
[ CAS No. ]:
12071-83-9
[ Name ]:
propineb
[Synonym ]:
[[(1-Methyl-1,2-ethanediyl)bis[carbamodithioato]](2-)]zinc
[Propylenebis(dithiocarbamato)]zinc
ZINC TRIFLUOROACETATE
trifluoro-acetic acid,zinc-trifluoroacetate
EINECS 235-134-0
Zinc 1,2-propanediyldicarbamodithioate
Zinc propane-1,2-diyldicarbamodithioate
Carbamodithioic acid, N,N'-(1-methyl-1,2-ethanediyl)bis-, zinc salt (1:1)
MFCD00055491
zinc rifluoroacetate
zinc,N-[1-(sulfidocarbothioylamino)propan-2-yl]carbamodithioate
Chemical & Physical Properties
[ Boiling Point ]:
315.4ºC at 760 mmHg
[ Melting Point ]:
160ºC
[ Molecular Formula ]:
C5H8N2S4Zn
[ Molecular Weight ]:
289.77
[ Flash Point ]:
144.5ºC
[ Exact Mass ]:
287.886169
[ PSA ]:
165.84000
[ LogP ]:
1.76530
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- ZH4950000
- CHEMICAL NAME :
- Zinc, (N,N'-propylene-1,2-bis(dithiocarbamate))
- CAS REGISTRY NUMBER :
- 12071-83-9
- LAST UPDATED :
- 199409
- DATA ITEMS CITED :
- 12
- WISWESSER LINE NOTATION :
- SUYS&MY1&1MYS&US &ZN-
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 8500 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LC50 - Lethal concentration, 50 percent kill
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- >693 mg/m3/4H
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- >1 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rabbit
- DOSE/DURATION :
- 2500 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Unreported
- SPECIES OBSERVED :
- Bird - quail
- DOSE/DURATION :
- >5 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- DOSE :
- 2300 mg/kg
- SEX/DURATION :
- female 11 day(s) after conception
- TOXIC EFFECTS :
- Reproductive - Fertility - post-implantation mortality (e.g. dead and/or resorbed implants per total number of implants) Reproductive - Specific Developmental Abnormalities - eye/ear Reproductive - Specific Developmental Abnormalities - craniofacial (including nose and tongue)
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- DOSE :
- 2300 mg/kg
- SEX/DURATION :
- female 11 day(s) after conception
- TOXIC EFFECTS :
- Reproductive - Specific Developmental Abnormalities - musculoskeletal system Reproductive - Specific Developmental Abnormalities - homeostasis
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- DOSE :
- 1 gm/kg
- SEX/DURATION :
- female 6-15 day(s) after conception
- TOXIC EFFECTS :
- Reproductive - Specific Developmental Abnormalities - other developmental abnormalities
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- DOSE :
- 2 gm/kg
- SEX/DURATION :
- female 6-15 day(s) after conception
- TOXIC EFFECTS :
- Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death, e.g., stunted fetus)
MUTATION DATA
- TEST SYSTEM :
- Rodent - rat
- DOSE/DURATION :
- 2600 mg/kg/5D (Intermittent)
- REFERENCE :
- PRKHDK Problemi na Khigienata. Problems in Hygiene. (Durzhavno Izdatel'stvo Meditsina i Fizkultura, Pl. Slaveikov 11, Sofia, Bulgaria) V.1- 1975- Volume(issue)/page/year: 4,151,1979
Safety Information
[ Personal Protective Equipment ]:
Eyeshields;Faceshields;Gloves
[ Hazard Codes ]:
N: Dangerous for the environment;
[ Risk Phrases ]:
51/53
[ Safety Phrases ]:
60-61
[ RIDADR ]:
UN3077 9/PG 3
[ RTECS ]:
ZH4950000
[ Packaging Group ]:
III
[ HS Code ]:
2930200012
Customs
[ HS Code ]: 2930200012
[ Summary ]:
2930200012 iron(iii) dimethylcarbamodithioate。supervision conditions:s(import or export registration certificate for pesticides)。VAT:17.0%。tax rebate rate:9.0%。MFN tarrif:6.5%。general tariff:30.0%
Articles
Boll. Soc. Ital. Biol. Sper. 61(2) , 271-8, (1985)
The teratogenic and goitrogenic effects of Propineb, dithiocarbamate pesticide and Propylenthiourea (PLTU), its metabolite and degradation product have been studied. The aim of this study was to show ...
Mutat. Res. 135(3) , 193-7, (1984)
The possible clastogenic activity of Propineb, Propineb technical grade and of its main metabolite, propylene-thiourea (PLTU), was investigated by the micronucleus test in mice according to Schmid. No...
Chemosphere 68(11) , 2104-10, (2007)
A simple, rapid and sensitive GC-MS method for the determination of dithiocarbamate fungicide propineb [polymeric zinc propylenebis (dithiocarbamate)] and an improved HPLC procedure for the simultaneo...