Iron, dicarbonyl(h5-2,4-cyclopentadien-1-yl)iodo-

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Names

[ CAS No. ]:
12078-28-3

[ Name ]:
Iron, dicarbonyl(h5-2,4-cyclopentadien-1-yl)iodo-

[Synonym ]:
dicarbonylcyclopentadienyliodoiron(ii)
MFCD00001437
Iron,dicarbonyleta5-2,4-cyclopentadien-1-yl)iodo
DICARBONYLCYCLOPENTADIENYLIODOIRON
Cyclopentadienyldicarbonylironiodide
cyclopentadienyl-irondicarbonyliodide

Chemical & Physical Properties

[ Melting Point ]:
119-120ºC (dec.)

[ Molecular Formula ]:
C7H5FeIO2

[ Molecular Weight ]:
303.86300

[ Exact Mass ]:
303.86800

[ LogP ]:
1.48870

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
NO6250000
CHEMICAL NAME :
Iron, dicarbonyl-pi-cyclopentadienyl-, iodide
CAS REGISTRY NUMBER :
12078-28-3
LAST UPDATED :
199012
DATA ITEMS CITED :
1
MOLECULAR FORMULA :
C7-H5-Fe-O2.I
MOLECULAR WEIGHT :
303.87
WISWESSER LINE NOTATION :
L50J 0-FE-CO&CO &I &8/18

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
630 ug/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#11289

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302 + H312 + H332

[ Precautionary Statements ]:
P280

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn: Harmful;

[ Risk Phrases ]:
20/21/22

[ Safety Phrases ]:
36

[ RIDADR ]:
UN 2811

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1(b)

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Cyclopentadienyliron dicarbonyl dimer
  • molecular iodine
  • Sodium iodide
  • 1,4-C6H4(CO(η5-C5H5)Fe(CO)2)2
  • (η(5)-C5H5)Fe(CO)2C6H4Fe(CO)2(η(5)-C5H5)
  • Fp(acetonitrile)(tetrafluoroborate)
  • Tetrabutylammonium iodide
  • dicarbonyl(η5-cyclopentadienyl)(η2-1,2-cycloheptadiene)iron triflate

DownStream

  • Iron,dicarbonyl(4-chlorobenzenethiolato)(h5-2,4-cyclopentadien-1-yl)- (9CI)
  • Iron, dicarbonyl(h5-2,4-cyclopentadien-1-yl)[4-(trifluoromethyl)benzenethiolato-kS]
  • Indium
  • 2,5-bis[dicarbonyl(η5-cyclopentadienyl)(σ1-ethynyl)iron(II)]thiophene
  • Tributyl(iodo)stannane
  • carbon monoxide,cyclopenta-1,3-diene,iron(6+),methoxybenzene
  • Iron, dicarbonylchloro(h5-2,4-cyclopentadien-1-yl)-
  • FERROCENE
  • (η5-1-(CO2C2H5)-2-methyl-4-t-butylcyclopentadienyl)dicarbonylruthenium(II) iodide

Related Compounds

  • Iron, dicarbonyl(h5-2,4-cyclopentadien-1-yl)(2,3,3,4,4,5,5,6,6-nonafluoro-1-cyclohexen-1-yl)-
  • Iron, dicarbonyl(h5-2,4-cyclopentadien-1-yl)[4-(trifluoromethyl)benzenethiolato-kS]
  • Iron, dicarbonyl(h5-2,4-cyclopentadien-1-yl)(4-nitrobenzenethiolato-S)-(9CI)
  • Iron,dicarbonyl(h5-2,4-cyclopentadien-1-yl)(2,3,6-trifluorophenyl)-
  • Iron, dicarbonyl(h5-2,4-cyclopentadien-1-yl)(2,3,5,6-tetrafluorophenyl)-
  • Iron, dicarbonyl(h5-2,4-cyclopentadien-1-yl)(trichlorostannyl)-(9CI)