(TOLUENE)TRICARBONYLCHROMIUM

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Names

[ CAS No. ]:
12083-24-8

[ Name ]:
(TOLUENE)TRICARBONYLCHROMIUM

[Synonym ]:
EINECS 235-148-7
(Toluene)tricarbonylchromium(0)
toluene chromium tricarbonyl complex
MFCD00010583
(Toluene)tricarbonylchromium

Chemical & Physical Properties

[ Melting Point ]:
78-82ºC(lit.)

[ Molecular Formula ]:
C10H8CrO3

[ Molecular Weight ]:
228.16500

[ Flash Point ]:
170 °F

[ Exact Mass ]:
227.98800

[ LogP ]:
1.37100

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
GB7370000
CHEMICAL NAME :
Chromium, tricarbonyl(toluene)-
CAS REGISTRY NUMBER :
12083-24-8
LAST UPDATED :
198712
DATA ITEMS CITED :
1
MOLECULAR FORMULA :
C10-H8-Cr-O3
MOLECULAR WEIGHT :
228.18

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
5620 ug/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1285,1986

Safety Information

[ Hazard Codes ]:
F: Flammable;Xn: Harmful;

[ Risk Phrases ]:
11-20/21/22

[ Safety Phrases ]:
16-36

[ RIDADR ]:
UN 1325 4.1/PG 2

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Toluene
  • (η6-C6H6)Cr(CO)3
  • bis(η6-benzene)chromium
  • (η6-1-fluoro-4-methylbenzene)tricarbonylchromium(0)
  • Lithium triethylborohydride
  • Lithium Aluminium Hydride
  • bis(benzylchromiumtricarbonyl)mercury
  • 4-Tolylboronic acid

DownStream

  • HEXAPHENYLBENZENE
  • 4'-Methylacetophenone
  • 2-Methylacetophenone
  • 3'-Methylacetophenone
  • chromium
  • Toluene
  • 4-(4-aminophenyl)aniline
  • carbon monoxide,chromium,1,3,5-trimethylbenzene
  • (ANISOLE)TRICARBONYLCHROMIUM

Related Compounds

  • toluene-4-sulfonic acid-((1S)-1,3,3-trimethyl-[2endo]norbornyl ester)
  • toluene-4-sulfonic acid 4-tert-butylcyclohex-1-en-1-yl ester
  • toluene-4-sulfonic acid-(4-chloro-2-nitro-phenyl ester)
  • toluene-4-sulfonic acid-[N-(2-diethylamino-ethyl)-p-anisidide]
  • Toluene-4-sulfonic acid (4R,5S)-2,2-dimethyl-5-vinyl-[1,3]dioxolan-4-ylmethyl ester
  • Toluene-4-sulfonic acid (E)-2,2-difluoro-1-phenyl-pent-3-enyl ester