(1,5-Cyclooctadiene)rhodium chloride dimer

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Names

[ CAS No. ]:
12092-47-6

[ Name ]:
(1,5-Cyclooctadiene)rhodium chloride dimer

[Synonym ]:
Bis(1,5-cyclooctadiene)dirhodium(I) Dichloride
(1Z,5Z)-cycloocta-1,5-diene,rhodium,dichloride
(1,5-Cyclooctadiene)rhodium chloride dimer
MFCD00012415
1,5-Cyclooctadiene - chlororhodium (1:1)
1,5-Cyclooctadiene Rhodium(I) Chloride Dimer
EINECS 235-157-6
Chloro(1,5-Cyclooctadiene)Rhodium(I) Dimer
(1Z,5Z)-Cycloocta-1,5-diene - chlororhodium (1:1)
Chloro(1,5-cyclooctadiene)rhodium(I)dimer

Chemical & Physical Properties

[ Boiling Point ]:
153.5ºC at 760mmHg

[ Melting Point ]:
255ºC (dec.)

[ Molecular Formula ]:
C₁₆H₂₄Cl₂Rh₂

[ Molecular Weight ]:
493.079

[ Flash Point ]:
31.7ºC

[ Exact Mass ]:
491.936523

[ Storage condition ]:
2-8°C

[ Stability ]:
hygroscopic

[ Water Solubility ]:
Soluble in chloroform, dichloromethane, and methanol. Sparingly soluble in most common solvents.

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

(2Z,6E,10E)-1-bromo-3,7,11,15-tetramethylhexadeca-2,6,10,14-tetraene
Dichloro(1,5-cyclooctadiene)palladium(II)
rhodium{C6H3(CH2NMe2)2-o,o'}(1,5-cyclooctadiene)
Silver hexafluorophosphate
Gold(1+) chloride-triphenylphosphine (1:1:1)
cis-[PdCl2(CN(t-Bu))2]
Rh2(1,5-cyclooctadiene)2(p-tolyl-formamidinate)2
bis(3,5-dimethylpyrazol-1-yl)(phenyl)methane

DownStream

(1Z,5Z)-cycloocta-1,5-diene,dichlororhodium(1-),rhodium,N,N,N',N'-tetramethylethane-1,2-diamine
BIS(ACETONITRILE)(1,5-CYCLOOCTADIENE) RHODIUM(1) TETRAFLUOROBORATE
2,2'-[1,2-Phenylenebis(oxy)]bis(1,3,2-benzodioxaborole)
Borane-triphenylphosphine (1:1)
cycloocta-1,5-diene; quinolin-8-ol; rhodium
orange crystal
Wilkinson's catalyst
Rhodium, [bis[3- (diphenylphosphino)propyl]phenylphosphine-P,P, P]chloro-, (SP-4-3)-
Chlorotrimethylsilane

Articles

The use of a [4 + 2] cycloaddition reaction for the preparation of a series of 'tethered' Ru(II)-diamine and aminoalcohol complexes.

Org. Biomol. Chem. 5 , 1093, (2007)

A series of catalysts have been prepared for use in the asymmetric transfer hydrogenation of ketones. The complexes were prepared using a [4 + 2] cycloaddition reaction at a key step in the reaction s...

Pure Appl. Chem. 66 , 1509, (1994)

Tetrahedron Asymmetry 4 , 2279, (1993)

Rhodium,chloro[(1,2,5,6-h)-1,5-cyclooctadiene](piperidine)-
Rhodium(1+), (2,2-bipyridine-N,N)((1,2,5,6-eta)-1,5-cyclooctadiene)-, chloride
(Acetylacetonato)(1,5-cyclooctadiene)rhodium(I)
bis(1,5-cyclooctadiene)rhodium trifluoromethanesulfonate
Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
Bis(1,5-cyclooctadiene)rhodium(I) hexafluoroantimonate