Ferrocenecarboxaldehyde

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Names

[ CAS No. ]:
12093-10-6

[ Name ]:
Ferrocenecarboxaldehyde

[Synonym ]:
FORMYLFERROCENE
MFCD00001429
Ferrocene,formyl
1-carboxaldehyde-ferrocene
formyl-ferrocen
FERROCENECARBALDEHYDE
FERROCENEALDEHYDE
Cyclopentadienyl(formylcyclopentadienyl)iron
Ferrocene Carboxyaldehyde
Iron(2+) 2,4-cyclopentadienide 2-formyl-2,4-cyclopentadienide (1:1:1)
ferrocene monocarbaldehyde
Ferrocene carboxaldehyde
EINECS 235-158-1
Ferrocenecarboxaldeh
ferrocene monocarboxaldehyde
ferrocene-2-carboxaldehyde

Chemical & Physical Properties

[ Density]:
1.149g/cm3

[ Boiling Point ]:
213.6ºC at 760 mmHg

[ Melting Point ]:
118-120 °C(lit.)

[ Molecular Formula ]:
C11H10FeO

[ Molecular Weight ]:
214.042

[ Flash Point ]:
98.8ºC

[ Exact Mass ]:
214.008102

[ PSA ]:
17.07000

[ LogP ]:
1.60960

[ Vapour Pressure ]:
5.03mmHg at 25°C

[ Index of Refraction ]:
1.623

[ Stability ]:
Stable. Incompatible with strong oxidizing agents.

MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
T

[ Risk Phrases ]:
R45:May cause cancer. R23/24/25:Toxic by inhalation, in contact with skin and if swallowed . R34:Causes burns. R42/43:May cause sensitization by inhalation and skin contact .

[ Safety Phrases ]:
22-24/25

[ RIDADR ]:
UN 3262 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
6.1

[ HS Code ]:
2912299000

Synthetic Route

Precursor & DownStream

Precursor

  • FERROCENE
  • N,N-Dimethylformamide
  • Ferrocenemethanol
  • Triethyl orthoformate
  • N-METHYLACETANILIDE
  • N-Methylformanilide
  • Dichloromethane
  • formyl chloride
  • N,N-Dimethylaminomethylferrocene

DownStream

  • Acetylferrocene
  • Ferrocenemethanol
  • 2-(ferrocenylmethyl)amino-2-methyl-propan-1-ol
  • Benzoylferrocene
  • N,N-Dimethylaminomethylferrocene
  • Vinylferrocene
  • 1-Ferrocenylethanol
  • (2α)-Ethynylferrocene
  • ferrocenecarboxylic acid
  • cyclopenta-1,3-diene; 3-(1-cyclopenta-1,4-dienyl)-1-phenyl-prop-2-en-1-one; iron(+2) cation

Customs

[ HS Code ]: 2912299000

[ Summary ]:
2912299000. other cyclic aldehydes without other oxygen function. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

Articles

Photocytotoxic oxovanadium(IV) complexes of ferrocenyl-terpyridine and acetylacetonate derivatives.

Eur. J. Med. Chem. 92 , 332-41, (2015)

Oxovanadium(IV) complexes [VO(Fc-tpy)(acac)](ClO4) (1), [VO(Fc-tpy)(nap-acac)](ClO4) (2), [VO(Fc-tpy)(py-acac)](ClO4) (3) and [VO(Ph-tpy)(py-acac)](ClO4) (4) of 4'-ferrocenyl-2,2':6',2"-terpyridine (F...

Interaction of ferrocene appended Ru(II), Rh(III) and Ir(III) dipyrrinato complexes with DNA/protein, molecular docking and antitumor activity.

Eur. J. Med. Chem. 84 , 17-29, (2014)

Efficacy of the ferrocene appended piano-stool dipyrrinato complexes [(η(6)-C6H6)RuCl(fcdpm)] (1), [(η(6)-C10H14)RuCl(fcdpm)] (2), [(η(6)-C12H18)RuCl(fcdpm)] (3) [(η(5)-C5Me5)RhCl(fcdpm)] (4) and [(η(...

A carbon nanotube/poly [Ni-(Protoporphyrin IX)] composite for amperometric detection of long chain aliphatic amines.

Bioelectrochemistry 104 , 51-7, (2015)

Poly [Ni-Protoporphyrin] film (pNiPP), containing multiwall carbon nanotubes (MWCNT) was used to cover a glassy carbon electrode. The hybrid material (pNiPP/MWCNT) successfully combines the permselect...


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