Horner-Emmons reagent

Names

[ CAS No. ]:
120943-70-6

[ Name ]:
Horner-Emmons reagent

[Synonym ]:
.dimethyl [2-(tert-butyldimethylsilyl)-2-oxoethyl]-phosphonate
.(MeO)2P(O)CH2COTBS
dimethyl <2-(tert-butyldimethylsilyl)-2-oxoethyl>-phosphonate
.dimethyl 2-(tert-butyldimethylsilyl)-2-oxoethylphosphonate

Chemical & Physical Properties

[ Molecular Formula ]:
C10H23O4PSi

[ Molecular Weight ]:
266.34600

[ Exact Mass ]:
266.11000

[ PSA ]:
62.41000

[ LogP ]:
3.08910

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 2-bromo-1-tert-butyldimethylsilyl-1-ethanone

DownStream

  • 1-[tert-butyl(dimethyl)silyl]-4,4-dimethylpent-2-en-1-one
  • 1-[tert-butyl(dimethyl)silyl]-4-methylpent-2-en-1-one

Related Compounds

  • slap hydropyridopyrazine reagent
  • ZINC ISOPROPYLSULFINATE
  • p-Dioxane, Reagent
  • bolton-hunter reagent, [125i]
  • Denny-Jaffe reagent
  • DOTAP Transfection Reagent
  • Tert-butyl 2-(3-amino-3-methylbutyl)-5,5-dimethylpiperidine-1-carboxylate
  • tert-butyl N-[3-(3-aminopropyl)-4-methoxyphenyl]carbamate
  • Tert-butyl 2-(2,4,5-trimethylphenyl)piperazine-1-carboxylate
  • Tert-butyl 3-[2-(dimethylamino)-5-fluorophenyl]piperazine-1-carboxylate
  • 2-(Butan-2-yl)-3-[(tert-butoxy)carbonyl]-1,3-thiazolidine-4-carboxylic acid
  • 6-[(tert-butoxy)carbonyl]-7-methyl-4H,5H,6H,7H-thieno[2,3-c]pyridine-7-carboxylic acid
  • 4-Bromo-5-{[(tert-butoxy)carbonyl]amino}thiophene-2-carboxylic acid
  • 2-(3-{[(Benzyloxy)carbonyl]amino}cyclobutyl)acetic acid
  • tert-butyl (2S)-2-amino-3-[4-(dimethylamino)phenyl]propanoate
  • 3-{[(9H-fluoren-9-yl)methoxy]carbonyl}-3-azabicyclo[3.2.0]heptane-6-carboxylic acid
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