Horner-Emmons reagent

Names

[ CAS No. ]:
120943-70-6

[ Name ]:
Horner-Emmons reagent

[Synonym ]:
.dimethyl [2-(tert-butyldimethylsilyl)-2-oxoethyl]-phosphonate
.(MeO)2P(O)CH2COTBS
dimethyl <2-(tert-butyldimethylsilyl)-2-oxoethyl>-phosphonate
.dimethyl 2-(tert-butyldimethylsilyl)-2-oxoethylphosphonate

Chemical & Physical Properties

[ Molecular Formula ]:
C10H23O4PSi

[ Molecular Weight ]:
266.34600

[ Exact Mass ]:
266.11000

[ PSA ]:
62.41000

[ LogP ]:
3.08910

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 2-bromo-1-tert-butyldimethylsilyl-1-ethanone

DownStream

  • 1-[tert-butyl(dimethyl)silyl]-4,4-dimethylpent-2-en-1-one
  • 1-[tert-butyl(dimethyl)silyl]-4-methylpent-2-en-1-one

Related Compounds

  • slap hydropyridopyrazine reagent
  • ZINC ISOPROPYLSULFINATE
  • p-Dioxane, Reagent
  • bolton-hunter reagent, [125i]
  • Denny-Jaffe reagent
  • DOTAP Transfection Reagent
  • Tert-butyl 2-(3-bromo-2,2-dimethylpropyl)pyrrolidine-1-carboxylate
  • 4-(2-Bromoethyl)-5-methyl-1,2-oxazole
  • 3-(3-Bromoprop-1-en-2-yl)-1,2-oxazole
  • 5-(1-bromopropan-2-yl)-3,4-dihydro-2H-pyran
  • tert-butyl N-[1-(2-bromopropyl)cyclohexyl]carbamate
  • 2-(2-bromoethyl)-5-chloro-1H-indole
  • 3-(1-Bromo-2-methylpropan-2-yl)-4-(trifluoromethyl)pyridine
  • 5-chloro-4-(3-chloroprop-1-en-2-yl)-1-methyl-3-(trifluoromethyl)-1H-pyrazole
  • 3-(1-Bromopropan-2-yl)-4-(trifluoromethyl)pyridine
  • Methyl 6-(3-bromo-2,2-dimethylpropyl)pyridine-3-carboxylate
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