dichlorobis(indenyl)titanium(iv)

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Names

[ CAS No. ]:
12113-02-9

[ Name ]:
dichlorobis(indenyl)titanium(iv)

[Synonym ]:
MFCD00799514
Bisindenyltitanium dichloride
bis(indenyl)titanium dichloride
dichlorobis(indenyl)titanium

Chemical & Physical Properties

[ Boiling Point ]:
298.6ºC at 760mmHg

[ Melting Point ]:
190-200ºC(lit.)

[ Molecular Formula ]:
C18H14Cl2Ti

[ Molecular Weight ]:
349.07700

[ Flash Point ]:
96.6ºC

[ Exact Mass ]:
347.99500

[ LogP ]:
5.15480

[ Vapour Pressure ]:
1.15mmHg at 25°C

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
XR2056000
CHEMICAL NAME :
Titanium, dichlorodi-pi-indenyl-
CAS REGISTRY NUMBER :
12113-02-9
LAST UPDATED :
198111
DATA ITEMS CITED :
1
MOLECULAR FORMULA :
C18-H22-Cl2-Ti
MOLECULAR WEIGHT :
357.20
WISWESSER LINE NOTATION :
L560&J 0-TI-GG- 0L560&J

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Unreported
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
360 mg/kg
TOXIC EFFECTS :
Tumorigenic - active as anti-cancer agent
REFERENCE :
EJMCA5 European Journal of Medicinal Chemistry--Chimie Therapeutique. (Editions Scientifiques Elsevier, 29 rue Buffon, F-75005, Paris, France) V.9- 1974- Volume(issue)/page/year: 16,275,1981

Safety Information

[ Hazard Codes ]:
C: Corrosive;

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S26-S27-S36/37/39-S45

[ RIDADR ]:
UN 3261

[ HS Code ]:
2903999090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Titanium tetrachloride
  • Indene
  • indenyl thallium(I)

DownStream

Customs

[ HS Code ]: 2903999090

[ Summary ]:
2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Related Compounds

  • ethylenebis(1-indenyl)titanium(iv) dichloride
  • Trichloro(1H-inden-1-yl)titanium
  • meso-dichloroethylenebis-(4,5,6,7-tetrahydro-1-indenyl)-titanium(iv)
  • (r,r)-ethylenebis-(4,5,6,7-tetrahydro-1-indenyl)-titanium(iv)-(r)-(1,1'-binaphthyl-2)
  • (r,r)-ethylenebis-(4,5,6,7-tetrahydro-1-indenyl)-titanium(iv)-(r)-(1,1'-binaphthyl-2)
  • dichloro[rac-ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]titanium(iv)
  • methyl 3-({[1-ethyl-6-(4-fluorobenzyl)-3-methyl-5,7-dioxo-1,5,6,7-tetrahydro-4H-pyrazolo[4,3-d]pyrimidin-4-yl]acetyl}amino)thiophene-2-carboxylate
  • 1-(3-chloro-4-methoxybenzenesulfonyl)-4-methyl-1H-imidazole
  • 2-(5-Bromo-6-methoxynaphthalen-2-yl)acetic acid
  • 5-(4-(1-Morpholinoethyl)phenyl)benzo[d]thiazol-2-amine
  • (2-Methoxy-2-methylpropyl)(methyl)amine
  • (5-Bromo-2-(2-methylpyrrolidin-1-YL)phenyl)methanol
  • 2-(1-Aminocyclohex-2-en-1-yl)acetic acid
  • 1,3-Dioxoisoindolin-2-YL propiolate
  • 4-Methyl-5-nitrobenzo[b]thiophene
  • 1-(Tert-butylcarbamoyl)prop-1-en-2-yl 3,5-diamino-6-chloropyrazine-2-carboxylate