Ammonium sulfide

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Names

[ CAS No. ]:
12135-76-1

[ Name ]:
Ammonium sulfide

[Synonym ]:
Ammonium bisulfide
Ammoniumsulfid
AMMONIUM SULPHIDE
Ammonium Sulfide
trueammoniumsulfide
EINECS 235-223-4
FEMA 2053
NH4HS
diammoniumsulfide
ammonium sulfude
ammonium monosulfide
MFCD00010892

Chemical & Physical Properties

[ Density]:
1 g/mL at 25 °C

[ Boiling Point ]:
40 °C

[ Melting Point ]:
-18ºC

[ Molecular Formula ]:
H8N2S

[ Molecular Weight ]:
68.14190

[ Flash Point ]:
90 °F

[ Exact Mass ]:
68.04080

[ PSA ]:
31.78000

[ LogP ]:
0.76060

[ Index of Refraction ]:
n20/D 1.467

[ Stability ]:
Stable. Pure material is highly flammable - note wide explosion limits. Incompatible with strong oxidizing agents, strong acids, copper, brass, bronze, strong bases, zinc, aluminium.

MSDS

Safety Information

[ Symbol ]:

GHS02, GHS05, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H226-H314-H400

[ Supplemental HS ]:
Contact with acids liberates toxic gas.

[ Precautionary Statements ]:
P210-P260-P280-P303 + P361 + P353-P305 + P351 + P338-P370 + P378

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F:Flammable;C:Corrosive;N:Dangerousfortheenvironment;

[ Risk Phrases ]:
R11;R31;R34;R50

[ Safety Phrases ]:
S26-S36/37/39-S45-S61

[ RIDADR ]:
UN 2683 8/PG 2

[ WGK Germany ]:
-

[ Packaging Group ]:
II

[ Hazard Class ]:
8

[ HS Code ]:
2830909000

Synthetic Route

Precursor & DownStream

Precursor

  • hydrogen sulfide
  • Ammonia
  • AMMONIUM THIOCARBAMATE
  • Sulfur

DownStream

  • Sodium thiocyanate
  • sodium carbonate
  • Ethanedioic acid diammoniate hydrate
  • SodiuM bicarbonate
  • Indium sulfide (2:3)
  • hydrogen sulfide
  • Ammonium Bicarbonate

Customs

[ HS Code ]: 2830909000

Articles

Characterization of volatile compounds from the reaction of 3-hydroxy-2-butanone and ammonium sulfide model system.

J. Agric. Food Chem. 47(1) , 245-8, (1999)

The reactions between 3-hydroxy-2-butanone and ammoniun sulfide at 25, 50, 75, 100, 125, and 150 degrees C were studied. Four well-known flavor compounds, 2,4,5-trimethyloxazole, 2,4, 5-trimethyl-3-ox...

A cataluminescence gas sensor for ammonium sulfide based on Fe(3)O(4)-carbon nanotubes composite.

Luminescence 25(4) , 294-9, (2010)

In the present work, Fe(3)O(4)-carbon nanotubes (CNTs) composite was explored as a sensing material candidate for ammonium sulfide. Intense chemiluminescence emission can be observed during the cataly...

Visualization of iron in cultured macrophages: a cytochemical light and electron microscopic study using autometallography.

Free Radic. Biol. Med. 15(1) , 1-11, (1993)

The objective of this study was to develop a sensitive cytochemical method for the visualization of iron, both at light microscopical (LM) and at electron microscopical (EM) levels, in glutaraldehyde-...


More Articles


Related Compounds

  • ammonium sulfide
  • Monoammonium sulfide
  • Ammonium sulfide ((NH4)2(S3))
  • Ammonium sulfide amide phosphate
  • Potassium ammonium sulfide mixed with ammonium potassium selenide
  • ammonium o-cresolate
  • N-(1-cyano-1,2-dimethylpropyl)-2-(2-methyl-3-nitrophenoxy)acetamide
  • N-(6-bromobenzo[d]thiazol-2-yl)-2-(4-fluorophenoxy)-N-(pyridin-2-ylmethyl)acetamide
  • N-(1-cyano-1-cyclopropylethyl)-2-(2-methyl-3-nitrophenoxy)acetamide
  • N-(1-cyanocyclopentyl)-2-(2-methyl-3-nitrophenoxy)acetamide
  • N-(4-fluorobenzo[d]thiazol-2-yl)-2-(4-fluorophenoxy)-N-(pyridin-2-ylmethyl)acetamide
  • N-(cyanomethyl)-2-(2-methyl-3-nitrophenoxy)-N-phenylacetamide
  • N-(7-chloro-4-methoxybenzo[d]thiazol-2-yl)-3,3-diphenyl-N-(pyridin-2-ylmethyl)propanamide
  • N-(1-cyano-1-cyclopropylethyl)-2-{[4-(1-phenylethyl)-4H-1,2,4-triazol-3-yl]sulfanyl}acetamide
  • 2,4-difluoro-N-(4-methoxy-1,3-benzothiazol-2-yl)-N-[(pyridin-2-yl)methyl]benzamide
  • 2-(5,6,7,8-Tetrahydronaphthalen-2-yl)butanoic acid
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