Di-μ-Methoxobis(1,5-cyclooctadiene)diiridiuM(I)

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Names

[ CAS No. ]:
12148-71-9

[ Name ]:
Di-μ-Methoxobis(1,5-cyclooctadiene)diiridiuM(I)

[Synonym ]:
Di-μ-methanolatodiiridium - (1Z,5Z)-1,5-cyclooctadiene (1:2)
MFCD08459360
Iridium, di-μ-methanolato-, compd. with (1Z,5Z)-1,5-cyclooctadiene (1:2)
Bis(1,5-cyclooctadiene)dimethoxydiiridium
(1,5-Cyclooctadiene)(Methoxy)iridiuM(I) DiMer
Bis(1,5-cyclooctadiene)di-μ-methoxydiiridium(I)
Di-μ-Methoxobis(1,5-cyclooctadiene)diiridiuM(I)

Chemical & Physical Properties

[ Melting Point ]:
154-177ºC

[ Molecular Formula ]:
C18H30Ir2O2

[ Molecular Weight ]:
662.864

[ Exact Mass ]:
664.150391

[ PSA ]:
34.14000

[ LogP ]:
5.53980

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P280-P304 + P340 + P312-P305 + P351 + P338-P337 + P313

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26

[ RIDADR ]:
NONH for all modes of transport

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Chloroiridium-cycloocta-1,5-diene (1:1)
  • Sodium Methylate

DownStream

Articles

C-H activation/borylation/oxidation: a one-pot unified route to meta-substituted phenols bearing ortho-/para-directing groups.

J. Am. Chem. Soc. 125 , 7792, (2003)

An efficient one-pot C-H activation/borylation/oxidation protocol for the preparation of phenols is described. This method is particularly attractive for the generation of meta-substituted phenols bea...


More Articles

Related Compounds

  • Di-u-acetatobis-(1,5-cyclooctadiene)-dirhodium
  • di[(cyclooctadiene)(μ-hydroxido)iridium(I)]
  • [Rh(μ-pyrazolate)(1,5-cyclooctadiene)]2
  • Chiralyst P1182
  • [1E,5Z,pR]-1,5-Cyclooctadiene
  • tricarbonyl(η(4)-1,5-cyclooctadiene)ruthenium
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 3-{[(4-Fluorophenyl)(methyl)amino]sulfonyl}thiophene-2-carboxylic acid
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine
  • 4-amino-N-[2-tert-butyl-1-(tetrahydro-2H-pyran-4-ylmethyl)-1H-benzimidazol-5-yl]-N-ethylbenzenesulfonamide