Di-μ-Methoxobis(1,5-cyclooctadiene)diiridiuM(I)

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Names

[ Name ]:
Di-μ-Methoxobis(1,5-cyclooctadiene)diiridiuM(I)

[Synonym ]:
Di-μ-methanolatodiiridium - (1Z,5Z)-1,5-cyclooctadiene (1:2)
MFCD08459360
Iridium, di-μ-methanolato-, compd. with (1Z,5Z)-1,5-cyclooctadiene (1:2)
Bis(1,5-cyclooctadiene)dimethoxydiiridium
(1,5-Cyclooctadiene)(Methoxy)iridiuM(I) DiMer
Bis(1,5-cyclooctadiene)di-μ-methoxydiiridium(I)
Di-μ-Methoxobis(1,5-cyclooctadiene)diiridiuM(I)

Chemical & Physical Properties

[ Melting Point ]:
154-177ºC

[ Molecular Formula ]:
C₁₈H₃₀Ir₂O₂

[ Molecular Weight ]:
662.864

[ Exact Mass ]:
664.150391

[ PSA ]:
34.14000

[ LogP ]:
5.53980

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P280-P304 + P340 + P312-P305 + P351 + P338-P337 + P313

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26

[ RIDADR ]:
NONH for all modes of transport

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Articles

C-H activation/borylation/oxidation: a one-pot unified route to meta-substituted phenols bearing ortho-/para-directing groups.

J. Am. Chem. Soc. 125 , 7792, (2003)

An efficient one-pot C-H activation/borylation/oxidation protocol for the preparation of phenols is described. This method is particularly attractive for the generation of meta-substituted phenols bea...