1,1-Bis(diphenylphosphino)ferrocene

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Names

[ CAS No. ]:
12150-46-8

[ Name ]:
1,1-Bis(diphenylphosphino)ferrocene

[Synonym ]:
1,1'-Ferrocenediyl-bis(diphenylphosphine)
Bis[(1,2,3,4,5-η)-1-(diphenylphosphino)cyclopentadienyl]iron
DPPF
Iron, bis[(1,2,3,4,5-η)-1-(diphenylphosphino)-2,4-cyclopentadien-1-yl]-
EINECS 430-420-3
1,1-Bis(diphenylphosphino)ferrocene
Cyclopentadienyldiphenylphosphine
1,1'-Bis(diphenylphosphiNA)ferrocene
1,1'-bis(diphenyphosphino)ferrocene
1,1'-Bis(diphenylpho
1,1'-Ferrocenebis(diphenylphosphine)
bis-1,1'-(diphenylphosphino)ferrocene
1,1‘-Bis(diphenylphosphino)ferrocene
1'-Bis(diphenylphosphino)ferrocene
1,1'-bis(diphenylphosphanyl)ferrocene
1,1'-bis(diphenylphosphino)ferrocene palladium chloride
1,1''-BIS(DIPHENYLPHOSPHINO)ERROCENE
L50J APR&R& 0-FE-0L50J APR&R
1,1`-Bis(diphenylphosphino)ferrocene
MFCD00001422
Zirconium ionophore I
1,1’-Bis(diphenylphosphino)ferrocene (DPPF)
1,1-BIS (DIPHENYLPHOSPHINO) FERROCENE

Chemical & Physical Properties

[ Boiling Point ]:
363.8ºC at 760mmHg

[ Melting Point ]:
181-182 °C (dec.)(lit.)

[ Molecular Formula ]:
C34H28FeP2

[ Molecular Weight ]:
558.410

[ Flash Point ]:
182.8ºC

[ Exact Mass ]:
558.132865

[ PSA ]:
27.18000

[ LogP ]:
6.38890

[ Storage condition ]:
2-8°C

[ Stability ]:
Stable. Incompatible with strong oxidizing agents.

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
T:Toxic

[ Risk Phrases ]:
R25

[ Safety Phrases ]:
22-24/25-45-28A-36-26

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • FERROCENE
  • Chlorodiphenylphosphine
  • [(η(6)-hexamethylbenzene)RuCl(1,1'-bis(diphenylphosphino)ferrocene-P,P')]PF6
  • dimethylphenylphosphine
  • 1,1′-dilithioferrocene
  • Phenyllithium

DownStream

  • carbon monoxide,cyclopenta-2,4-dien-1-yl(diphenyl)phosphane,iron(2+),tungsten
  • carbon monoxide,cyclopenta-2,4-dien-1-yl(diphenyl)phosphane,iron(2+),molybdenum
  • [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
  • dibromo[1,1'-bis(diphenylphosphino)ferrocene]palladium(II)

Articles

Catalytic selective deuteration of halo(hetero)arenes.

Org. Biomol. Chem. 14 , 3091-7, (2016)

Deuterium labeled aromatic and heteroaromatic compounds are synthesized in good to excellent yields with >98% deuterium purity via palladium catalyzed deuterodehalogenation reaction using commercially...

A new one-Pot synthesis of alkynylphosphonates

Org. Lett. 2 , 3873, (2000)

A method for the palladium-catalyzed synthesis of alkynylphosphonates from 1,1-dibromo-1-alkenes has been developed. In general, the best catalyst system for this transformation was found to be Pd(OAc...

Stereoselective ring opening of meso bicyclic hydrazines: a straightforward approach to hydrazino cyclopentenic cores.

Org. Lett. 5 , 4771, (2003)

The diastereoselective synthesis of hydrazinocyclopentenes 6 or 7 can be achieved in a straightforward manner from Diels-Alder adduct 4 using an acid-catalyzed rearrangement or a palladium-catalyzed a...


More Articles

Related Compounds

  • [1,1-BIS(DIPHENYLPHOSPHINO)FERROCENE]DICHLOROPALLADI
  • Dichloro(1,1-bis(diphenylphosphino)ferrocene)palladium(II) acetone adduct
  • 1,1-Bis(diphenylphosphino)prop-1-ene
  • 1,1-bis(diphenylphosphino)ethylene
  • 1,1-bis(diphenylphosphino)-3-methyl-1,2-butadiene
  • Bis(chlorogold(I)) [1,1′-bis(diphenylphosphino)ferrocene],95