N-Boc-glycine N'-methoxy-N'-methylamide

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Names

[ Name ]:
N-Boc-glycine N'-methoxy-N'-methylamide

[Synonym ]:
tert-Butyl {2-[methoxy(methyl)amino]-2-oxoethyl}carbamate
tert-butyl (2-(methoxy(methyl)amino)-2-oxoethyl)carbamate
N-Boc-glycine N'-methoxy-N'-methylamide
2-Methyl-2-propanyl {2-[methoxy(methyl)amino]-2-oxoethyl}carbamate
N-tert-butoxycarbonylglycine N-methyl-N-methoxyamide
Carbamic acid, N-[2-(methoxymethylamino)-2-oxoethyl]-, 1,1-dimethylethyl ester
MFCD00674101
N-(Tert-Butoxycarbonyl)Glycine N-Methoxy-N-Methylamide
[(N-Methoxy-N-methylcarbamoyl)methyl]carbamic acid tert-butyl ester
Boc-Gly-NMe (OMe)

Chemical & Physical Properties

[ Density]:
1.090±0.06 g/cm3

[ Melting Point ]:
102-103 ºC (ethyl acetate )

[ Molecular Formula ]:
C₉H₁₈N₂O₄

[ Molecular Weight ]:
218.250

[ Exact Mass ]:
218.126663

[ PSA ]:
67.87000

[ LogP ]:
0.72

[ Index of Refraction ]:
1.458

[ Storage condition ]:
Store at 0°C

[ Water Solubility ]:
Sparingly soluble (11 g/L) (25 ºC)

MSDS

Click to get detail MSDS

Safety Information

[ Hazard Codes ]:
Xi

[ RIDADR ]:
NONH for all modes of transport

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Boc-Gly-OH
N,O-Dimethylhydroxylamine hydrochloride
N-methoxymethanamine
BOC-GLY-OME
Boc-Gly-OSu

DownStream

tert-Butyl prop-2-yn-1-ylcarbamate
2-Butenoicacid,4-[[(1,1-dimethylethoxy)carbonyl]amino]-,(2E)-(9CI)
Methyl nicotinate
6-(2-tert-butoxycarbonylamino-acetyl)-nicotinic acid methyl ester
2-Methyl-2-propanyl (2-oxoethyl)carbamate
[2-(3-BROMO-PHENYL)-2-OXO-ETHYL]-CARBAMIC ACID TERT-BUTYL ESTER
2-isocyano-N-methoxy-N-methylacetamide
tert-Butyl-(2-oxopropyl)carbamat
(2-O-BENZYL-4,6-O-BENZYLIDENE)METHYL-ALPHA-D-GLUCOPYRANOSIDE
tert-butyl N-[2-(furan-3-yl)-2-oxoethyl]carbamate

Articles

S. Nahm, S.M. Weinreb

Tetrahedron Lett. 22 , 3815, (1981)

M.P. Sibi

Org. Prep. Proced. Int. 25 , 15, (1993)

Overhand, M. Hecht, S.M

J. Org. Chem. 59 , 4721, (1994)

N-Boc-glycine N'-methoxy-N'-methylamide
N-Boc-D-valine N'-methoxy-N'-methylamide
N-Boc-D-leucine N'-Methoxy-N'-Methylamide
N-ALPHA-CBZ-GLYCINE N-METHOXY-N-METHYLAMIDE
Z-Lys(Boc)-OMe
tert-butyl (1-(methoxy(methyl)amino)-1-oxopropan-2-yl)carbamate
4-((4-cyclopropylthiazol-2-yl)methoxy)-N-(quinolin-8-yl)benzamide
4-((4-cyclopropylthiazol-2-yl)methoxy)-N-(3-(2-methylthiazol-4-yl)phenyl)benzamide
4-((4-cyclopropylthiazol-2-yl)methoxy)-N-(2-methylbenzo[d]thiazol-5-yl)benzamide
4-((4-cyclopropylthiazol-2-yl)methoxy)-N-(2-(thiophen-2-yl)ethyl)benzamide
4-((4-cyclopropylthiazol-2-yl)methoxy)-N-(4,5-dimethylthiazol-2-yl)benzamide
4-((4-(furan-2-yl)thiazol-2-yl)methoxy)-N-(4-sulfamoylphenethyl)benzamide
N-cyclopropyl-4-((4-(furan-2-yl)thiazol-2-yl)methoxy)benzamide
4-((4-(furan-2-yl)thiazol-2-yl)methoxy)-N-((3-methyl-1,2,4-oxadiazol-5-yl)methyl)benzamide
N-benzyl-5-methyl-1-(thiazol-2-yl)-1H-1,2,3-triazole-4-carboxamide
(5-methyl-1-(5-methylthiazol-2-yl)-1H-1,2,3-triazol-4-yl)(morpholino)methanone

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