4-Methoxyphenylacetone

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Names

[ CAS No. ]:
122-84-9

[ Name ]:
4-Methoxyphenylacetone

[Synonym ]:
ACETONYLANISOLE
4-methoxyphenyl-propan-2-one
4-ANISYL ACETONE
FEMA 2674
P-ANISYL ACETONE
Anisketone
p-Methoxy
Anisic ketone
EINECS 204-578-7
p-Anisylactone
1-(p-Methoxyphenyl)-2-propanone
4-Acetonylanisole
MFCD00008773

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
268.0±0.0 °C at 760 mmHg

[ Melting Point ]:
-15ºC

[ Molecular Formula ]:
C10H12O2

[ Molecular Weight ]:
164.201

[ Flash Point ]:
101.7±0.0 °C

[ Exact Mass ]:
164.083725

[ PSA ]:
26.30000

[ LogP ]:
1.35

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.502

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
UC2990000
CHEMICAL NAME :
2-Propanone, 1-(p-methoxyphenyl)-
CAS REGISTRY NUMBER :
122-84-9
BEILSTEIN REFERENCE NO. :
2044332
LAST UPDATED :
199706
DATA ITEMS CITED :
5
MOLECULAR FORMULA :
C10-H12-O2
MOLECULAR WEIGHT :
164.22
WISWESSER LINE NOTATION :
1V1R DO1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 17,857,1979 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
3330 mg/kg
TOXIC EFFECTS :
Behavioral - altered sleep time (including change in righting reflex) Behavioral - tremor Behavioral - changes in motor activity (specific assay)
REFERENCE :
FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 17,857,1979
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
560 mg/kg
TOXIC EFFECTS :
Behavioral - altered sleep time (including change in righting reflex) Behavioral - tremor Behavioral - changes in motor activity (specific assay)
REFERENCE :
JPMSAE Journal of Pharmaceutical Sciences. (American Pharmaceutical Assoc., 2215 Constitution Ave., NW, Washington, DC 20037) V.50- 1961- Volume(issue)/page/year: 60,799,1971
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
>5 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 17,857,1979

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;half-mask respirator (US);multi-purpose combination respirator cartridge (US)

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S23-S24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
2

[ RTECS ]:
UC2990000

[ HS Code ]:
29145000

Synthetic Route

Precursor & DownStream

Precursor

  • p-isopropenylanisole
  • Benzene,1-methoxy-4-(2-nitro-1-propen-1-yl)-
  • cis-Anethol
  • 4-Bromoanisole
  • Isopropenyl acetate
  • Chloroacetone

DownStream

  • p-Anisic acid
  • Bromoform
  • 4-Methoxyphenylacetic acid
  • 3-(4-methoxyphenyl)-3-methylbutan-2-one
  • 4, 4-Dimethoxystilbene
  • Formoterol Hemifumarate
  • 1-methoxy-1-(4-methoxyphenyl)propan-2-one
  • iodoform
  • ACETAMIDE, N-[(4-METHOXYPHENYL)METHYL]-
  • 4-Methoxybenzyl alcohol

Customs

[ HS Code ]: 2914509090

[ Summary ]:
HS:2914509090 other ketones with other oxygen function VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Design and synthesis of 4-methoxyphenylacetic acid esters as 15-lipoxygenase inhibitors and SAR comparative studies of them.

Bioorg. Med. Chem. 17 , 2327-35, (2009)

A group of 4-methoxyphenylacetic acid esters were designed, synthesized and evaluated as potential inhibitors of soybean 15-lipoxygenase (SLO) on the basis of eugenol and esteragol structures. Compoun...


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Related Compounds

  • 2,4-methoxyphenylacetone
  • 2-nitro-4-methoxyphenylacetone
  • 2-fluoro-4-methoxyphenylacetone
  • 3-Chloro-4-methoxyphenylacetone
  • 3-hydroxy-4-methoxyphenylacetone
  • 3-(Chlorosulfonyl)-4-methoxyphenylacetone
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 5-Chloro-1-(1,1-dioxo-1lambda6-thiolan-3-yl)-3-ethyl-1H-pyrazole-4-carboxylic acid
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • 1-(Tert-butyl)-3-(8-methyl-11-oxo-10,11-dihydrodibenzo[b,f][1,4]oxazepin-2-yl)urea
  • N-(furan-2-ylmethyl)-3-oxo-5-((tetrahydrofuran-2-yl)methyl)-3,5-dihydro-2H-pyrazolo[4,3-c]pyridine-7-carboxamide