Benzyl (3R)-3-amino-1-pyrrolidinecarboxylate

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Names

[ CAS No. ]:
122536-72-5

[ Name ]:
Benzyl (3R)-3-amino-1-pyrrolidinecarboxylate

[Synonym ]:
Benzyl (3S)-3-amino-1-pyrrolidinecarboxylate
Benzyl (3S)-3-aminopyrrolidine-1-carboxylate
Benzyl (3R)-3-aminopyrrolidine-1-carboxylate
1-Pyrrolidinecarboxylic acid, 3-amino-, phenylmethyl ester, (3R)-
1-Pyrrolidinecarboxylic acid, 3-amino-, phenylmethyl ester, (3S)-
(S)-(+)-3-Amino-1-(benzyloxycarbonyl)pyrrolidine
Benzyl (3R)-3-amino-1-pyrrolidinecarboxylate
(S)-(+)-1-Cbz-3-aminopyrrolidine

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
351.7±42.0 °C at 760 mmHg

[ Molecular Formula ]:
C12H16N2O2

[ Molecular Weight ]:
220.268

[ Flash Point ]:
166.5±27.9 °C

[ Exact Mass ]:
220.121185

[ PSA ]:
55.56000

[ LogP ]:
0.89

[ Vapour Pressure ]:
0.0±0.8 mmHg at 25°C

[ Index of Refraction ]:
1.571

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xn: Harmful;

[ Risk Phrases ]:
R22;R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2933990090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • S-1-Cbz-3-Boc-amino pyrrolidine
  • (S)-3-azido-1-pyrrolidinecarboxylic acid phenylmethyl ester
  • Benzyl chloroformate
  • Benzyl 3-hydroxy-1-pyrrolidinecarboxylate
  • (R)-3-[(methylsulfonyl)oxy]-1-pyrrolidinecarboxylic acid phenylmethyl ester

DownStream

  • S-1-Cbz-3-Boc-amino pyrrolidine

Customs

[ HS Code ]: 2933990090

[ Summary ]:
2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Related Compounds

  • Benzyl (3R)-3-[(chloroacetyl)(isopropyl)amino]-1-pyrrolidinecarboxylate
  • Benzyl (3R)-3-[glycyl(methyl)amino]-1-pyrrolidinecarboxylate
  • Benzyl (3R)-3-[cyclopropyl(glycyl)amino]-1-pyrrolidinecarboxylate
  • Benzyl (3R)-3-[alanyl(cyclopropyl)amino]-1-pyrrolidinecarboxylate
  • Benzyl (3R)-3-[(chloroacetyl)(cyclopropyl)amino]-1-pyrrolidinecarboxylate
  • Benzyl (3R)-3-[(chloroacetyl)(methyl)amino]-1-pyrrolidinecarboxylate
  • 4-[(3R)-3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-4-methylpentanamido]-3,3-dimethylbutanoic acid
  • 3-[benzyl(methyl)amino]-2-[(3R)-3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-4-methylpentanamido]propanoic acid
  • (2R)-2-[(3S)-3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-4-methylpentanamido]-3,3-dimethylbutanoic acid
  • 5-[(3S)-3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-4-methylpentanamido]-2-methylpentanoic acid
  • 2-[(3S)-3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-4-methylpentanamido]-3-methoxy-2-methylpropanoic acid
  • (R)-4-(1-Amino-2-hydroxyethyl)benzoic acid hydrochloride
  • 3-{2-[(3S)-3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-4-methylpentanamido]ethoxy}propanoic acid
  • 4-[(3S)-3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-4-methylpentanamido]-3-methoxybutanoic acid
  • 2-[(3S)-3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-4-methylpentanamido]-4,4-difluorobutanoic acid
  • [2-(Bromomethyl)prop-2-en-1-yl]cyclopropane
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