Thiomorpholine

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Names

[ CAS No. ]:
123-90-0

[ Name ]:
Thiomorpholine

[Synonym ]:
T6M DSTJ
1-Thia-4-azacyclohexane
perhydro-1,4-thiazine
EINECS 204-660-2
Thiomorpholine
UNII-3A8R61G6QV
Tetrahydro-2H-1,4-thiazine,Thiamorpholine
thiamorpholine
Thiazolidinane
parathiazan
1,4-Thiazane
Tetrahydro-2H-1,4-thiazine
[1,4]thiazinane
MFCD00005974
1,4-Thiazan
tetrahydro-1,4-thiazine

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
170.0±15.0 °C at 760 mmHg

[ Melting Point ]:
166-168

[ Molecular Formula ]:
C4H9NS

[ Molecular Weight ]:
103.19

[ Flash Point ]:
60.0±0.0 °C

[ Exact Mass ]:
103.045570

[ PSA ]:
37.33000

[ LogP ]:
0.27

[ Vapour Pressure ]:
1.5±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.499

MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C:Corrosive;

[ Risk Phrases ]:
R34;R37

[ Safety Phrases ]:
S26-S36/37/39-S45

[ RIDADR ]:
UN 3267 8/PG 3

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
8

[ HS Code ]:
2934999090

Synthetic Route

Precursor & DownStream

Precursor

  • Thiomorpholin-3-one
  • Mustard gas
  • thiomorpholine-4-carbodithioic acid
  • 3-BROMO-6,7-DIHYDRO-5H-PYRROLO[3,4-B]PYRIDINE
  • 1,2-Dibromoethane
  • Ethanol
  • 2-Aminoethanethiol

DownStream

  • Thiomorpholine-1,1-Dioxide
  • tert-Butyl thiomorpholine-4-carboxylate
  • 4-(5-BROMO-PYRIDIN-2-YL)-THIOMORPHOLINE
  • 3,5-Dimethylpyrazole
  • N-NITROSOTHIOMORPHOLINE
  • N,4-Dimethylbenzenesulfonamide
  • 1-amino-1-carboxy-2-methylpropane-2-thiolate
  • N-(2-Hydroxgethyl)moypholine
  • 4-[Dimethyl(vinyl)silyl]thiomorpholine

Customs

[ HS Code ]: 2934999090

[ Summary ]:
2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Synthesis and antitumor activities of some new N1-(flavon-6-yl)amidrazone derivatives.

Arch. Pharm. (Weinheim) 347(6) , 415-22, (2014)

A new series of N1-(flavon-6-yl)amidrazones were synthesized by reacting the hydrazonoyl chloride derived from 6-aminoflavone with the appropriate sec-cyclic amines. The antitumor activities of these ...

Structure-activity relationships of a novel pyranopyridine series of Gram-negative bacterial efflux pump inhibitors.

Bioorg. Med. Chem. 23(9) , 2024-34, (2015)

Recently we described a novel pyranopyridine inhibitor (MBX2319) of RND-type efflux pumps of the Enterobacteriaceae. MBX2319 (3,3-dimethyl-5-cyano-8-morpholino-6-(phenethylthio)-3,4-dihydro-1H-pyrano[...

Redox-neutral α-sulfenylation of secondary amines: ring-fused N,S-acetals.

Org. Lett. 16(13) , 3556-9, (2014)

Secondary amines react with thiosalicylaldehydes in the presence of catalytic amounts of acetic acid to generate ring-fused N,S-acetals in redox-neutral fashion. A broad range of amines undergo α-sulf...


More Articles


Related Compounds

  • Thiomorpholine HCl
  • thiomorpholine-3-one
  • thiomorpholine-3-one
  • N-Boc-thiomorpholine
  • Phenylthiomorpholine
  • Nitrosothiomorpholine
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 3,5-dimethyl-1-[(thiolan-2-yl)methyl]-1H-pyrazol-4-amine
  • (2-Fluoro-3-methoxy-5-(trifluoromethyl)phenyl)(methyl)sulfane
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • Unii-T7UZ9VP9UP
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 2-(3-Bromo-2,2-dimethylpropyl)-5-chloropyridine