Azelaic acid

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Names

[ CAS No. ]:
123-99-9

[ Name ]:
Azelaic acid

[Synonym ]:
Skinoren
AZALEIC ACID
Azelaate
3,4-Dimethoxybenzaldehyde
Nonanedioic acid
Azelaic acid
UNII-F2VW3D43YT
AZELAIC ACID/NONANEDIOIC ACID
Barasertib
AZELAIC ACID FOR SYNTHESIS
INH 34
Azelex
Azelaicacid
Finaceae
lepargylic acid
1,7-HEPTANE DICARBONIC ACID
1,7-HEPTANEDICARBOXYLIC
AZD1152-HQPA
Azelainic acid
HEPTANE-1,7-DICARBOXYLIC ACID
Azalaic Acid
AZELAIC ACID( MICRONIZED )
EINECS 204-669-1
anchoic acid
1,7-Heptanedicarboxylic acid
MFCD00004432

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
286 ºC (100 mmHg)

[ Melting Point ]:
98-103 ºC

[ Molecular Formula ]:
C9H16O4

[ Molecular Weight ]:
188.221

[ Flash Point ]:
215 ºC

[ Exact Mass ]:
188.104858

[ PSA ]:
74.60000

[ LogP ]:
1.33

[ Vapour density ]:
6.5 (vs air)

[ Vapour Pressure ]:
0.0±1.8 mmHg at 25°C

[ Index of Refraction ]:
1.475

[ Stability ]:
Stable. Combustible. Incompatible with bases, strong oxidizing agents. Readily biodegrades in soil and water with >70% DOC reduction after 28 days.

[ Water Solubility ]:
2.4 g/L (20 ºC)

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
CM1980000
CHEMICAL NAME :
Azelaic acid
CAS REGISTRY NUMBER :
123-99-9
BEILSTEIN REFERENCE NO. :
1101094
LAST UPDATED :
199701
DATA ITEMS CITED :
7
MOLECULAR FORMULA :
C9-H16-O4
MOLECULAR WEIGHT :
188.25
WISWESSER LINE NOTATION :
QV7VQ

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
EMERY* Emery Industries, Inc., Data Sheets. (4900 Este Ave., Cincinnati, OH 45232) Volume(issue)/page/year: S3B,-,1964
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
EMERY* Emery Industries, Inc., Data Sheets. (4900 Este Ave., Cincinnati, OH 45232) Volume(issue)/page/year: S3B,-,1964 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>5 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: AD-A067-313 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 83495 No. of Facilities: 170 (estimated) No. of Industries: 8 No. of Occupations: 11 No. of Employees: 1676 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 83495 No. of Facilities: 3427 (estimated) No. of Industries: 35 No. of Occupations: 42 No. of Employees: 34469 (estimated) No. of Female Employees: 7576 (estimated)

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H319

[ Precautionary Statements ]:
P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
1

[ RTECS ]:
CM1980000

[ HS Code ]:
2917139000

Synthetic Route

Precursor & DownStream

Precursor

  • oleic acid
  • Methyl oleate
  • Octadecanedioic acid, 9,10-dihydroxy-
  • ω-carboxyl OA dimethyl ester
  • 9,10-dihydroxystearic acid
  • 8-cyanooctanoic acid
  • 9-Decenoic acid
  • ricinoleic acid
  • Palmitoleic acid
  • Elaidic Acid

DownStream

  • bis(2-ethylbutyl) azelate
  • Nonanedioic acid 1,9-bis(2,5-dioxo-1-pyrrolidinyl) ester
  • 9-HYDROXYNONANOIC ACID
  • Nonanedioic acid,1,9-dihydrazide
  • Heptacosane
  • 1,9-Dibromononane
  • 1,7-Dibromoheptane
  • 8-Methoxycarbonyloctanol
  • 1,9-Nonanediol
  • Cyclooctanone

Customs

[ HS Code ]: 2917139000

[ Summary ]:
2917139000 azelaic acid, sebacic acid, their salts and esters VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

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Related Compounds

  • Azelaic acid
  • azelaic acid aldehyde
  • azelaic acid methyl ester
  • azelaic acid monochloride
  • Azelaic acid,dioctyl ester
  • Azelaic acid,diethyl ester
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 3-(Aminomethyl)-1-methyl-1,2-dihydropyrazin-2-one
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine
  • 4-amino-N-[2-tert-butyl-1-(tetrahydro-2H-pyran-4-ylmethyl)-1H-benzimidazol-5-yl]-N-ethylbenzenesulfonamide