ethylene bis(chloroformate)

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Names

[ CAS No. ]:
124-05-0

[ Name ]:
ethylene bis(chloroformate)

[Synonym ]:
Ethylene glycol,bischloroformate
Aethylenglykol-O.O-dicarbonsaeure-dichlorid
Aethylen-bis-chlorformiat
Carbonochloride acid,1,2-ethanediyl ester
2,5-Dioxy-adipoylchlorid
Aethylenglykol-bis-chlorformiat
Ethylene chloroformate
MFCD00126859
1,2-Bis-chlorcarbonyloxy-aethan
EINECS 204-674-9

Chemical & Physical Properties

[ Density]:
1.504g/cm3

[ Boiling Point ]:
215.7ºC at 760mmHg

[ Molecular Formula ]:
C4H4Cl2O4

[ Molecular Weight ]:
186.97800

[ Flash Point ]:
93.9ºC

[ Exact Mass ]:
185.94900

[ PSA ]:
52.60000

[ LogP ]:
1.73720

[ Vapour Pressure ]:
0.146mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.436(lit.)

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
LQ6000000
CHEMICAL NAME :
Formic acid, chloro-, ethylene ester
CAS REGISTRY NUMBER :
124-05-0
BEILSTEIN REFERENCE NO. :
1707046
LAST UPDATED :
199701
DATA ITEMS CITED :
4
MOLECULAR FORMULA :
C4-H4-Cl2-O4
MOLECULAR WEIGHT :
186.98
WISWESSER LINE NOTATION :
GVO2OVG

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1100 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
37ASAA "Kirk-Othmer Encyclopedia of Chemical Technology," 3rd ed., Grayson, M., and D. Eckroth, eds., New York, John Wiley & Sons, Inc., 1978 Volume(issue)/page/year: 4,758,1978
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
5659 ppm/1H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
37ASAA "Kirk-Othmer Encyclopedia of Chemical Technology," 3rd ed., Grayson, M., and D. Eckroth, eds., New York, John Wiley & Sons, Inc., 1978 Volume(issue)/page/year: 4,758,1978
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
2 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
37ASAA "Kirk-Othmer Encyclopedia of Chemical Technology," 3rd ed., Grayson, M., and D. Eckroth, eds., New York, John Wiley & Sons, Inc., 1978 Volume(issue)/page/year: 4,758,1978

Safety Information

[ Symbol ]:

GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H302-H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C: Corrosive;

[ Risk Phrases ]:
22-34

[ Safety Phrases ]:
S26;S45;S36/S37/S39

[ RIDADR ]:
UN 3265 8/PG 3

[ WGK Germany ]:
3

[ RTECS ]:
LQ6000000

[ HS Code ]:
2915900090

Synthetic Route

Precursor & DownStream

Precursor

  • phosgene
  • Ethylene glycol
  • Antipyrine

DownStream

  • Vinyl Chloroformate
  • Ethane, 1,1-dichloro-
  • CHLOROETHYL CHLOROFORMATE
  • CHLOROETHYL CHLOROFORMATE
  • 2-carbamoyloxyethyl carbamate
  • 2,5-DIOXAHEXANEDIOIC ACID DIETHYL ESTER
  • Carbonic acid,C,C'-1,2-ethanediyl C,C'-dimethyl ester
  • 4-Morpholinecarboxylicacid, 1,2-ethanediyl ester (9CI)
  • Carbonicacid, C,C'-1,2-ethanediyl C,C'-di-2-propen-1-yl ester
  • Carbanilic acid,m-chloro-, ethylene ester (8CI)

Customs

[ HS Code ]: 2915900090

[ Summary ]:
2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

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Related Compounds

  • Oxydiethylene bis(chloroformate)
  • hexamethylene bis(chloroformate)
  • tetramethylene bis(chloroformate)
  • 1,4-Phenylenedimethylene bis(chloroformate)
  • ethylene bis(cyclohexanecarboxylate)
  • ethylene bis[[(8-octyl-5,11-dioxo-1,4-dioxa-7,9-dithia-8-stannacycloundec-8-yl)thio]acetate]