Sodium Methylate

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Names

[ CAS No. ]:
124-41-4

[ Name ]:
Sodium Methylate

[Synonym ]:
Sodium Methoxide, Powder
Sodium methylate
EINECS 204-699-5
Sodium Methoxide
Sodium Methanolate
methanol sodium salt
MFCD00012179

Chemical & Physical Properties

[ Density]:
0.945

[ Boiling Point ]:
65 °C

[ Melting Point ]:
127 ºc

[ Molecular Formula ]:
CH3NaO

[ Molecular Weight ]:
54.024

[ Flash Point ]:
11 °C

[ Exact Mass ]:
54.008160

[ PSA ]:
23.06000

[ LogP ]:
0.04670

[ Vapour density ]:
1.1 (vs air)

[ Vapour Pressure ]:
50 mm Hg ( 20 °C)

[ Index of Refraction ]:
1.3700

[ Stability ]:
Stability Highly flammable. Reacts violently with water. Keep container dry. Incompatible with water, acids, chlorinated solvents.

[ Water Solubility ]:
reacts

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
PC3570000
CHEMICAL NAME :
Methanol, sodium salt
CAS REGISTRY NUMBER :
124-41-4
LAST UPDATED :
199806
DATA ITEMS CITED :
5
MOLECULAR FORMULA :
C-H3-O.Na
MOLECULAR WEIGHT :
54.03
WISWESSER LINE NOTATION :
O1 &-NA- &6/1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
2037 mg/kg
TOXIC EFFECTS :
Sense Organs and Special Senses (Eye) - chromodacryorrhea Behavioral - ataxia Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0555267 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 80549 No. of Facilities: 185 (estimated) No. of Industries: 6 No. of Occupations: 14 No. of Employees: 3624 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 80549 No. of Facilities: 330 (estimated) No. of Industries: 9 No. of Occupations: 27 No. of Employees: 18230 (estimated) No. of Female Employees: 4356 (estimated)

Safety Information

[ Symbol ]:

GHS02, GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H251-H302-H314

[ Supplemental HS ]:
Reacts violently with water.

[ Precautionary Statements ]:
P235 + P410-P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
F:Flammable

[ Risk Phrases ]:
R11;R14;R23/24/25;R36/38;R39/23/24/25

[ Safety Phrases ]:
S8-S16-S26-S43-S45-S7-S36/37-S7/8-S36/37/39

[ RIDADR ]:
UN 1431 4.2/PG 2

[ WGK Germany ]:
1

[ RTECS ]:
PC3570000

[ Packaging Group ]:
II

[ Hazard Class ]:
4.2

[ HS Code ]:
2905199090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Methanol
  • sodium
  • Trimethyl borate
  • 1-ethenylbicyclo[1.1.0]butane-3-carbonitrile
  • Sodium tetramethoxyborate
  • Trimethyl Methoxysilane
  • Sodium 1,1-dimethoxy-2,4,6-trinitrocyclohexadienate-2,5
  • malonic acid dimethyl ester, deprotonated form
  • ethyl cyanoacetate anion
  • 4-nitrobenzyl cyanide anion

DownStream

  • 4-methoxy-2,3-dimethyl-1-oxidopyridin-1-ium
  • dibutyldimethoxytin
  • diethyl(dimethoxy)stannane
  • tetramethyl 1-methoxyethane-1,1,2,2-tetracarboxylate
  • methyl 2-methoxy-4-(methylamino)benzoate
  • Methyl (2S)-2-methylbutanoate
  • 5-methoxy-1H-1,4-benzodiazepine
  • 5-Chloro-3,4-dimethoxypyridazine
  • 4-chloro-3,5-dimethoxy-pyridazine
  • 5-Methyl-2-phenyl-oxazole-4-carboxylic acid Methyl ester

Customs

[ HS Code ]: 2905199090

[ Summary ]:
2905199090. saturated monohydric alcohols. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

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Related Compounds

  • sodium methylate
  • 2,4,6-trinitro-anisole, compound with sodium methylate
  • Reaction product of benzoic acid,2,3,4,5-tetrachloro-6-cyano-,methyl ester with sodium methylate and 1,4-benzenediamine
  • Reaction product of benzoic acid,2,3,4,5-tetrachloro-6-cyano-,methyl ester with sodium methylate and 1,3-benzenediamine,2-methyl
  • sodium lauroamphoacetate
  • sodium,(Z)-4-[(2-amino-3-methylbutanoyl)amino]-3-chloro-5-hydroxy-5-oxopent-2-enoate
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 2-{bis[(furan-2-yl)methyl]amino}-N-(1-cyano-1,2-dimethylpropyl)acetamide
  • 2-[4-(1-{[(4-ethoxyphenyl)carbamoyl]methyl}-2,4-dioxo-1,2,3,4-tetrahydroquinazolin-3-yl)phenyl]-N-(propan-2-yl)acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine