Dichloro(methyl)vinylsilane

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Names

[ CAS No. ]:
124-70-9

[ Name ]:
Dichloro(methyl)vinylsilane

[Synonym ]:
METHYLVINYLDICHLOROSILANE
silane,dichloromethylvinyl
dichloroethenylmethyl-silan
Vinylmethyldichlorsilane
Methyldichlorovinylsilane
dichloro(ethenyl)methylsilane
EINECS 204-710-3
CV-4772
Dichloro(methyl)(vinyl)silane
MFCD00000492
Dichloro(methyl)vinylsilane
dichloromethylvinyl-silan
DichloroMethylvinylsilane
VINYLMETHYLDICHLOROSILANE
METHYLVINYLCHLOROSILANE
Silane, dichloroethenylmethyl-

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
92.5±9.0 °C at 760 mmHg

[ Melting Point ]:
-78°C

[ Molecular Formula ]:
C3H6Cl2Si

[ Molecular Weight ]:
141.071

[ Flash Point ]:
4.4±0.0 °C

[ Exact Mass ]:
139.961578

[ LogP ]:
3.78

[ Vapour density ]:
>1 (vs air)

[ Vapour Pressure ]:
58.4±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.431

[ Storage condition ]:
0-6°C

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
VV3533000
CHEMICAL NAME :
Silane, dichloromethylvinyl-
CAS REGISTRY NUMBER :
124-70-9
BEILSTEIN REFERENCE NO. :
1740822
LAST UPDATED :
199701
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
C3-H6-Cl2-Si
MOLECULAR WEIGHT :
141.08
WISWESSER LINE NOTATION :
G-SI-G1&1U1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
56 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#03620

Safety Information

[ Symbol ]:

GHS02, GHS05, GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H302-H314-H331

[ Supplemental HS ]:
Corrosive to the respiratory tract., Reacts violently with water.

[ Precautionary Statements ]:
P210-P261-P280-P303 + P361 + P353-P305 + P351 + P338-P370 + P378

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F:Highlyflammable;C:Corrosive;

[ Risk Phrases ]:
R11;R14;R34

[ Safety Phrases ]:
S16-S26-S36/37/39-S45

[ RIDADR ]:
UN 2985 3/PG 2

[ WGK Germany ]:
1

[ RTECS ]:
VV3533000

[ Packaging Group ]:
II

[ Hazard Class ]:
3

[ HS Code ]:
29310095

Synthetic Route

Precursor & DownStream

Precursor

  • methyl dichlorosilane
  • Acetylene
  • (chloromethyl)divinylmethylsilane
  • Vinyltrichlorosilane
  • 1-CHLOROETHYLMETHYLDICHLOROSILANE
  • Dichloro(2-chloroethyl)methylsilane
  • ethene
  • METHYLMAGNESIUM BROMIDE
  • Methyl(trivinyl)silane
  • hexylmethyldichlorosilane

DownStream

  • ethane-1,2-diylbis(dichloromethylsilane)
  • ethylenebis(chlorodimethylsilane)
  • 1,2-ethanediylbis(trimethyl-Silane
  • 2-(dichloromethylsilyl)ethyl-trimethylsilane
  • 2,4,6-Trimethyl-2,4,6-trivinylcyclotrisilazane
  • methylvinyldiethoxysilane
  • 1,3,5,7-tetramethyl-1,3,5,7-tetravinylcyclotetrasilazane
  • dimethylvinylchlorosilane
  • Dichloro(ethyl)methylsilane

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

[Graft polymerization onto poly(methylvinylsiloxane)-bonded silica gel by gamma-ray irradiation].

Radioisotopes 33(8) , 513-8, (1984)

Poly(methylvinylsiloxane)-bonded silica gel was synthesized by condensation reaction between silica gel and the hydrolysis product of methylvinyldichlorosilane. Graft polymerization of styrene or inde...

Growth of β-SiC nanowires and thin films by metalorganic chemical vapor deposition using dichloromethylvinylsilane. Kang B-C, et al.

J. Vac. Sci. Technol. B 23(4) , 1722-1725, (2005)

Influence of the Precursor Cross-Linking Route on the Thermal Stability of Si- B- C- O Ceramics. Ischenko V, et al.

Chem. Mater. 20(22) , 7148-7156, (2008)


More Articles


Related Compounds

  • Dichloro(methyl)(p-tolyl)silane
  • dichloro-methyl-selanylidene-λ5-phosphane
  • dichloro-methyl-(3-methyl-benzyl)-silane
  • Dichloro(methyl)[2-(4-methylphenyl)ethyl]silane
  • Dichloro(methyl)(4-phenylbutyl)silane
  • Dichloro-methyl-((Z)-2-methyl-but-2-enyl)-silane
  • N-(2-bromo-6-methoxy-pyridin-4-yl)-N'-methoxy-N'-methyl-oxalamide
  • 3-(3-Methylthiophen-2-yl)pyrrolidine
  • 2-amino-N-[2-fluoro-3-(trifluoromethyl)benzyl]acetamide
  • N-(3,4-Dihydroxyphenyl)formamide
  • 6-Methoxy-2-(methylamino)quinoline-3-carbaldehyde
  • N-(2-Bromo-6-methoxy-pyridin-4-yl)-3-methyl-2-oxo-butyramide
  • 2-(4-Fluorophenyl)-6-(trifluoromethyl)imidazo[1,2-a]pyridine-3-carbaldehyde
  • tert-butyl (5-cyano-2-oxo-1,3-benzoxazol-3(2H)-yl)acetate
  • Methyl 2-amino-5-fluoro-4-methoxybenzoate
  • (1-Methylcyclohex-3-en-1-yl)methanamine
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