Trimethyl(pentafluoroethyl)silane

Names

[ Name ]:
Trimethyl(pentafluoroethyl)silane

[Synonym ]:
Silane, trimethyl(1,1,2,2,2-pentafluoroethyl)-
Trimethyl(pentafluoroethyl)silane
trimethyl(1,1,2,2,2-pentafluoroethyl)silane
MFCD04116436

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
43.4±40.0 °C at 760 mmHg

[ Molecular Formula ]:
C₅H₉F₅Si

[ Molecular Weight ]:
192.202

[ Flash Point ]:
-20.0±27.3 °C

[ Exact Mass ]:
192.039368

[ LogP ]:
2.47

[ Vapour Pressure ]:
390.2±0.1 mmHg at 25°C

[ Index of Refraction ]:
1.321

MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H315-H319-H335

[ Precautionary Statements ]:
P210-P305 + P351 + P338-P370 + P378-P403 + P235

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R11

[ Safety Phrases ]:
S26-S36/37/39

[ RIDADR ]:
1993

[ Packaging Group ]:
II

[ Hazard Class ]:
3

Synthetic Route

Click to get detail synthetic route

Articles

Synthetic and mechanistic aspects of the regioselective base-mediated reaction of perfluoroalkyl- and perfluoroarylsilanes with heterocyclic N-oxides.

Org. Biomol. Chem. 12(32) , 6190-9, (2014)

The scope and mechanistic implications of the direct transformation of heterocyclic N-oxides to 2-trifluoromethyl-, and related perfluoroalkyl- and perfluoroaryl-substituted N-heterocycles has been st...

A Facile New Method for the Two-step Substitution of Hydroxy Groups in Primary Alcohols for Trifluoromethyl and Pentafluoroethyl Moieties. Sevenard DV, et al.

Synlett 2001(03) , 0379-0381, (2001)

Experimental determination of the conformational free energies (A values) of fluorinated substituents in cyclohexane by dynamic 19 F NMR spectroscopy. Part 2. Extension to fluoromethyl, difluoromethyl, pentafluoroethyl, trifluoromethylthio and trifluoromethoxy groups. Carcenac Y, et al.

New J. Chem. 30(3) , 447-457, (2006)

methanidyl(trimethyl)silane,vanadium
cyclopropyl(trimethyl)silane
cycloheptyl(trimethyl)silane
hydroxy(trimethyl)silane,2-nitrobenzoic acid
cyclopropylmethyl(trimethyl)silane
hydroxy(trimethyl)silane,3-nitrobenzoic acid
Carbamic acid, N-[1-[1-[(methylsulfonyl)oxy]ethyl]pentyl]-, 1,1-dimethylethyl ester
tert-Butyl (5-oxo-4-azaspiro[2.6]nonan-6-yl)carbamate
Methyl 2-{[(tert-butoxy)carbonyl]amino}-3-methylpent-4-enoate
tert-butyl N-(1-hydroxy-4-methylhexan-2-yl)carbamate
tert-Butyl (4-amino-2-methylcyclopentyl)carbamate
tert-Butyl N-(4-amino-2-fluorocyclopentyl)carbamate
tert-Butyl (4-amino-2-fluorocyclohexyl)carbamate
Tert-butyl 2-(hydroxymethyl)-4-methylazetidine-1-carboxylate
3-{Benzyl[(tert-butoxy)carbonyl]amino}-4-methylpentanoic acid
Tert-butyl N-[1-(chlorosulfonyl)-3,3-dimethylbutan-2-YL]carbamate

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