Trimethyl(pentafluoroethyl)silane

Names

[ Name ]:
Trimethyl(pentafluoroethyl)silane

[Synonym ]:
Silane, trimethyl(1,1,2,2,2-pentafluoroethyl)-
Trimethyl(pentafluoroethyl)silane
trimethyl(1,1,2,2,2-pentafluoroethyl)silane
MFCD04116436

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
43.4±40.0 °C at 760 mmHg

[ Molecular Formula ]:
C₅H₉F₅Si

[ Molecular Weight ]:
192.202

[ Flash Point ]:
-20.0±27.3 °C

[ Exact Mass ]:
192.039368

[ LogP ]:
2.47

[ Vapour Pressure ]:
390.2±0.1 mmHg at 25°C

[ Index of Refraction ]:
1.321

MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H315-H319-H335

[ Precautionary Statements ]:
P210-P305 + P351 + P338-P370 + P378-P403 + P235

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R11

[ Safety Phrases ]:
S26-S36/37/39

[ RIDADR ]:
1993

[ Packaging Group ]:
II

[ Hazard Class ]:
3

Synthetic Route

Click to get detail synthetic route

Articles

Synthetic and mechanistic aspects of the regioselective base-mediated reaction of perfluoroalkyl- and perfluoroarylsilanes with heterocyclic N-oxides.

Org. Biomol. Chem. 12(32) , 6190-9, (2014)

The scope and mechanistic implications of the direct transformation of heterocyclic N-oxides to 2-trifluoromethyl-, and related perfluoroalkyl- and perfluoroaryl-substituted N-heterocycles has been st...

A Facile New Method for the Two-step Substitution of Hydroxy Groups in Primary Alcohols for Trifluoromethyl and Pentafluoroethyl Moieties. Sevenard DV, et al.

Synlett 2001(03) , 0379-0381, (2001)

Experimental determination of the conformational free energies (A values) of fluorinated substituents in cyclohexane by dynamic 19 F NMR spectroscopy. Part 2. Extension to fluoromethyl, difluoromethyl, pentafluoroethyl, trifluoromethylthio and trifluoromethoxy groups. Carcenac Y, et al.

New J. Chem. 30(3) , 447-457, (2006)

methanidyl(trimethyl)silane,vanadium
cyclopropyl(trimethyl)silane
cycloheptyl(trimethyl)silane
hydroxy(trimethyl)silane,2-nitrobenzoic acid
cyclopropylmethyl(trimethyl)silane
hydroxy(trimethyl)silane,3-nitrobenzoic acid
Tert-butyl [[1-(n-methylsulfamoyl)piperidin-4-yl]methyl]carbamate
4-((Benzyloxy)carbonyl)-1-(tert-butoxycarbonyl)-1,4-diazepane-5-carboxylic acid
4-[2-[(2E)-2-[(4-hydroxyphenyl)methylidene]hydrazinyl]-1,3-thiazol-4-yl]-N,N-dimethylbenzenesulfonamide
1,5,5-trimethyl-3-(2-phenoxyethyl)-2,4-Imidazolidinedione
5-Bromo-6-isocyanato-3-methyl-1-[(4-methylphenyl)sulfonyl]-1h-indazole
N-[(1R)-1-(Hydroxymethyl)-3-(methylthio)propyl]-2-[[3-[(1E)-2-(2-pyridinyl)ethenyl]-1H-indazol-6-yl]thio]benzamide
(5-Cyclopropyl-4-fluoro-1H-pyrazol-3-YL)methanol
9-Methyl-N-(4-(2-methylpyridin-4-yl)benzyl)-9H-carbazole-2-carboxamide
methyl 1-ethyl-5-formyl-1H-pyrazole-3-carboxylate
1-(3-Aminopiperidin-1-yl)-2-chloroethan-1-one

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