Aminoglutethimide

Suppliers

Names

[ CAS No. ]:
125-84-8

[ Name ]:
Aminoglutethimide

[Synonym ]:
Orimeten
UNII:0O54ZQ14I9
3-(p-Aminophenyl)-3-ethylpiperidine-2,6-dione (3-(4-Aminophenyl)-3-ethyl-2,6-piperidinedione
Cytadren
(RS)-Aminoglutethimide
2,6-Piperidinedione, 3-(4-aminophenyl)-3-ethyl-
MFCD00010122
EINECS 204-756-4
(±)-Aminoglutethimide
(±)-p-Aminoglutethimide
2,6-Piperidinedione, 3-(4-aminophenyl)-3-ethyl-, (+)-
aminoglutethimide
DL-Aminoglutethimide
3-(4-aminophenyl)-3-ethylpiperidine-2,6-dione
p-Aminoglutethimide
3-(4-Aminophenyl)-3-ethyl-2,6-piperidinedione
3-(p-Aminophenyl)-3-ethylpiperidine-2,6-dione 3-(4-Aminophenyl)-3-ethyl-2,6-piperidinedione

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
457.4±45.0 °C at 760 mmHg

[ Melting Point ]:
152-154 °C(lit.)

[ Molecular Formula ]:
C13H16N2O2

[ Molecular Weight ]:
232.278

[ Flash Point ]:
230.4±28.7 °C

[ Exact Mass ]:
232.121185

[ PSA ]:
72.19000

[ LogP ]:
1.41

[ Vapour Pressure ]:
0.0±1.1 mmHg at 25°C

[ Index of Refraction ]:
1.566

[ Water Solubility ]:
H2O: 0.2 mg/mL, slightly soluble

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
MA4026950
CHEMICAL NAME :
Glutarimide, 2-(p-aminophenyl)-2-ethyl-
CAS REGISTRY NUMBER :
125-84-8
BEILSTEIN REFERENCE NO. :
0210656
LAST UPDATED :
199612
DATA ITEMS CITED :
5
MOLECULAR FORMULA :
C13-H16-N2-O2
MOLECULAR WEIGHT :
232.31
WISWESSER LINE NOTATION :
T6VMVTJ D2 DR DZ

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Human - woman
DOSE/DURATION :
20500 mg/kg/94W-I
TOXIC EFFECTS :
Blood - agranulocytosis
REFERENCE :
BMJOAE British Medical Journal. (British Medical Assoc., BMA House, Tavistock Sq., London WC1H 9JR, UK) V.1- 1857- Volume(issue)/page/year: 291,970,1985
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Human - man
DOSE/DURATION :
21 mg/kg/3D-I
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - dyspnea Nutritional and Gross Metabolic - body temperature increase
REFERENCE :
AIMEAS Annals of Internal Medicine. (American College of Physicians, 4200 Pine St., Philadelphia, PA 19104) V.1- 1927- Volume(issue)/page/year: 105,633,1986
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
625 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Behavioral - antipsychotic
REFERENCE :
JMCMAR Journal of Medicinal Chemistry. (American Chemical Soc., Distribution Office Dept. 223, POB POB 57136, West End Stn., Washington, DC 20037) V.6- 1963- Volume(issue)/page/year: 18,736,1975 ** REPRODUCTIVE DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
3630 mg/kg
SEX/DURATION :
female 1-35 week(s) after conception
TOXIC EFFECTS :
Reproductive - Specific Developmental Abnormalities - urogenital system
REFERENCE :
AJDCAI American Journal of Diseases of Children. (AMA, 535 N. Dearborn St., Chicago, IL 60610) V.1-80(3), 1911-50; V.100- 1960- Volume(issue)/page/year: 124,421,1972 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X5423 No. of Facilities: 18 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 403 (estimated) No. of Female Employees: 179 (estimated)

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
3249

[ WGK Germany ]:
3

[ RTECS ]:
MA4026950

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1(b)

[ HS Code ]:
2925190090

Synthetic Route

Precursor & DownStream

Precursor

  • 3-ethyl-3-(4-nitrophenyl)piperidine-2,6-dione
  • 2-ethyl-2-phenylglutaronitrile
  • 2-phenylbutyronitrile
  • Benzyl cyanide
  • glutethimide
  • nitrobenzene
  • Benzeneacetic acid, a-ethyl-4-nitro-, ethyl ester
  • 1-hydroxy-3-ethyl-3-(4-aminophenyl)piperidine-2,6-dione
  • 1-benzyloxy-3-ethyl-3-(4-nitrophenyl)piperidine-2,6-dione

DownStream

  • D-Aminoglutethimide
  • (-)-Aminoglutethimide
  • 3-iodo-4-aminoglutethimide

Customs

[ HS Code ]: 2925190090

[ Summary ]:
2925190090 other imides and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

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Related Compounds

  • (-)-Aminoglutethimide
  • (S)-Aminoglutethimide tartrate
  • S-(-)-Aminoglutethimide D-Tartrate Salt
  • aminoglutethimide phosphate
  • aminoglutethimide
  • aminoglutethimide phosphate
  • 3-(Difluoromethyl)-2-iodo-5-nitropyridin-4-amine
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 2-(3-Chloropropyl)-5-(difluoromethoxy)phenylacetonitrile
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine