Tris(pentafluorophenyl)phosphine

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Names

[ Name ]:
Tris(pentafluorophenyl)phosphine

[Synonym ]:
Tris(perfluorophenyl)phosphine
Phosphine, tris(pentafluorophenyl)-
MFCD00079654
Phosphine, tris(2,3,4,5,6-pentafluorophenyl)-
EINECS 215-021-2
Tris(pentafluorophenyl)phosphine
tris(2,3,4,5,6-pentafluorophenyl)phosphane

Chemical & Physical Properties

[ Boiling Point ]:
343.4±42.0 °C at 760 mmHg

[ Melting Point ]:
108-110 °C(lit.)

[ Molecular Formula ]:
C₁₈F₁₅P

[ Molecular Weight ]:
532.15

[ Flash Point ]:
161.5±27.9 °C

[ Exact Mass ]:
531.949829

[ PSA ]:
13.59000

[ LogP ]:
6.24

[ Vapour Pressure ]:
0.0±0.7 mmHg at 25°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2903999090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Difluorotris(pentafluorophenyl)phosphorane
1-Bromo-2,3,4,5,6-pentafluorobenzene
Phosphine oxide,tris(2,3,4,5,6-pentafluorophenyl)-
N-[bis(trifluoromethyl)amino]oxy-1,1,1-trifluoro-N-(trifluoromethyl)methanamine
2,3,4,5,6-Pentafluorobenzoic acid
silver(I) n-butyrate

Customs

[ HS Code ]: 2903999090

[ Summary ]:
2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Laser flash photolysis generation and kinetic studies of porphyrin-manganese-oxo intermediates. Rate constants for oxidations effected by porphyrin-Mn(V)-oxo species and apparent disproportionation equilibrium constants for porphyrin-Mn(IV)-oxo species.

J. Am. Chem. Soc. 127(18) , 6573-82, (2005)

Porphyrin-manganese(V)-oxo and porphyrin-manganese(IV)-oxo species were produced in organic solvents by laser flash photolysis (LFP) of the corresponding porphyrin-manganese(III) perchlorate and chlor...

Structure of tris(pentafluorophenyl)phosphine.

Acta Crystallogr. C 45 ( Pt 11) , 1743-5, (1989)

C18F15P, Mr = 532.1, monoclinic, P2(1)/c, a = 7.194 (2), b = 17.930 (4), c = 13.834 (2) A, beta = 94.29 (2) degrees, V = 1779 A3, Z = 4, Dm = 2.00, Dx = 1.99 g cm-3, lambda(Mo K alpha) = 0.71073 A, mu...

Probing bare high-valent transition oxo-metal complexes: an electrospray ionization Fourier transform ion cyclotron resonance study of reactive intermediates.

Eur. J. Mass Spectrom. (Chichester, Eng.) 16(3) , 407-14, (2010)

Functional models of the Compound I intermediate of monooxygenase heme enzymes, namely [(TPFPP)(*+)Fe(IV)=O](+) and [(TPFPP)Mn(V)=O](+) (TPFPP = meso-tetrakis (pentafluorophenyl)porphyrinato dianion),...

tris(pentafluorophenyl)phosphine oxide
Tris(pentafluorophenyl)phosphine sulfide
undecacarbonyl(tris(pentafluorophenyl)phosphine)triosmium
tris(pentafluorophenyl)-bis{bis(trifluoromethyl)aminooxy}stiborane
tris(pentafluorophenyl)germanium bromide
Tris[(pentafluorophenyl)thio]arsane