Petasis reagent

Suppliers

Names

[ CAS No. ]:
1271-66-5

[ Name ]:
Petasis reagent

[Synonym ]:
Bis(cyclopentadienyl)dimethyltitanium
Dimethyltitanium(2+) di(2,4-cyclopentadienide)
Cp2TiMe2
Petasis reagent
dimethyltitanocene
bis(η5-cyclopentadienyl)dimethyltitanium

Chemical & Physical Properties

[ Molecular Formula ]:
C12H16Ti

[ Molecular Weight ]:
208.122

[ Exact Mass ]:
208.073151

[ LogP ]:
3.21060

[ Storage condition ]:
Freezer (-20°C)

[ Water Solubility ]:
SLOW hydrolysis

MSDS

Click to get detail MSDS

Safety Information

[ Hazard Codes ]:
F: Flammable;Xn: Harmful;

[ Risk Phrases ]:
R11;R38;R48/20;R63;R65;R67

[ Safety Phrases ]:
62-46-36/37

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Titanocene dichloride
  • Methylmagnesium chloride
  • METHYLLITHIUM
  • METHYLMAGNESIUM BROMIDE
  • Titanium tetrachloride
  • Cyclopentadiene
  • carbanide,chlorotitanium(3+),cyclopenta-1,3-diene
  • trimethylaluminum
  • lithium tetramethylaluminate(III)

DownStream

  • 1-Brom-3,3-dimethylbutan-2-on
  • 2-Bromo-1-cyclohexylethanone
  • Titanocene dichloride
  • 2-Butanone,1,1-dibromo-3,3-dimethyl-
  • 1-Bromo-2-butanone
  • 1,1-dibromo-butan-2-one
  • 1,3-DIBROMO-2-BUTANONE
  • 1-Bromoacetone
  • carbanide,chlorotitanium(3+),cyclopenta-1,3-diene
  • dimethylmercury

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Related Compounds

  • Eschenmoser's reagent
  • Comins' Reagent
  • Cornforth reagent
  • Hendrickson's reagent
  • Stang's reagent
  • Freeman's reagent
  • [(3-Bromophenyl)imino](ethyl)methyl-lambda6-sulfanone
  • (4S,5R)-4-Amino-5-(4-chloro-3-fluorophenyl)-1-propan-2-ylpyrrolidin-2-one;hydrochloride
  • 3-(3-Methoxyazetidin-3-yl)-4-methyl-4H-1,2,4-triazole dihydrochloride
  • lithium(1+) ion 5-bromo-1-methyl-1H-imidazole-2-carboxylate
  • 2-Hydroxy-3-(1-methyl-1H-imidazol-4-yl)propanoic acid hydrochloride
  • 3-[(4-Methoxybutyl)(methyl)amino]propanoic acid hydrochloride
  • 4-(Difluoromethyl)-N-methylcyclohexan-1-amine hydrochloride
  • [1,2,4]Triazolo[4,3-a]pyridine-8-carboxylic acid hydrochloride
  • [1-(Oxan-2-yl)cyclopropyl]methanol
  • Tert-butyl N-[4-fluoro-3-(nitromethyl)phenyl]carbamate
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