Petasis reagent

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Names

[ CAS No. ]:
1271-66-5

[ Name ]:
Petasis reagent

[Synonym ]:
Bis(cyclopentadienyl)dimethyltitanium
Dimethyltitanium(2+) di(2,4-cyclopentadienide)
Cp2TiMe2
Petasis reagent
dimethyltitanocene
bis(η5-cyclopentadienyl)dimethyltitanium

Chemical & Physical Properties

[ Molecular Formula ]:
C12H16Ti

[ Molecular Weight ]:
208.122

[ Exact Mass ]:
208.073151

[ LogP ]:
3.21060

[ Storage condition ]:
Freezer (-20°C)

[ Water Solubility ]:
SLOW hydrolysis

MSDS

Click to get detail MSDS

Safety Information

[ Hazard Codes ]:
F: Flammable;Xn: Harmful;

[ Risk Phrases ]:
R11;R38;R48/20;R63;R65;R67

[ Safety Phrases ]:
62-46-36/37

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Titanocene dichloride
  • Methylmagnesium chloride
  • METHYLLITHIUM
  • METHYLMAGNESIUM BROMIDE
  • Titanium tetrachloride
  • Cyclopentadiene
  • carbanide,chlorotitanium(3+),cyclopenta-1,3-diene
  • trimethylaluminum
  • lithium tetramethylaluminate(III)

DownStream

  • 1-Brom-3,3-dimethylbutan-2-on
  • 2-Bromo-1-cyclohexylethanone
  • Titanocene dichloride
  • 2-Butanone,1,1-dibromo-3,3-dimethyl-
  • 1-Bromo-2-butanone
  • 1,1-dibromo-butan-2-one
  • 1,3-DIBROMO-2-BUTANONE
  • 1-Bromoacetone
  • carbanide,chlorotitanium(3+),cyclopenta-1,3-diene
  • dimethylmercury

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Related Compounds

  • Eschenmoser's reagent
  • Comins' Reagent
  • Cornforth reagent
  • Hendrickson's reagent
  • Stang's reagent
  • Freeman's reagent
  • 3-(1-(2-(o-Tolyloxy)acetyl)azetidin-3-yl)imidazolidine-2,4-dione
  • 4-((4-methoxy-2-methylphenylsulfonamido)methyl)-N,N-dimethylpiperidine-1-carboxamide
  • 4-[(4-methoxy-3,5-dimethylbenzenesulfonamido)methyl]-N,N-dimethylpiperidine-1-carboxamide
  • 4-((5-ethyl-2-methoxyphenylsulfonamido)methyl)-N,N-dimethylpiperidine-1-carboxamide
  • methyl 3-(N-((1-(dimethylcarbamoyl)piperidin-4-yl)methyl)sulfamoyl)thiophene-2-carboxylate
  • 4-((2,5-dichlorophenylsulfonamido)methyl)-N,N-dimethylpiperidine-1-carboxamide
  • 4-((2-bromophenylsulfonamido)methyl)-N,N-dimethylpiperidine-1-carboxamide
  • N,N-dimethyl-4-((3,3,3-trifluoropropylsulfonamido)methyl)piperidine-1-carboxamide
  • 4-((benzo[c][1,2,5]thiadiazole-4-sulfonamido)methyl)-N,N-dimethylpiperidine-1-carboxamide
  • 4-((4-(1H-pyrazol-1-yl)phenylsulfonamido)methyl)-N,N-dimethylpiperidine-1-carboxamide
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