Sodium dimethyldithiocarbamate

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Names

[ CAS No. ]:
128-04-1

[ Name ]:
Sodium dimethyldithiocarbamate

[Synonym ]:
Carbamodithioic acid, dimethyl-, sodium salt
Sodium dimethylcarbamodithioate
Carbamodithioic acid, N,N-dimethyl-, sodium salt (1:1)
MSL
Sodium Dimethyldithiocarbamate
Dimethyldithiocarbamic acid sodium salt
MFCD00150729
EINECS 204-876-7

Chemical & Physical Properties

[ Density]:
1.17

[ Boiling Point ]:
130ºC

[ Melting Point ]:
120-122 °C (dec.)(lit.)

[ Molecular Formula ]:
C3H6NNaS2

[ Molecular Weight ]:
143.206

[ Flash Point ]:
32ºC

[ Exact Mass ]:
142.983932

[ PSA ]:
60.63000

[ LogP ]:
1.03040

[ Storage condition ]:
0-6°C

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
FD3500000
CHEMICAL NAME :
Carbamodithioic acid, dimethyl-, sodium salt
CAS REGISTRY NUMBER :
128-04-1
LAST UPDATED :
199710
DATA ITEMS CITED :
13
MOLECULAR FORMULA :
C3-H6-N-S2.Na
MOLECULAR WEIGHT :
143.21
WISWESSER LINE NOTATION :
SUYSHN1&1 &-NA-

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1500 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold Behavioral - changes in motor activity (specific assay)
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
573 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
1840 mg/kg/23D-I
TOXIC EFFECTS :
Blood - leukopenia Blood - changes in other cell count (unspecified) Related to Chronic Data - death

MUTATION DATA

TYPE OF TEST :
Mutation in microorganisms
TEST SYSTEM :
Bacteria - Salmonella typhimurium
DOSE/DURATION :
5 ug/plate
REFERENCE :
PCBRD2 Progress in Clinical and Biological Research. (Alan R. Liss, Inc., 41 E. 11th St., New York, NY 10003) V.1- 1975- Volume(issue)/page/year: 141,407,1984 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 84240 No. of Facilities: 836 (estimated) No. of Industries: 25 No. of Occupations: 24 No. of Employees: 15271 (estimated) No. of Female Employees: 2653 (estimated)

Safety Information

[ Symbol ]:

GHS09

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H400

[ Precautionary Statements ]:
P273

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xn:Harmful

[ Risk Phrases ]:
R22;R36

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
UN 3082 9 / PGIII

[ WGK Germany ]:
-

[ RTECS ]:
FD3500000

[ HS Code ]:
2930909090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Carbon disulphide
  • Dimethylamine
  • Dimethylamine hydrochloride
  • Thiram
  • Carbon tetrachloride
  • N,N-Dimethylacetamide
  • N,N-Dimethylformamide

DownStream

  • Carbamodithioic acid,dimethyl-, methylene ester (9CI)
  • Stibine,[(dimethylthiocarbamoyl)thio]diphenyl- (7CI,8CI)
  • 2-(dimethylcarbamothioylsulfanyl)-2-methylpropanoic acid
  • dimethylaminomethanedithioate; phenylantimony
  • Triphenylbismuth
  • 2-hydroxyethyl N,N-dimethylcarbamodithioate
  • Carbamodithioic acid,dimethyl-, 2-oxo-2-phenylethyl ester (9CI)
  • Carbamodithioicacid, dimethyl-, 2-chloro-2-propenyl ester (9CI)
  • Thiram

Customs

[ HS Code ]: 2930909090

[ Summary ]:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Related Compounds

  • sodium dimethyldithiocarbamate hydrate
  • Fuberidazole,mixted with sodium dimethyldithiocarbamate
  • Sodium dimethyldithiocarbamate mixt. with sodium 2-mercaptobenzothiazole
  • SODIUM PYROPHOSPHATE PEROXIDE
  • sodium,(Z)-4-[(2-amino-3-methylbutanoyl)amino]-3-chloro-5-hydroxy-5-oxopent-2-enoate
  • sodium lauroamphoacetate
  • (3-(methoxymethyl)piperidin-1-yl)(1-methyl-1H-1,2,3-triazol-4-yl)methanone
  • 1-(3-(1H-benzo[d]imidazol-2-yl)azetidin-1-yl)-2-(2-methoxyphenoxy)ethanone
  • N2-(sec-butyl)-5-nitropyrimidine-2,4-diamine
  • N-(4-(1H-tetrazol-1-yl)phenyl)-1-(6-(3,5-dimethyl-1H-pyrazol-1-yl)pyridazin-3-yl)piperidine-3-carboxamide
  • 2-(2-chlorophenyl)-N-(2-(6-oxo-4-phenylpyrimidin-1(6H)-yl)ethyl)acetamide
  • 2-(5-methyl-4-nitro-1H-pyrazol-1-yl)acetamide
  • 2-Bromo-5-methylphenylisothiocyanate
  • 1-Ethynyl-3-(nitromethyl)benzene
  • 4-acetyl-2-[4-(benzyloxy)phenyl]-5,6,7,8-tetrahydro-4H-[1,3]thiazolo[5,4-b]azepine
  • N~5~-(1,3-benzodioxol-5-ylmethyl)-3-(4-fluorophenyl)-5-isothiazolecarboxamide
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