1,4-Bis(p-tolylamino)anthracene-9,10-dione

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Names

[ CAS No. ]:
128-80-3

[ Name ]:
1,4-Bis(p-tolylamino)anthracene-9,10-dione

[Synonym ]:
1,4-Bis[(4-methylphenyl)amino]-9,10-anthraquinone
D and C green 6
solvent green 2
1,4-Bis(p-tolylamino)anthracene-9,10-dione
EINECS 204-909-5
greenno.202
C Green 6
GREEN 6
1,4-DI(P-TOLUIDINO)ANTHRAQUINONE
MIDORI202
Quinizarin Green SS
1,4-di-p-toluidino-anthraquinone
C-Green 10
MFCD00001195
9,10-Anthracenedione, 1,4-bis[(4-methylphenyl)amino]-
1,4-Bis[(4-methylphenyl)amino]-9,10-anthracenedione
D & C Green No. 6
1,4-Bis[(4-methylphenyl)amino]anthra-9,10-quinone
Oil Blue KS

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
633.8±55.0 °C at 760 mmHg

[ Melting Point ]:
220-221 °C

[ Molecular Formula ]:
C28H22N2O2

[ Molecular Weight ]:
418.487

[ Flash Point ]:
197.0±31.7 °C

[ Exact Mass ]:
418.168121

[ PSA ]:
58.20000

[ LogP ]:
5.41

[ Vapour Pressure ]:
0.0±1.9 mmHg at 25°C

[ Index of Refraction ]:
1.714

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
CB5775000
CHEMICAL NAME :
Anthraquinone, 1,4-bis(p-tolylamino)-
CAS REGISTRY NUMBER :
128-80-3
BEILSTEIN REFERENCE NO. :
2227927
LAST UPDATED :
199701
DATA ITEMS CITED :
6
MOLECULAR FORMULA :
C28-H22-N2-O2
MOLECULAR WEIGHT :
418.52
WISWESSER LINE NOTATION :
L C666 BV IVJ DMR D1& GMR D1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1330,1986 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
3660 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1330,1986
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intratracheal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
250 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1330,1986 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - M3850 No. of Facilities: 112 (estimated) No. of Industries: 6 No. of Occupations: 13 No. of Employees: 1596 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - M3850 No. of Facilities: 1631 (estimated) No. of Industries: 15 No. of Occupations: 33 No. of Employees: 55064 (estimated) No. of Female Employees: 41703 (estimated)

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S24/25-S22-S26

[ RIDADR ]:
NONH for all modes of transport

[ RTECS ]:
CB5775000

[ HS Code ]:
3204120000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Quinizarin
  • p-Toluidine
  • 1-bromo-4-methoxy-anthraquinone
  • 1,4-Anthracenedione,2,3-dihydro-9,10-dihydroxy-
  • 1-Methoxyanthraquinone
  • Chloroanthraquinone
  • 1,4-Dichloro-9,10-anthraquinone
  • 1,4-Diaminoanthraquinone
  • 1-methoxy-4-nitro-anthraquinone

DownStream

  • 2,2'-[(9,10-Dihydro-9,10-dioxo-1,4-anthracenediyl)diimino]bis[5-methylbenzenesulfonic acid]

Customs

[ HS Code ]: 2922399090

[ Summary ]:
2922399090 other amino-aldehydes, amino-ketones and amino-quinones, other than those containing more than one kind of oxygen function; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

[Cytotoxicity of chemicals used in household products: 1997- 2004].

Kokuritsu Iyakuhin Shokuhin Eisei Kenkyusho. Hokoku. (123) , 53-6, (2005)

The cytotoxicities of chemicals used in household products were evaluated using a neutral red (NR) uptake assay. The chemicals tested during 1997-2004 were rubber additives (accelerators, antioxidants...

The inhalation toxicity of two commercial dyes: solvent yellow 33 and solvent green 3.

Fundam. Appl. Toxicol. 8(3) , 358-71, (1987)

The quinoline dye 2-(2'-quinolyl)-1,3-indandione or Solvent Yellow 33 (SY) and the anthraquinone dye 1,4-di-p-toluidinoanthraquinone or Solvent Green 3 (SG) are used in many manufactured products incl...

Liquid chromatographic separations of basic compounds.

Adv. Chromatogr. 46 , 305-50, (2008)


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Related Compounds

  • 1,4-Bis(p-cyclohexylanilino)anthraquinone
  • 1-((2-phenylpropan-2-yl)amino)-4-(p-tolylamino)anthracene-9,10-dione
  • 1,4-bis(4-methylphenyl)anthracene-9,10-dione
  • 1,4-bis(4-dodecylanilino)anthracene-9,10-dione
  • 1,4-bis(2-methylpropylamino)anthracene-9,10-dione
  • 1,4-bis(4-hydroxyanilino)anthracene-9,10-dione
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