4'-Chloro-2,2':6',2''-terpyridine

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Names

[ Name ]:
4'-Chloro-2,2':6',2''-terpyridine

[Synonym ]:
4'-Chloro-2,2':6',2''-terpyridine
2,2':6',2''-Terpyridine, 4'-chloro-
4‘-Chloro-2,2‘:6‘,2‘‘-terpyridine
4′-Chloro-2,2′﹕6′,2′′-terpyridine
4-chloro-2,6-dipyridin-2-ylpyridine
MFCD00191930

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
421.4±40.0 °C at 760 mmHg

[ Melting Point ]:
148 - 150ºC

[ Molecular Formula ]:
C₁₅H₁₀ClN₃

[ Molecular Weight ]:
267.713

[ Flash Point ]:
241.2±12.9 °C

[ Exact Mass ]:
267.056335

[ PSA ]:
38.67000

[ LogP ]:
2.52

[ Vapour Pressure ]:
0.0±1.0 mmHg at 25°C

[ Index of Refraction ]:
1.623

[ Storage condition ]:
2~8 ℃

[ Water Solubility ]:
Slightly soluble in water.

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05, GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301-H315-H318-H335

[ Precautionary Statements ]:
P261-P280-P301 + P310-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R22

[ Safety Phrases ]:
S26-S39

[ RIDADR ]:
UN 2811 6.1 / PGIII

[ WGK Germany ]:
3

[ HS Code ]:
2933399090

Synthetic Route

Click to get detail synthetic route

Customs

[ HS Code ]: 2933399090

[ Summary ]:
2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

4'-Chloro-2, 2': 6', 2''-terpyridine. Beves JE, et al.

Acta Crystallogr. Sect. E Struct. Rep. Online 62(6) , o2497-o2498, (2006)

Access to supramolecular polymers: Large scale synthesis of 4'-chloro-2, 2': 6', 2''-terpyridine and an application to poly (propylene oxide) telechelics. Schubert US, et al.

Des. Monomers Polym. 5(2-3) , 211-21, (2002)

4'-Functionalized 2, 2': 6', 2 ?-terpyridines as building blocks for supramolecular chemistry and nanoscience. Schubert US, et al.

Tetrahedron Lett. 42(28) , 4705-7, (2001)

4-[2-[6-[4-(2,6-dimethyl-4-oxocyclohexa-2,5-dien-1-ylidene)-1H-pyridin-2-yl]pyridin-2-yl]-1H-pyridin-4-ylidene]-3,5-dimethylcyclohexa-2,5-dien-1-one
2,6-dipyridin-2-ylpyridine; platinum(+2) cation; chloride
4-[6-[6-[5-(4-hydroxy-2,6-dimethylphenyl)pyridin-2-yl]-1H-pyridin-2-ylidene]pyridin-3-ylidene]-3,5-dimethylcyclohexa-2,5-dien-1-one
4'-iodo-2,2':6',2''-terpyridine
4'-nitro-2,2':6',2''-terpyridine
4'-TRIFLUOROMETHYLSULFONO-2,2':6',2''-TERPYRIDINE