(6-BROMOHEXYLOXY)-TERT-BUTYLDIMETHYL-

Names

[ Name ]:
(6-BROMOHEXYLOXY)-TERT-BUTYLDIMETHYL-

[Synonym ]:
1-t-butyldimethylsilyloxy-6-bromohexane
MFCD01863708
6-bromo-1-hexanol tert-butyldimethylsilyl ether
6-bromohexyl t-butyldimethylsilyl ether

Chemical & Physical Properties

[ Density]:
1.053 g/mL at 25ºC(lit.)

[ Boiling Point ]:
276ºC(lit.)

[ Molecular Formula ]:
C₁₂H₂₇BrOSi

[ Molecular Weight ]:
295.33200

[ Flash Point ]:
>230 °F

[ Exact Mass ]:
294.10100

[ PSA ]:
9.23000

[ LogP ]:
4.96350

[ Vapour Pressure ]:
0.00728mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.4565(lit.)

MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;half-mask respirator (US);multi-purpose combination respirator cartridge (US)

[ Hazard Codes ]:
Xn

[ RIDADR ]:
NONH for all modes of transport

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

6-bromohexanol
tert-Butyldimethylsilyl chloride
Imidazole
O-6-(tert-butyldimethylsiloxy)hexyl dimethylcarbamothioate
6-Bromohexanoic acid
Hexan-1,6-diol
2-(6-Bromohexyloxy)tetrahydropyran
tert-Butyldimethylsilyl Trifluoromethanesulfonate
6-bromo-1-tert-amyloxy-hexane

DownStream

tert-butyl-(6-iodohexoxy)-dimethylsilane
(2E,13Z)-2,13-octadecadien-1-ol
2-undec-2-ynoxyoxane

Articles

Novel lepidopteran sex pheromone components from Marmara gulosa (Lepidoptera: Gracillariidae).

J. Econ. Entomol. 102(2) , 574-84, (2009)

Marmara gulosa Guillén & Davis (Lepidoptera: Gracillariidae) is a sporadic pest of citrus and a number of other crops in southern and central California. Coupled gas chromatographic-electroantennogram...

6,6'-Dimethyl-2,2'-bipyridine-4-ester: A pivotal synthon for building tethered bipyridine ligands. Havas F, et al.

Tetrahedron 65(36) , 7673-7686, (2009)

6-(tert-butyldimethyl)siloxyhexanoic benzyl ester
(3S,4S)-6-{[(tert-butyldimethyl)silyl]oxy}-4-hydroxy-3-methylhex-1-ene
6-tert-butyl-6-phenyl-6H-dibenzo[c,e][1,2]oxasiline
6-tert-butyl-2-ethenyl-1-oxaspiro[2.5]octane
6-tert-Butyl-m-cresol
6-tert-butyl-3-methyl-2-propan-2-ylpyrimidin-4-one
8-(4-aminonaphthalen-1-yloxy)pyrido[2,3-b]pyrazin-3(4H)-one
N-(cyanomethyl)-1,2,3,4-tetrahydronaphthalene-1-carboxamide
(E)-4-(6-Methoxy-2-(3-nitrostyryl)-4-oxoquinazolin-3(4H)-yl)-benzonitrile
(11I(2),17I(2))-11-[9-[(4,4,5,5,5-Pentafluoropentyl)sulfinyl]nonyl]estra-1,3,5(10)-triene-3,17-diol
5-(2,2-Dimethylmorpholino)pyridin-2-amine
6-(4-(3-chloro-4-fluorophenyl)piperazine-1-carbonyl)-2-methylpyridazin-3(2H)-one
N-(1-methoxypropan-2-yl)-3,3,5-trimethylcyclohexan-1-amine
N-(2,4-difluorophenyl)-1-(3-fluorobenzyl)-6-oxo-1,6-dihydropyridazine-3-carboxamide
1-(3-fluorobenzyl)-6-oxo-N-(thiazol-2-yl)-1,6-dihydropyridazine-3-carboxamide
1-(3-fluorobenzyl)-6-oxo-N-(4-(trifluoromethoxy)phenyl)-1,6-dihydropyridazine-3-carboxamide

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