(+)-1,2-bis((2r,5r)-2,5-dimethylphospholano)ethane

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Names

[ CAS No. ]:
129648-07-3

[ Name ]:
(+)-1,2-bis((2r,5r)-2,5-dimethylphospholano)ethane

[Synonym ]:
MFCD01073770
(R,R)-Me-BPE

Chemical & Physical Properties

[ Density]:
0.940 g/mL at 25ºC

[ Boiling Point ]:
64-67ºC 0.06 mm Hg

[ Molecular Formula ]:
C14H28P2

[ Molecular Weight ]:
258.32000

[ Flash Point ]:
162.1ºC

[ Exact Mass ]:
258.16700

[ PSA ]:
27.18000

[ LogP ]:
5.09180

[ Vapour Pressure ]:
0.000285mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.534

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H250-H413

[ Precautionary Statements ]:
P222-P231-P422

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F: Flammable;

[ Risk Phrases ]:
R11

[ Safety Phrases ]:
24/25

[ RIDADR ]:
UN 2845 4.2/PG 1

[ WGK Germany ]:
3

[ HS Code ]:
29310099

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • (2S,5S)-(+)-HEXANEDIOL
  • 1,2-bis(tosyloxy)ethane

DownStream

Related Compounds

  • (+)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)ethane(cyclooctadiene)rhodium(I)trifluoromethanesulfonate
  • 1,2-Bis((2R,5R)-2,5-dimethylphospholano)ethane(cyclooctadiene)rhodium(I) trifluoromethanesulfonate
  • (1Z,5Z)-cycloocta-1,5-diene,(2R,5R)-1-[2-[(2R,5R)-2,5-dimethylphospholan-1-yl]ethyl]-2,5-dimethylphospholane,rhodium,tetrafluoroborate
  • (+)-1,2-bis-((2R,5R)-2,5-Diethylphospholano)ethane
  • (+)-1,2-BIS((2R,5R)-2,5-DI-I-PROPYLPHOSPHOLANO)BENZENE)1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE
  • 1,2-DIAMINO-4-(TRIFLUOROMETHOXY)BENZENE
  • 1-(4-chloro-2-fluorophenyl)-5-methyl-1H-1,2,3-triazole-4-carboxylic acid
  • 2-((2-chloro-6-fluorobenzyl)thio)-N,3-diisobutyl-4-oxo-3,4-dihydroquinazoline-7-carboxamide
  • N,3-diisobutyl-2-((4-nitrobenzyl)thio)-4-oxo-3,4-dihydroquinazoline-7-carboxamide
  • 2-((2-chloro-4-fluorobenzyl)thio)-N,3-diisobutyl-4-oxo-3,4-dihydroquinazoline-7-carboxamide
  • 2-((2,5-dimethylbenzyl)thio)-N,3-diisobutyl-4-oxo-3,4-dihydroquinazoline-7-carboxamide
  • N,3-diisobutyl-4-oxo-2-((4-vinylbenzyl)thio)-3,4-dihydroquinazoline-7-carboxamide
  • 3-(4-bromophenyl)-4,5-dihydroxyfuran-2(3H)-one
  • Tert-butyl (8-methyl-8-azabicyclo[3.2.1]octan-3-yl)carbamate
  • 2-[2-(diethylamino)-5,7-dioxo-6-(prop-2-en-1-yl)-4H,5H,6H,7H-[1,3]thiazolo[4,5-d]pyrimidin-4-yl]-N-(2,6-dimethylphenyl)acetamide
  • 2-(8-methoxy-10-oxo-3,4-dihydrobenzo[b][1,6]naphthyridin-2(1H,5H,10H)-yl)-N-(m-tolyl)acetamide
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