(+)-1,2-bis((2r,5r)-2,5-dimethylphospholano)ethane

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Names

[ CAS No. ]:
129648-07-3

[ Name ]:
(+)-1,2-bis((2r,5r)-2,5-dimethylphospholano)ethane

[Synonym ]:
MFCD01073770
(R,R)-Me-BPE

Chemical & Physical Properties

[ Density]:
0.940 g/mL at 25ºC

[ Boiling Point ]:
64-67ºC 0.06 mm Hg

[ Molecular Formula ]:
C14H28P2

[ Molecular Weight ]:
258.32000

[ Flash Point ]:
162.1ºC

[ Exact Mass ]:
258.16700

[ PSA ]:
27.18000

[ LogP ]:
5.09180

[ Vapour Pressure ]:
0.000285mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.534

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H250-H413

[ Precautionary Statements ]:
P222-P231-P422

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F: Flammable;

[ Risk Phrases ]:
R11

[ Safety Phrases ]:
24/25

[ RIDADR ]:
UN 2845 4.2/PG 1

[ WGK Germany ]:
3

[ HS Code ]:
29310099

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • (2S,5S)-(+)-HEXANEDIOL
  • 1,2-bis(tosyloxy)ethane

DownStream

Related Compounds

  • (+)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)ethane(cyclooctadiene)rhodium(I)trifluoromethanesulfonate
  • 1,2-Bis((2R,5R)-2,5-dimethylphospholano)ethane(cyclooctadiene)rhodium(I) trifluoromethanesulfonate
  • (1Z,5Z)-cycloocta-1,5-diene,(2R,5R)-1-[2-[(2R,5R)-2,5-dimethylphospholan-1-yl]ethyl]-2,5-dimethylphospholane,rhodium,tetrafluoroborate
  • (+)-1,2-bis-((2R,5R)-2,5-Diethylphospholano)ethane
  • (+)-1,2-BIS((2R,5R)-2,5-DI-I-PROPYLPHOSPHOLANO)BENZENE)1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE
  • 1,2-DIAMINO-4-(TRIFLUOROMETHOXY)BENZENE
  • 1-[2-(3-Fluorophenoxy)ethyl]cyclopropan-1-amine
  • 4-(2,5-Dimethoxyphenyl)but-3-en-2-amine
  • 2,2-Dimethyl-2-[(1-phenylethyl)carbamoyl]acetic acid
  • 3-Chloro-4-hydroxybenzene-1-sulfonyl fluoride
  • 4-(4-(Aminomethyl)thiazol-2-yl)-2-methoxyaniline
  • N-(Phenylmethyl)-L-norvaline ethyl ester
  • 2-(3-Bromo-2,4-difluorophenyl)ethan-1-amine
  • 3,6-Difluoro-2-methoxyphenylacetonitrile
  • 5-Chloro-2-fluoro-3-methylphenylacetonitrile
  • 4-bromo-3-(4-methoxyphenyl)-5-methyl-1H-pyrazole
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