Bis(triphenylphosphine)dicarbonylnickel

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Names

[ CAS No. ]:
13007-90-4

[ Name ]:
Bis(triphenylphosphine)dicarbonylnickel

[Synonym ]:
Bis(triphenylphosphine)dicarbonylnickel
EINECS 235-851-9
MFCD00009591

Chemical & Physical Properties

[ Density]:
1.09

[ Melting Point ]:
206-209ºC(lit.)

[ Molecular Formula ]:
C38H30NiO2P2

[ Molecular Weight ]:
639.28500

[ Exact Mass ]:
638.10700

[ PSA ]:
27.18000

[ LogP ]:
6.47360

[ Storage condition ]:
0-6°C

MSDS

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Safety Information

[ Symbol ]:

GHS07, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H317-H350

[ Precautionary Statements ]:
P201-P280-P308 + P313

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;Gloves;type P2 (EN 143) respirator cartridges

[ Hazard Codes ]:
T: Toxic;

[ Risk Phrases ]:
R45

[ Safety Phrases ]:
53-22-36/37-45

[ RIDADR ]:
UN 3281

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
6.1

Synthetic Route

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Precursor & DownStream

Precursor

  • Triphenylphosphine
  • nickel carbonyl
  • ethoxymethanedithioic acid
  • [tricarbonyl(triphenylphosphine)nickel]
  • Bis(triphenylphosphine)nickel(II)chloride
  • Zinc
  • pentacarbonyliron
  • Nickel-triphenylphosphine (1:4)

DownStream

  • 5-Azido Oseltamivir
  • Bis(triphenylphosphine)nickel(II)chloride
  • Carbon dioxide
  • carbon monoxide
  • Hydrogen
  • Nickel
  • Nickel(II) oxide
  • [tricarbonyl(triphenylphosphine)nickel]

Related Compounds

  • Bis(triphenylphosphine)iminium trifluoroacetate
  • {bis(triphenylphosphine)nitrogen}{cis-HW(CO)4P(OMe)3}
  • bis(triphenylphosphine)chloro(4,4-diphenyl-1-(triethylgermyl)-1,2,3-butatriene)rhodium
  • [bis(triphenylphosphine)nitrogen][W(CO)5(SH)]
  • bis(triphenylphosphine)chloro(4,4-diphenyl-1-(triethylstannyl)-1,2,3-butatriene)rhodium
  • {bis(triphenylphosphine)(phenyldihiocarboxylato)copper(I)}