H-Glu-Obzl

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Names

[ CAS No. ]:
13030-09-6

[ Name ]:
H-Glu-Obzl

[Synonym ]:
H-Glu(OBzl)-OH
L-Glutamic acid γ-benzyl ester
L-Glutamic acid γ-benzyl ester
Glutamic acid, 5-benzyl ester, L-
L-Glutamic acid 1-Benzyl Ester
L-Glutamic acid, 5-(phenylmethyl) ester
(S)-4-Amino-5-(benzyloxy)-5-oxopentanoic acid
MFCD00037312
1-Benzyl L-glutamate
L-Glutamic acid alpha-benzyl ester
(2S)-2-Amino-5-(benzyloxy)-5-oxopentanoic acid
L-Glutamic acid α-benzyl ester
L-Glutamic acid, 5- (phenylmethyl) ester
L-Glutamic acid alpha-benzyl ester
H-Glu-Obzl
L-Glutamic acid alpha-benzylester

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
426.1±45.0 °C at 760 mmHg

[ Melting Point ]:
157 °C

[ Molecular Formula ]:
C12H15NO4

[ Molecular Weight ]:
237.252

[ Flash Point ]:
211.5±28.7 °C

[ Exact Mass ]:
237.100113

[ PSA ]:
89.62000

[ LogP ]:
1.56

[ Vapour Pressure ]:
0.0±1.1 mmHg at 25°C

[ Index of Refraction ]:
1.555

[ Storage condition ]:
-15°C

MSDS

Safety Information

[ Hazard Codes ]:
Xn,T

[ Risk Phrases ]:
R36/37/38:Irritating to eyes, respiratory system and skin . R42:May cause sensitization by inhalation. R42/43:May cause sensitization by inhalation and skin contact . R23/24/25:Toxic by inhalation, in contact with skin and if swallowed .

[ Safety Phrases ]:
S22-S26-S36-S45-S36/37/39

[ RIDADR ]:
UN 2811 6.1/PG 2

[ WGK Germany ]:
3

[ RTECS ]:
NX9500000

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1

[ HS Code ]:
2922509090

Synthetic Route

Precursor & DownStream

Precursor

  • L-glutamic acid
  • Benzyl alcohol
  • H-Glu(OBzl)-OBzl
  • (4S)-5-oxo-5-phenylmethoxy-4-(tritylamino)pentanoate
  • dibenzyl N-trityl-(S)-glutamate
  • Z-Glu-OBzl

DownStream

  • Z-Glu-OBzl
  • Boc-L-glutamic acid 1-benzyl ester
  • H-Glu(OtBu)-OH
  • H-Glu(Ala-OH)-OH
  • H-Glu(Glu-OH)-OH
  • L-Aspartic acid,N-[4-[[(2,4-diamino-6-pteridinyl)methyl]methylamino]benzoyl]-L-g-glutamyl- (9CI)
  • L-Glutamine,N2-[4-[[(2,4-diamino-6-pteridinyl)methyl]methylamino]benzoyl]-N-pentyl-
  • L-Glutamine, N2-[4-[[(2,4-diamino-6-pteridinyl)methyl]methylamino]benzoyl]-N,N-dimethyl
  • L-Glutamine, N(2)-[4-[[(2, 4-diamino-6-pteridinyl)methyl]methylamino]benzoyl]-N-(phenylmethyl )-
  • Glycine, N-[N-[4-[[(2, 4-diamino-6-pteridinyl)methyl]methylamino]benzoyl]-L-.gamma.-gluta myl]-

Customs

[ HS Code ]: 2922509090

[ Summary ]:
2922509090. other amino-alcohol-phenols, amino-acid-phenols and other amino-compounds with oxygen function. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%


Related Compounds

  • H-Glu-OBzl.HCl
  • H-Glu(OBzl)-OBzl
  • H-Glu(OBzl)-Val-Tyr-N2H2Boc*TFA
  • H-Glu(OBzl)-Val-Tyr-OBut*TFA
  • H-Glu(OBzl)-OBzl.TosOH
  • H-Glu(OBzl)-Val-Tyr-N2H2Boc
  • tert-butyl 4-{3-ethynyl-5-[({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)methyl]-2,6-dimethylphenyl}piperazine-1-carboxylate
  • tert-butyl 4-{[3-ethynyl-5-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-2,4-dimethylphenyl]methyl}piperazine-1-carboxylate
  • (9H-fluoren-9-yl)methyl 4-[(5-{[(tert-butoxy)carbonyl]amino}-3-ethynyl-2,4-dimethylphenyl)methyl]piperazine-1-carboxylate
  • 3-{4-[(Tert-butoxy)carbonyl]piperazin-1-yl}-5-[(fluorosulfonyl)oxy]-4-methylbenzoic acid
  • tert-butyl 3-[(2S)-2-hydroxypropyl]piperidine-1-carboxylate
  • Tert-butyl 4-({4-methyl-3-sulfanyl-5-[2-(trimethylsilyl)ethynyl]phenyl}methyl)piperazine-1-carboxylate
  • Tert-butyl 4-({2-methyl-3-sulfanyl-5-[2-(trimethylsilyl)ethynyl]phenyl}methyl)piperazine-1-carboxylate
  • 2-[3-({[2-(Tert-butoxy)-2-oxoethyl]amino}methyl)-5-iodo-4-methylphenyl]acetic acid
  • Methyl 5-({[2-(tert-butoxy)-2-oxoethyl]amino}methyl)-3-iodo-2-methylbenzoate
  • Methyl 3-({[2-(tert-butoxy)-2-oxoethyl]amino}methyl)-5-iodo-2-methylbenzoate
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