Dimethyl 5-hydroxyisophthalate

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Names

[ CAS No. ]:
13036-02-7

[ Name ]:
Dimethyl 5-hydroxyisophthalate

[Synonym ]:
Dimethyl-5-hydroxybenzol-1,3-dicarboxylat
MFCD00134367
Dimethyl 5-hydroxyisophthalate
EINECS 235-899-0
1,3-Benzenedicarboxylic acid, 5-hydroxy-, dimethyl ester
5-Hydroxyisophthalic Acid Dimethyl Ester
Dimethyl 5-hydroxybenzene-1,3-dicarboxylate

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
360.6±22.0 °C at 760 mmHg

[ Melting Point ]:
162-164 °C(lit.)

[ Molecular Formula ]:
C10H10O5

[ Molecular Weight ]:
210.183

[ Flash Point ]:
143.3±15.8 °C

[ Exact Mass ]:
210.052826

[ PSA ]:
72.83000

[ LogP ]:
2.57

[ Vapour Pressure ]:
0.0±0.8 mmHg at 25°C

[ Index of Refraction ]:
1.544

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2918199090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Methanol
  • 5-Hydroxyisophthalic acid
  • (Trimethylsilyl)diazomethane
  • methyl iodide
  • Di-tert-butyl dicarbonate
  • Boc-NH-PEG1-OH
  • dead
  • 4-hydroxypyridine-2,6-dicarboxylic acid
  • 5-hydroxy-1,3-Benzenedicarbonyl dichloride

DownStream

  • 3,5-Bis(trifluoromethyl)anisole
  • 5-Methoxyisophthalic acid
  • Methyl 5-methoxy-isophthalate
  • 2-Methoxy-4,6-bis(trifluoromethyl)benzoic acid
  • methyl 3-hydroxy-5-(hydroxymethyl)benzoate
  • 5-Hydroxyisophthalic acid
  • 5-hydroxyisophthalamide
  • dimethyl 5,5-difluorocyclohexane-1,3-dicarboxylate
  • METHYL 4-[3,5-BIS(METHOXYCARBONYL)PHENOXY]-3-AMINOBENZOATE
  • METHYL-3-NITRO-4-(3,5-DICARBOXYMETHYL-PHENOXY)-BENZOATE

Customs

[ HS Code ]: 2918199090

[ Summary ]:
2918199090 other carboxylic acids with alcohol function but without other oxygen function, their anhydrides, halides, peroxides, peroxyacids and their derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

Articles

Amphiphilic diblock dendrimers: synthesis and incorporation in Langmuir and Langmuir-Blodgett films.

J. Am. Chem. Soc. 123(40) , 9743-8, (2001)

A new dendron with peripheral long alkyl chains and containing five C(60) units in the branching shell has been prepared and attached to a Fréchet-type dendron functionalized with ethylene glycol chai...

Synthesis of 5-Substituted Derivatives of Isophthalic Acid as Non-Polymeric Amphiphilic Coating for Metal Oxide Nanoparticles.

Tetrahedron Lett. 55(36) , 5078-5081, (2014)

In the course of development of novel capping ligands with variable steric factor, which will be used as an organic coating for metal oxide nanoparticles, a base-catalyzed nucleophilic oxirane ring-op...

Solid-phase synthesis and acidolytic degradation of sterically congested oligoether dendrons.

Org. Biomol. Chem. 10(24) , 4788-94, (2012)

Up to third-generation sterically crowded polyether dendrons were prepared on a solid support, using a novel building block derived from dimethyl 5-hydroxyisophthalate via O-allylation/Claisen rearran...


More Articles

Related Compounds

  • dimethyl 5-hydroxyisophthalate propargyl ether
  • Dimethyl 5-Chloromethyl-1,3-Benzene-Dicarboxylate
  • Dimethyl-5-(3-nitro-4-chloroanylinsulphonic)izophthalate
  • dimethyl-[(5-nitro-2-furyl)methyl]-[4-(2,4,6-tribromophenoxy)butyl]azanium
  • dimethyl 5-[amino(phenyl)methylidene]-4-oxohex-2-enedioate
  • dimethyl 5-[(5-nitrofuran-2-carbonyl)amino]benzene-1,3-dicarboxylate