1-fluoro-2,6-dichloropyridinium triflate

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Names

[ CAS No. ]:
130433-68-0

[ Name ]:
1-fluoro-2,6-dichloropyridinium triflate

[Synonym ]:
2,6-Dichloro-1-fluoropyridinium trifluoromethanesulfonate
2,6-Dichloro-1-fluoropyridinium Triflate
MFCD00191438
N-Fluoro-2,6-dichloropyridinium triflate
2,6-dichloro-1-fluoropyridin-1-ium,trifluoromethanesulfonate
1-FLUORO-2,6-DICHLOROPYRIDINIUM TRIFLATE
2,6-Dichloro-1-fluoropyridin-1-ium trifluoromethanesulfonate

Chemical & Physical Properties

[ Density]:
1.46g/cm3

[ Boiling Point ]:
100ºC at 760mmHg

[ Melting Point ]:
176-182 °C

[ Molecular Formula ]:
C6H3Cl2F4NO3S

[ Molecular Weight ]:
316.057

[ Flash Point ]:
15ºC

[ Exact Mass ]:
314.914673

[ PSA ]:
69.46000

[ LogP ]:
3.14570

[ Storage condition ]:
Refrigerator

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Hazard Codes ]:
C: Corrosive;

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S45-S36/37/39-S26

[ RIDADR ]:
UN 3261 8 / PGII

[ HS Code ]:
2933399090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 2,6-Dichloropyridine
  • Trifluoromethanesulfonic acid

DownStream

  • 2,6-Dichloro-4-pyridinol
  • N-Fluoro-6-chloro-2-pyridone

Customs

[ HS Code ]: 2933399090

[ Summary ]:
2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

1-Fluoropyridinium triflates: versatile reagents for transformation of thioglycoside into O-glycoside, glycosyl azide and sulfoxide Tsukamoto, H.; et al.

Tetrahedron Lett. 28th ed., 44 , 5247-5249, (2003)

Electrolytic partial fluorination of organic compounds. Part 62. Highly diastereoselective anodic fluorination of chiral 1,3-oxathiolan-5-ones derived from camphorsulfonamides Baba, D.; et al.

J. Fluor. Chem. 1st ed., 121 , 93-96, (2003)

Electrolytic partial fluorination of organic compound. Part: 53 Highly regioselective anodic mono- and difluorination of 4-arylthio-1,3-dioxolan-2-ones. A marked solvent effect on fluorinated product selectivity Ishii, H.; et al.

Tetrahedron 44th ed., 57 , 9067-9072, (2001)


More Articles

Related Compounds

  • 2,6-Dichloro-1-fluoropyridinium tetrafluoroborate
  • 1-Fluoro-2,6-bis(methoxycarbonyl)pyridin-1-ium trifluoromethanesulfonate
  • 5-tert-butyl-2-fluoro-1,3-dimethylbenzene
  • 2-fluoro-1,3-dinitrobenzene
  • 2-Fluoro-1,3-dimethyl-5-nitrobenzene
  • 1-Fluoro-2,4,6-trimethylpyridinium Trifluoromethanesulfonate [Fluorinating Reagent]
  • 4,4-Dimethyl-1-propylcyclohex-2-en-1-ol
  • rac-1-[(3R,4S)-4-hydroxypyrrolidin-3-yl]ethan-1-one
  • 2-Amino-4,4-difluoro-1-methylcyclohexan-1-ol
  • (3-Methyloxetan-3-yl)methyl chloroformate
  • 4-Amino-2,3-dimethyl-1-(oxolan-2-yl)butan-2-ol
  • 3-[amino(1-methyl-1H-1,2,4-triazol-3-yl)methyl]-8-azabicyclo[3.2.1]octan-3-ol
  • {1-[(2-bromophenyl)methyl]-5-cyclopropyl-1H-1,2,3-triazol-4-yl}methanol
  • 4-Amino-2,3-dimethyl-1-(pyrrolidin-2-yl)butan-2-ol
  • 4-Amino-1-(4-bromophenyl)cyclohexan-1-ol
  • Methyl 2-(3-aminooxetan-3-yl)propanoate
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