iodo(methoxy)methane

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Names

[ CAS No. ]:
13057-19-7

[ Name ]:
iodo(methoxy)methane

[Synonym ]:
methoxymethyl iodide
MFCD00134516
2-iodomethyl methyl ether
Methane,iodomethoxy
iodomethylmethyl ether

Chemical & Physical Properties

[ Density]:
1.982g/cm3

[ Boiling Point ]:
123ºC at 760mmHg

[ Molecular Formula ]:
C2H5IO

[ Molecular Weight ]:
171.96500

[ Flash Point ]:
22.2ºC

[ Exact Mass ]:
171.93900

[ PSA ]:
9.23000

[ LogP ]:
1.02530

[ Vapour Pressure ]:
16.4mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.546(lit.)

Safety Information

[ Symbol ]:

GHS02, GHS05, GHS06, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H301 + H311 + H331-H314-H351

[ Precautionary Statements ]:
P210-P261-P280-P301 + P310-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
T: Toxic;

[ Risk Phrases ]:
10-23/24/25-34-40

[ Safety Phrases ]:
16-26-36/37/39-45

[ RIDADR ]:
UN 3286 3/PG 2

[ Packaging Group ]:
II

[ Hazard Class ]:
3.1

[ HS Code ]:
2909199090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • dimethoxymethane
  • Chloromethyl methyl ether
  • Methanol
  • Formaldehyde
  • methoxymethyl benzenesulfenate

DownStream

  • methyl iodide
  • Diethyl (Methoxymethyl)phosphonate
  • dimethyl ethylphosphonite
  • O-ethyl(methyl)diethoxymethyl phosphinate
  • O-ethyl bis(diethoxymethyl)phosphinate
  • 1-chloro-2-(methoxymethyl)benzene
  • 2-(methoxymethyl)-1,3,5-trimethyl-benzene

Customs

[ HS Code ]: 2909199090

[ Summary ]:
2909199090. other acyclic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

Articles

Microwave spectrum and nuclear quadrupole coupling constant tensor of iodomethyl methyl ether. Fujitake M and Hayashi M.

J. Mol. Spectrosc. 128(2) , 444-55, (1988)

Iodomethyl Methyl Ether Jung ME, et al.

e-EROS Encyclopedia of Reagents for Organic Synthesis. , (2007)

The carbon-hydrogen bond strength in dimethyl ether and some properties of iodomethyl methyl ether. Cruickshank FR and Benson SW.

Int. J. Chem. Kinet. 1(4) , 381-90, (1969)


More Articles

Related Compounds

  • trideuterio(methoxy)methane
  • dichlorophosphoryl(methoxy)methane
  • fluoro(methoxy)methane
  • Bromo(methoxy)methane
  • isocyanato(methoxy)methane
  • hydroperoxy(methoxy)methane
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 6-Phenyl-9H-pyrido[3,4-b]indole
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • 1-(7-(2-Chlorophenyl)-1,1-dioxido-1,4-thiazepan-4-yl)-2-(2-methylthiazol-5-yl)ethanone
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine