Methylboronic acid
Suppliers
Names
[ CAS No. ]:
13061-96-6
[ Name ]:
Methylboronic acid
[Synonym ]:
methyl-boronic acid
Methylboronic acid
methaneboronic acid
UNII-8Z1ME41SCH
MFCD00002105
Boronic acid, B-methyl-
Dihydroxymethylborane
Methyl boronic acid
Chemical & Physical Properties
[ Density]:
1.0±0.1 g/cm3
[ Boiling Point ]:
141.7±23.0 °C at 760 mmHg
[ Melting Point ]:
91-94 °C(lit.)
[ Molecular Formula ]:
CH5BO2
[ Molecular Weight ]:
59.86
[ Flash Point ]:
39.5±22.6 °C
[ Exact Mass ]:
60.038261
[ PSA ]:
40.46000
[ LogP ]:
-0.16
[ Vapour Pressure ]:
2.4±0.6 mmHg at 25°C
[ Index of Refraction ]:
1.345
MSDS
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H315-H319-H335
[ Precautionary Statements ]:
P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves
[ Hazard Codes ]:
Xi:Irritant;
[ Risk Phrases ]:
R36/37/38
[ Safety Phrases ]:
S26-S36
[ RIDADR ]:
NONH for all modes of transport
[ WGK Germany ]:
3
[ HS Code ]:
2931900090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2931900090
[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%
Articles
Nucl. Med. Biol. 41(10) , 813-24, (2014)
(99m)Tc-Teboroxime ([(99m)TcCl(CDO)(CDOH)2BMe]) is a member of the BATO (boronic acid adducts of technetium dioximes) class of (99m)Tc(III) complexes. This study sought to explore the impact of co-lig...
J. Am. Chem. Soc. 44th ed., 132 , 15474-15476, (2010)
A novel amino-thiocarbamate-catalyzed bromolactonization of unsaturated carboxylic acids has been developed. The scope of the reaction is evidenced by 22 examples of γ-lactones with up to 99% yield an...
J. Am. Chem. Soc. 133 , 9164-9167, (2011)
A facile and efficient enantioselective bromoaminocyclization of unsaturated sulfonamides has been developed using an amino-thiocarbamate catalyst. A range of enantioenriched pyrrolidines were prepare...