2-Methyl-5-nitroanisole

Suppliers

Names

[ CAS No. ]:
13120-77-9

[ Name ]:
2-Methyl-5-nitroanisole

[Synonym ]:
1-Methoxy-2-methyl-5-nitrobenzene
2-Methyl-5-nitroanisole
Methyl 2-methyl-5-nitrophenyl ether
2-Methoxy-4-nitrotoluene
Anisole, 2-methyl-5-nitro-
Benzene, 2-methoxy-1-methyl-4-nitro-
EINECS 236-048-6
2-Methoxy-1-methyl-4-nitrobenzene
MFCD00043912

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
281.2±20.0 °C at 760 mmHg

[ Melting Point ]:
69-71 °C(lit.)

[ Molecular Formula ]:
C8H9NO3

[ Molecular Weight ]:
167.162

[ Flash Point ]:
135.5±23.8 °C

[ Exact Mass ]:
167.058243

[ PSA ]:
55.05000

[ LogP ]:
2.63

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.538

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H319

[ Precautionary Statements ]:
P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R22

[ Safety Phrases ]:
S24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2909309090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 2-Methyl-5-nitrophenol
  • methyl iodide
  • 4-Methoxy-5-methyl-2-nitroaniline
  • 4'-methoxy-3'-methylacetanilide
  • acetic acid-(4-methoxy-5-methyl-2-nitro-anilide)
  • Methyl p-toluenesulfonate
  • Dimethyl sulfate
  • Methanol
  • 2-Fluoro-4-nitrotoluene
  • Sodium Methylate

DownStream

  • 3-methoxy-4-methylphenol
  • 3-methoxy-4-(1,3-oxazol-5-yl)aniline
  • 3-Methyl-9H-carbazol-2-ol
  • (2-ISOPROPYL-PHENOXY)-ACETICACID
  • 5-(2-METHOXY-4-NITROPHENYL)OXAZOLE
  • 2,4-dimethoxybenzaldehyde
  • 2-Methoxy-4-nitrobenzaldehyde
  • 2-METHOXY-4-NITROBENZYLALCOHOL
  • 2-Methoxy-4-nitrobenzoic acid
  • 4-hydroxy-o-anisaldehyde

Customs

[ HS Code ]: 2909309090

[ Summary ]:
2909309090 other aromatic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Oxidation of substituted 4-fluorobenzaldehydes: application to the no-carrier-added syntheses of 4-[18F]fluoroguaiacol and 4-[18F]fluorocatechol.

Int. J. Rad. Appl. Instrum. A. 42(7) , 673-81, (1991)

The synthesis of 4-[18F]fluoroguaiacol (4-[18F]fluoro-2-methoxyphenol) has been achieved in no-carrier-added form starting from 2-methoxy-4-nitrobenzaldehyde, using nucleophilic aromatic substitution ...

Anodic oxidations. VII. Nuclear cyanation of methylanisoles. Yoshida K, et al.

J. Org. Chem. 40(1) , 63-66, (1975)


More Articles

Related Compounds

  • 4-Fluoro-2-Methyl-5-nitroanisole
  • 2-methyl-5-phenyl-3-(trifluoromethyl)pent-2-en-4-ynenitrile
  • 2-methyl-5-oxo-1-phenylpyrazole-3-carboxylic acid
  • 2-methyl-5-phenylpyrimidine
  • 2-methyl-5-(2-methylprop-1-enyl)furan
  • 2-[methyl-(5-methylnaphthalene-1-carbothioyl)amino]acetic acid
  • N-[3-(4-methoxyphenyl)-1,2,4-thiadiazol-5-yl]benzamide
  • 8-(1-tert-butyl-5-methyl-1H-pyrazole-4-carbonyl)-1-oxa-8-azaspiro[5.5]undecane-7-carbonitrile
  • Methyl 3-[(3-chloro-4-fluorophenyl)sulfamoyl]-4-(4-methylphenyl)thiophene-2-carboxylate
  • 2-Amino-4-chloropent-4-enoic acid hydrochloride
  • 3-{[3-(Dimethylamino)propyl]amino}-1lambda6-thiolane-1,1-dione dihydrochloride
  • N-[2-(Phenylthio)phenyl]imidodicarbonimidic diamide
  • 4-(4-Methylpiperidin-1-yl)aniline dihydrochloride
  • 2-(3,5-Difluorophenyl)-5-methyl-2,4-dihydro-3h-pyrazol-3-one
  • 1-(1,1-Dioxidotetrahydro-3-thienyl)piperazine dihydrochloride
  • 2-(4-Chloro-2-fluorophenyl)-5-methyl-2,4-dihydro-3h-pyrazol-3-one
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