Tri-tert-butylphosphine tetrafluoroborate

Suppliers

Names

[ CAS No. ]:
131274-22-1

[ Name ]:
Tri-tert-butylphosphine tetrafluoroborate

[Synonym ]:
Tris(2-methyl-2-propanyl)phosphonium tetrafluoroborate
tritert-butylphosphanium,tetrafluoroborate
Tri-tert-butylphosphonium Tetrafluoroborate
MFCD07189501
Tri-tert-butyl phosphoniumtetra fluoro borate

Chemical & Physical Properties

[ Melting Point ]:
261 °C(lit.)

[ Molecular Formula ]:
C12H27P.BF4.H

[ Molecular Weight ]:
290.13

[ Exact Mass ]:
290.195770

[ PSA ]:
13.59000

[ LogP ]:
6.16380

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R20/21/22;R36/37/38

[ Safety Phrases ]:
S22-S24/25-S36/37/39-S26

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Tri-tert-butylphosphine
  • TERT-BUTYLMAGNESIUM CHLORIDE

DownStream

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

Heck coupling with nonactivated alkenyl tosylates and phosphates: examples of effective 1,2-migrations of the alkenyl palladium(II) intermediates.

Angew. Chem. Int. Ed. Engl. 45 , 3349, (2006)

Enantioselective, palladium-catalyzed alpha-arylation of N-Boc-pyrrolidine.

Tetrahedron Asymmetry 6 , 1283, (1995)

This communication discloses the first instance of the enantioselective Pd-catalyzed alpha-arylation of N-Boc-pyrrolidine. The methodology relies on Beak's sparteine-mediated, enantioselective deproto...

Synlett , 3001, (2006)


More Articles

Related Compounds

  • Tri-tert-butylphosphine
  • TRI-TERT-BUTYLPHOSPHINE
  • [(tri-tert-butylphosphine)Pd(CH2C(CH3)2P(t-Bu)2)(OAc)]HOAC
  • pentafluorophenyl(tri-tert-butylphosphine)gold(I)
  • bromo(tri-tert-butylphosphine)copper(I) tetramer
  • Ni(tri-tert-butylphosphine)2
  • 7-(Quinolin-2-yl)quinolin-5-ol
  • tert-butyl N-{[(3-ethynylphenyl)carbamoyl]methyl}-N-methylcarbamate
  • 3-[4-(2-methylphenyl)-1H-1,2,3-triazol-1-yl]piperidine-2,6-dione
  • N-(2,6-dioxopiperidin-3-yl)-N-methylpyridine-3-sulfonamide
  • N-(4-Bromo-2-methoxyphenyl)-N-(3-methoxypropyl)acetamide
  • 5-Bromo-6-fluoro-1-(2-methoxyethyl)-1H-indazole
  • (2S)-2-((((9H-Fluoren-9-yl)methoxy)carbonyl)amino)-3-((tert-butoxycarbonyl)amino)butanoic acid
  • 4-(Dimethylamino)-3-formyl-N-[(4-propan-2-yl-1,3-thiazol-2-yl)methyl]benzamide
  • 2-(2-{[(Tert-butoxy)carbonyl]amino}ethanesulfonyl)propanoic acid
  • 5-(1-Aminoethyl)-N,N-diethyl-1H-1,2,4-triazol-3-amine
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