bromofenoxim
Suppliers
Names
[ CAS No. ]:
13181-17-4
[ Name ]:
bromofenoxim
[Synonym ]:
2,6-dibromo-4-[[(2,4-dinitrophenoxy)amino]methylidene]cyclohexa-2,5-dien-1-one
Bromofenoxim
EINECS 236-129-6
2,6-dibromo-4-[(Ξ)-N-(2,4-dinitrophenoxy)methanimidoyl]phenol
MFCD00055409
3,5-dibromo-4-hydroxybenzaldehyde O-(2,4-dinitrophenyl)oxime
3,5-dibromo-4-hydroxybenzaldehyde 2,4-dinitrophenyloxime
Chemical & Physical Properties
[ Density]:
2.135g/cm3
[ Boiling Point ]:
476ºC at 760mmHg
[ Molecular Formula ]:
C13H7Br2N3O6
[ Molecular Weight ]:
461.01900
[ Flash Point ]:
241.7ºC
[ Exact Mass ]:
458.87000
[ PSA ]:
133.46000
[ LogP ]:
5.19290
[ Vapour Pressure ]:
0mmHg at 25°C
[ Index of Refraction ]:
1.705
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- EG7000000
- CHEMICAL NAME :
- Bromofenoxim
- CAS REGISTRY NUMBER :
- 13181-17-4
- LAST UPDATED :
- 199710
- DATA ITEMS CITED :
- 7
- MOLECULAR FORMULA :
- C13-H7-Br2-N3-O6
- MOLECULAR WEIGHT :
- 461.05
- WISWESSER LINE NOTATION :
- WNR CNW DONU1R DQ CE EE
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 1100 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- 85ARAE "Agricultural Chemicals," Thomson, W.T., 4 vols., Fresno, CA, Thomson Publications, 1976/77 revision Volume(issue)/page/year: 2,203,1977
- TYPE OF TEST :
- LC50 - Lethal concentration, 50 percent kill
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- >242 mg/m3/6H
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,98,1991
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- >3 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,98,1991
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Mammal - dog
- DOSE/DURATION :
- >1 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- 85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year: A042,1983
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rabbit
- DOSE/DURATION :
- >500 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- WRPCA2 World Review of Pest Control. (London, UK) V.1-10, 1962-71. Discontinued. Volume(issue)/page/year: 9,119,1970
Safety Information
[ Symbol ]:
GHS07, GHS09
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H302-H410
[ Precautionary Statements ]:
P273-P501
[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves
[ Hazard Codes ]:
Xn: Harmful;N: Dangerous for the environment;
[ Risk Phrases ]:
22-50/53
[ Safety Phrases ]:
S25;S60;S61
[ RIDADR ]:
UN3077 9/PG 3
[ RTECS ]:
EG7000000
[ HS Code ]:
2928000033
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2928000033
[ Summary ]:
2928000033 (e)-3,5-dibromo-4-hydroxybenzaldehyde o-(2,4-dinitrophenyl) oxime。supervision conditions:s(import or export registration certificate for pesticides)。VAT:17.0%。tax rebate rate:9.0%。MFN tarrif:6.5%。general tariff:20.0%
Articles
Zentralbl. Mikrobiol. 140(8) , 607-19, (1985)
The effects of the herbicides simazine and bromophenoxim on the microflora of two soil-types were studied. It was found that the effects produced on the microbial biomass depended on the type and conc...