6,6'-Dibromo-1,1'-binaphthalene-2,2'-diol

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Names

[ CAS No. ]:
13185-00-7

[ Name ]:
6,6'-Dibromo-1,1'-binaphthalene-2,2'-diol

[Synonym ]:
(±)-6,6'-Dibromo-2,2'-dihydroxy-1,1'-binaphthyl
6-bromo-1-(6-bromo-2-hydroxynaphthalen-1-yl)naphthalen-2-ol
MFCD00798290
6,6'-Dibromo-1,1'-binaphthalene-2,2'-diol
[1,1'-Binaphthalene]-2,2'-diol, 6,6'-dibromo-
)-6,6'-Dibromo-1,1'-bi-2-naphthol
(+/-)-6,6'-DibroMo-1,1'-bi-2-naphthol
6,6′-Dibromo-1,1′-bi-2-naphthol

Chemical & Physical Properties

[ Density]:
1.8±0.1 g/cm3

[ Boiling Point ]:
546.2±45.0 °C at 760 mmHg

[ Melting Point ]:
195-199ºC(lit.)

[ Molecular Formula ]:
C20H12Br2O2

[ Molecular Weight ]:
444.116

[ Flash Point ]:
284.1±28.7 °C

[ Exact Mass ]:
441.920380

[ PSA ]:
40.46000

[ LogP ]:
5.91

[ Vapour Pressure ]:
0.0±1.5 mmHg at 25°C

[ Index of Refraction ]:
1.779

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
26-36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • (S)-(-)-1,1'-Bi-2-naphthol
  • 6-Bromo-2-naphthol

DownStream

Articles

Conformational sensitivity of chiroptical spectroscopic methods: 6,6'-dibromo-1,1'-bi-2-naphthol.

J. Phys. Chem. A 113(18) , 5423-31, (2009)

The experimental vibrational circular dichroism (VCD), electronic circular dichroism (ECD), and optical rotatory dispersion (ORD) spectra for both enantiomers of 6,6'-dibromo-1,1'-bi-2-naphthol have b...

Novel binuclear chiral zirconium catalysts used in enantioselective strecker reactions.

Chirality 12(5-6) , 540-3, (2000)

A novel binuclear chiral zirconium catalyst was successfully used in enantioselective Strecker reactions. The catalyst was readily prepared from zirconium t-butoxide (Zr(OtBu)4), (R)-6,6'-dibromo-1, 1...

Diastereoselective and enantioselective glyoxylate-ene reaction catalyzed by new class of binaphthol-derived titanium complex. Terada M, et al.

Tetrahedron Lett. 35(36) , 6693-6696, (1996)


More Articles

Related Compounds

  • 6,6'-Dibromo-1,1'-binaphthalene-2,2'-diol
  • 6,6'-Dibromo-1,1'-binaphthalene-2,2'-diol
  • (S)-6,6'-Dibromo-[1,1'-binaphthalene]-2,2'-diamine
  • (R)-3,3'-Dibromo-5,5',6,6',7,7',8,8'-octahydro-[1,1'-binaphthalene]-2,2'-diol
  • 5,5',6,6',7,7',8,8'-Octahydro[1,1'-binaphthalene]-2,2'-diol dipentanoate
  • (S)-5,5',6,6',7,7',8,8'-octahydro-[1,1'-binaphthalene]-2,2'-diol
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • 1-(4-Methylpyrrolidin-3-yl)piperidine
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine
  • 4-amino-N-[2-tert-butyl-1-(tetrahydro-2H-pyran-4-ylmethyl)-1H-benzimidazol-5-yl]-N-ethylbenzenesulfonamide