Diisopropyl malonate

Names

[ Name ]:
Diisopropyl malonate

[Synonym ]:
MFCD00059359
Diisopropyl malonate
EINECS 236-156-3
Propanedioic acid, bis(1-methylethyl) ester
dipropan-2-yl propanedioate
Malonic acid diisopropyl ester

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
207.0±8.0 °C at 760 mmHg

[ Molecular Formula ]:
C₉H₁₆O₄

[ Molecular Weight ]:
188.221

[ Flash Point ]:
89.4±16.9 °C

[ Exact Mass ]:
188.104858

[ PSA ]:
52.60000

[ LogP ]:
1.40

[ Vapour Pressure ]:
0.2±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.425

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ WGK Germany ]:
3

[ HS Code ]:
2917190090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Malonic acid
Isopropanol
2-Bromopropane
Diethyl malonate
2-Cyanoacetamide
malonoyl chloride
Aluminium isopropoxide
Dimethyl malonate
3-Isopropyloxy-2,2-dichloro-propionsaeure-isopropylester

DownStream

isopropyl phenyl acetate
5-(4-phenoxyphenyl)-1,3-diazinane-2,4,6-trione
dipropan-2-yl 2-benzylidenepropanedioate
N,N''-BIS-(2,3-DICHLORO-PHENYL)-MALONAMIDE
Diisopropyl 3,3-dimethoxycyclobutane-1,1-dicarboxylate
isopropyl N-(3,4-dichlorophenyl)malonamate
N,N''-BIS-(3,4-DICHLORO-PHENYL)-MALONAMIDE
isopropyl N-(4-chlorophenyl)malonamate
N,N''-BIS-(4-CHLORO-PHENYL)-MALONAMIDE

Customs

[ HS Code ]: 2917190090

[ Summary ]:
2917190090 acyclic polycarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Hepatotoxicity of diisopropyl ester of malonic acid and chloromalonic acids, disinfection by-products of the fungicide isoprothiolane.

Arch. Toxicol. 71(9) , 550-5, (1997)

The fungicide isoprothiolane (diisopropyl 1,3-dithiolane-2-ylidenemalonate) decomposes to the diisopropyl esters of malonic acid (DM), chloromalonic acid (DCM) and dichloromalonic acid (DDCM) upon aqu...

Synthesis of quinoxaline 1,4-di-N-oxide analogues and crystal structure of 2-carbomethoxy-3-hydroxyquinoxaline-di-N-oxide.

Molecules 16(8) , 6894-901, (2011)

A series of quinoxaline 1,4-di-N-oxide analogues were prepared from benzofurazan N-oxide derivatives and β-diketone ester compounds by the improved Beirut reaction. The structures of the target produc...

Use of isopropyl alcohol as a solvent in Ti (O-i-Pr) 4-catalyzed Knöevenagel reactions. Yamashita K, et al.

Tetrahedron 61(33) , 7981-85, (2005)

diisopropyl 2-((tosyloxy)imino)malonate
diisopropyl 2-(propan-2-ylidene)malonate
diisopropyl 2-(((methylsulfonyl)oxy)imino)malonate
diisopropyl 2-(2-methylpent-4-en-2-yl)malonate
diisopropyl 2-(((2-(ethyldisulfanyl)ethyl)thio)(ethylthio)methylene)malonate
diisopropyl 2-(4-hydroxy-4-methylpent-2-ynyl)-2-(prop-2-ynyl)malonate
Tert-butyl 2-amino-3-(4-bromophenyl)-2-methylpropanoate
4,6-Dichloro-1,2-dimethyl-1H-imidazo[4,5-c]pyridine
2-(ethoxymethyl)-1-(1H-pyrazol-4-yl)prop-2-en-1-ol
1-(2-Methylprop-2-en-1-yl)cyclopropane-1-sulfonyl chloride
Tert-butyl 2-amino-4-(2-bromophenyl)butanoate
3,5-dimethyl-4-(pyrrolidin-3-yl)-4H-1,2,4-triazole
Tert-butyl 2-amino-3-(2-bromophenyl)-2-methylpropanoate
2-[1-(4-hydroxypentyl)-5-propyl-1H-1,2,3-triazol-4-yl]acetonitrile
benzyl N-[(4-bromo-2-phenoxyphenyl)methyl]carbamate
1-Fluoro-3-[methyl(2-methylphenyl)amino]propan-2-ol

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