BIS((S)-4-PHENYL-4,5-DIHYDROOXAZOL-2-YL)METHANE

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Names

[ CAS No. ]:
132098-59-0

[ Name ]:
BIS((S)-4-PHENYL-4,5-DIHYDROOXAZOL-2-YL)METHANE

[Synonym ]:
KEHOIBBPRFRZFW-GHMZBOCLSA
Bis((S)-4-phenyl-4,5-dihydrooxazol-2-yl)methane
MFCD00192295

Chemical & Physical Properties

[ Density]:
1.28 g/mL at 25ºC(lit.)

[ Boiling Point ]:
131-134ºC0.01 mm Hg(lit.)

[ Molecular Formula ]:
C₁₉H₁₈N₂O₂

[ Molecular Weight ]:
306.35800

[ Flash Point ]:
>230 °F

[ Exact Mass ]:
306.13700

[ PSA ]:
43.18000

[ LogP ]:
2.58770

[ Vapour Pressure ]:
3.6E-08mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.587

[ Storage condition ]:
2~8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
26-36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3.0

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

(S)-(+)-2-Phenylglycinol
Diethyl malonate
N1,N3-bis((S)-2-chloro-1-phenylethyl)malonamide
N1,N3-bis((S)-2-hydroxy-1-phenylethyl)malonamide
Diethyl propanediimidate dihydrochloride

DownStream

Articles

Gant, T.G. Meyers, A.I.

Tetrahedron 50 , 2297, (1994)

Pfaltz, A.

Acc. Chem. Res. 26 , 339, (1993)

Bolm, C.

Angew. Chem. Int. Ed. Engl. 30 , 542, (1991)

2,2'-Bis((S)-4-phenyl-4,5-dihydrooxazol-2-yl)-1,1'-biphenyl
1,3-Bis((S)-4-phenyl-4,5-dihydrooxazol-2-yl)benzene
2,2-bis((S)-4-phenyl-4,5-dihydrooxazol-2-yl)acetonitrile
6,6'-bis((S)-4-phenyl-4,5-dihydrooxazol-2-yl)-2,2'-bipyridine
(1S)-2,2'-Bis((S)-4-phenyl-4,5-dihydrooxazol-2-yl)-1,1'-binaphthalene
(1R)-2,2'-Bis((S)-4-phenyl-4,5-dihydrooxazol-2-yl)-1,1'-binaphthalene
4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
3-(5-{[(tert-butoxy)carbonyl]amino}-1H-1,2,3,4-tetrazol-1-yl)benzoic acid
1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
1-[3-(difluoromethyl)-1-methyl-1H-pyrazol-4-yl]-2-methylpropan-2-amine
(4-Methyl-tetrahydro-furan-2-yl)-methanol
N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
[5-(difluoromethyl)-1-[(4-fluorophenyl)methyl]-1H-1,2,3-triazol-4-yl]methanol