r(+)-2 2'-bis-(diphenylphosphino)-6 6'-&

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Names

[ CAS No. ]:
133545-16-1

[ Name ]:
r(+)-2 2'-bis-(diphenylphosphino)-6 6'-&

[Synonym ]:
rac-MeO-BiPhep
(R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl
(S)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine)
(RS)-(6,6'-dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine)
(6,6'-dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine)
MFCD03095430
(S)-(-)-MeO-BIPHEP,SL-A101-2,(S)-(-)-2,2

Chemical & Physical Properties

[ Boiling Point ]:
651.1ºC at 760 mmHg

[ Melting Point ]:
213-216ºC

[ Molecular Formula ]:
C₃₈H₃₂O₂P₂

[ Molecular Weight ]:
582.60700

[ Flash Point ]:
438.5ºC

[ Exact Mass ]:
582.18800

[ PSA ]:
45.64000

[ LogP ]:
6.88720

[ Vapour Pressure ]:
4.05E-16mmHg at 25°C

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

1-methyl-4-(trichloromethyl)benzene
Water
m-Bromoanisole
Chlorodiphenylphosphine

DownStream

Articles

R. Schmid et al.

Helv. Chim. Acta 74 , 370, (1991)

R. Schmid et al.

Pure Appl. Chem. 68 , 131-138, (1996)

B. Heiser et al.

Tetrahedron Asymmetry 2 , 51, (1991)

Related Compounds

Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthy]ruthenium(II)
(6,6'-dimethyl-[1,1'-biphenyl]-2,2'-diyl)bis(diphenylphosphine)
(R)-(+)-2,2'-BIS(DICYCLOBUTYLPHOSPHINO)-6,6'-DIMETHOXY-1,1'-BIPHENYL
(R)-(+)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.
(R)-(+)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97
(R)-(+)-2,2'-BIS(N-DIPHENYLPHOSPHINOAMINO)-5,5',6,6',7,7',8,8'-OCTAHYDRO-1,1'-BINAPHTHYL
2-Fluoro-4-(1-(1,4-dihydro-1,1,4,4,6-pentamethylnaphthalen-7-yl)vinyl)benzoic acid
(E)-3-(4-(1,2,3,4-tetrahydro-1,1,4,4,6-pentamethylnaphthalen-7-yl)-5-methylpyridin-2-yl)acrylic acid
1-Tert-butyl 4-ethyl 4-(1-(tert-butoxycarbonyl)piperidine-4-carbonyl)piperidine-1,4-dicarboxylate
Ethyl (6-bromo-2-quinolinyl)acetate
Methyl 3-[(piperidin-3-ylmethyl)sulfanyl]propanoate hydrochloride
[3-(1H-1,2,3-Benzotriazol-1-yl)propyl]amine hydrochloride
2-Aminomethyl-6-fluoro-4-iodopyridine
2-(3-ethyl-6,7-dimethoxy-2,4-dioxo-4a,5,6,7,8,8a-hexahydroquinazolin-1-yl)-N-(4-methylphenyl)acetamide
(2S)-2-{[1-(4-Methoxybenzenesulfonyl)piperidin-4-YL]formamido}-4-methylpentanoic acid
7-(2-Bromoethoxy)-3-(4-chlorophenyl)-4a,5,6,7,8,8a-hexahydrochromen-4-one

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