r(+)-2 2'-bis-(diphenylphosphino)-6 6'-&

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Names

[ CAS No. ]:
133545-16-1

[ Name ]:
r(+)-2 2'-bis-(diphenylphosphino)-6 6'-&

[Synonym ]:
rac-MeO-BiPhep
(R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl
(S)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine)
(RS)-(6,6'-dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine)
(6,6'-dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine)
MFCD03095430
(S)-(-)-MeO-BIPHEP,SL-A101-2,(S)-(-)-2,2

Chemical & Physical Properties

[ Boiling Point ]:
651.1ºC at 760 mmHg

[ Melting Point ]:
213-216ºC

[ Molecular Formula ]:
C38H32O2P2

[ Molecular Weight ]:
582.60700

[ Flash Point ]:
438.5ºC

[ Exact Mass ]:
582.18800

[ PSA ]:
45.64000

[ LogP ]:
6.88720

[ Vapour Pressure ]:
4.05E-16mmHg at 25°C

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 1-methyl-4-(trichloromethyl)benzene
  • Water
  • m-Bromoanisole
  • Chlorodiphenylphosphine

DownStream

Articles

R. Schmid et al.

Helv. Chim. Acta 74 , 370, (1991)

R. Schmid et al.

Pure Appl. Chem. 68 , 131-138, (1996)

B. Heiser et al.

Tetrahedron Asymmetry 2 , 51, (1991)


More Articles

Related Compounds

  • Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthy]ruthenium(II)
  • (6,6'-dimethyl-[1,1'-biphenyl]-2,2'-diyl)bis(diphenylphosphine)
  • (R)-(+)-2,2'-BIS(DICYCLOBUTYLPHOSPHINO)-6,6'-DIMETHOXY-1,1'-BIPHENYL
  • (R)-(+)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.
  • (R)-(+)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97
  • (R)-(+)-2,2'-BIS(N-DIPHENYLPHOSPHINOAMINO)-5,5',6,6',7,7',8,8'-OCTAHYDRO-1,1'-BINAPHTHYL
  • N-(3-(benzo[d]thiazol-2-yl)-6-methyl-4,5,6,7-tetrahydrothieno[2,3-c]pyridin-2-yl)-2-(phenylthio)acetamide hydrochloride
  • N-(3-(benzo[d]thiazol-2-yl)-6-methyl-4,5,6,7-tetrahydrothieno[2,3-c]pyridin-2-yl)-2-((4-fluorophenyl)thio)acetamide hydrochloride
  • N-(2-(dimethylamino)ethyl)-N-(5,6-dimethylbenzo[d]thiazol-2-yl)-3-(ethylsulfonyl)benzamide hydrochloride
  • 2-(benzylthio)-N-((4-oxo-3-(2-(pyrrolidin-1-yl)ethyl)-3,4-dihydrophthalazin-1-yl)methyl)acetamide
  • 4-methyl-N-((4-oxo-3-(2-(pyrrolidin-1-yl)ethyl)-3,4-dihydrophthalazin-1-yl)methyl)thiophene-2-carboxamide
  • N-(4,7-dimethylbenzo[d]thiazol-2-yl)-2,4-difluoro-N-(3-morpholinopropyl)benzamide hydrochloride
  • 5-chloro-N-(4,5-dimethylbenzo[d]thiazol-2-yl)-2-methoxy-N-(3-morpholinopropyl)benzamide hydrochloride
  • N-(4-chlorobenzo[d]thiazol-2-yl)-N-(3-morpholinopropyl)-2-(2-oxobenzo[d]oxazol-3(2H)-yl)acetamide hydrochloride
  • N-(5-methoxybenzo[d]thiazol-2-yl)-2,5-dimethyl-N-(3-morpholinopropyl)furan-3-carboxamide hydrochloride
  • N-(5-methoxybenzo[d]thiazol-2-yl)-4-methyl-N-(3-morpholinopropyl)-1,2,3-thiadiazole-5-carboxamide hydrochloride
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