Cupric acetylacetonate

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Names

[ CAS No. ]:
13395-16-9

[ Name ]:
Cupric acetylacetonate

[Synonym ]:
3-Penten-2-one, 4-hydroxy-, copper(2+) salt, (3Z)- (2:1)
Copper(2+) bis[(2Z)-4-oxopent-2-en-2-olate]
Cupric(II) acetylacetonate
2,4-Pentanedione copper(II) derivative (Bis(2,4-pentanedionato)copper(II)
Copper(2+) bis[(2Z)-4-oxo-2-penten-2-olate]
Copper(II) Acetylacetonate
Copper(II) 4-oxopent-2-en-2-olate
EINECS 236-477-9
Bis(2,4-pentanedionato)copper(II)
Bis(acetylacetone)copper
Copper acetylacetonate
2,4-Pentanedione copper(II) derivative
MFCD00000016
Cupric Acetylacetonate
Acetylacetone Copper(II) Salt

Chemical & Physical Properties

[ Boiling Point ]:
160ºC (9.8 mmHg)

[ Melting Point ]:
245ºC

[ Molecular Formula ]:
C10H14CuO4

[ Molecular Weight ]:
261.762

[ Flash Point ]:
160°C/10mm

[ Exact Mass ]:
261.018799

[ PSA ]:
52.60000

[ LogP ]:
1.91770

[ Water Solubility ]:
0.2 g/L (20 ºC)

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
GL6520000
CHEMICAL NAME :
Copper, bis(2,4-pentanedionato)-
CAS REGISTRY NUMBER :
13395-16-9
LAST UPDATED :
199701
DATA ITEMS CITED :
4
MOLECULAR FORMULA :
C10-H14-Cu-O4
MOLECULAR WEIGHT :
261.78
WISWESSER LINE NOTATION :
1VYV1&-CU-YV1&V1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
19 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CHTHBK Chemotherapy (Basel). (S. Karger Pub., Inc., 79 Fifth Ave., New York, NY 10003) V.13- 1968- Volume(issue)/page/year: 16,371,1971
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
10 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#00604 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X2730 No. of Facilities: 1041 (estimated) No. of Industries: 11 No. of Occupations: 13 No. of Employees: 8588 (estimated) No. of Female Employees: 1749 (estimated)

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R20/21/22;R36/37/38

[ Safety Phrases ]:
S26-S36/37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
GL6520000

[ HS Code ]:
29420000

Synthetic Route

Precursor & DownStream

Precursor

  • 2,4-Pentandione
  • Copper(II) acetate

DownStream

  • Acetone
  • 2,4-Pentandione
  • Zinc
  • 3-CHLORO-2,4-PENTANEDIONE

Customs

[ HS Code ]: 29420000

Articles

Local vanadium release from a calcium sulfate carrier accelerates fracture healing.

J. Orthop. Res. 32(5) , 727-34, (2014)

This study evaluated the efficacy of using calcium sulfate (CaSO4 ) as a carrier for intramedullary delivery of an organic vanadium salt, vanadyl acetylacetonate (VAC) after femoral fracture. VAC can ...

Microbrachytherapy using holmium-166 acetylacetonate microspheres: a pilot study in a spontaneous cancer animal model.

Brachytherapy 12(2) , 171-7, (2013)

Holmium-166 acetylacetonate microspheres ((166)Ho-AcAc-MS) are proposed as an intratumoral radioablation device. This article presents a pilot study in housecats with unresectable liver cancer. Feasib...

Evaluation of electrogenerated chemiluminescence from a neutral Ir(III) complex for quantitative analysis in flowing streams.

Analyst 136(10) , 2151-5, (2011)

Though recently Ir(III) complexes have attracted much interest in electrochemiluminescent (ECL) analysis due to their high emission in various wavelengths, there were a few studies reported on its ana...


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Related Compounds

  • CUPRIC FERRICYANIDE
  • cupric dichromate
  • Cupric cyanide
  • Cupric carbonate basic
  • Cupric hydroxide
  • Cupric acetate monohydrate