Gallium trichloride

Names

[ Name ]:
Gallium trichloride

[Synonym ]:
MFCD00011018
gallium chloride
GaCl3
gallium(III) chloride
Gallium trichloride
EINECS 236-610-0
trichlorogallane
Trichlorogallium

Chemical & Physical Properties

[ Density]:
2.47

[ Boiling Point ]:
201.03ºC

[ Melting Point ]:
77.9ºC

[ Molecular Formula ]:
Cl₃Ga

[ Molecular Weight ]:
176.082

[ Flash Point ]:
-26 °F

[ Exact Mass ]:
173.832138

[ LogP ]:
1.68770

[ Vapour Pressure ]:
33900mmHg at 25°C

[ Stability ]:
Stability Stable, but reacts violently with water.

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: LW9100000

CHEMICAL NAME :: Gallium(3+) chloride

CAS REGISTRY NUMBER :: 13450-90-3

LAST UPDATED :: 199701

DATA ITEMS CITED :: 10

MOLECULAR FORMULA :: Cl3-Ga

MOLECULAR WEIGHT :: 176.07

WISWESSER LINE NOTATION :: GA G3

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LCLo - Lowest published lethal concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 316 mg/m3/3H

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Subcutaneous

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 306 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 47 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Parenteral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1408 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 36975 ug/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Mammal - dog

DOSE/DURATION :: 41 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Subcutaneous

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 245 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 43 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

MUTATION DATA

TYPE OF TEST :: DNA repair

TEST SYSTEM :: Bacteria - Bacillus subtilis

DOSE/DURATION :: 2350 ug/disc

REFERENCE :: MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 264,163,1991

Safety Information

[ Symbol ]:

GHS02, GHS05, GHS07, GHS08, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H224-H304-H314-H336-H411

[ Supplemental HS ]:
Reacts violently with water.

[ Precautionary Statements ]:
P210-P261-P273-P280-P301 + P310-P305 + P351 + P338

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US)

[ Hazard Codes ]:
C: Corrosive;

[ Risk Phrases ]:
R14;R34

[ Safety Phrases ]:
26-27-28-36/37/39-45

[ RIDADR ]:
UN 3260

[ WGK Germany ]:
3

[ RTECS ]:
LW9100000

[ Packaging Group ]:
II

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

gallium
Chlorine
Trimethyl-Gallium
Hydrochloric acid
Gallium(III) hydride.
Gallate(1-),tetrachloro-, gallium(1+) (1:1), (T-4)-
(GaCl3)2(4-bis(trimethylsilyl)amino-1,2,3,4,5-triazadiphosphole)
Silver chloride

DownStream

dichloro-(2,4,6-trimethylphenyl)gallane
tris[2,4,6-tri(propan-2-yl)phenyl]gallane
chlorogallium,tritert-butylsilicon
gallium
Gallate(1-),tetrachloro-, gallium(1+) (1:1), (T-4)-
DIETHYLGALLIUM CHLORIDE
gallium triflate
ditert-butylphosphane,gallium
chloro-bis(2,4,6-tritert-butylphenyl)gallane

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A new siderophore named albachelin was isolated from iron deficient culture of Amycolatopsis alba. The planar structure of albachelin was elucidated by the combination of ESI-MS/MS experiment and NMR ...

Cyclopropylmethylation of benzylic and allylic chlorides with cyclopropylmethylstannane catalyzed by gallium or indium halide.

Org. Lett. 12(7) , 1520-3, (2010)

Benzylic and allylic chlorides easily coupled with cyclopropylmethylstannane in the presence of GaCl(3) or InBr(3) catalyst, in which an intermediate of an active butenylgallium or -indium species was...

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