Gallium trichloride

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Names

[ CAS No. ]:
13450-90-3

[ Name ]:
Gallium trichloride

[Synonym ]:
MFCD00011018
gallium chloride
GaCl3
gallium(III) chloride
Gallium trichloride
EINECS 236-610-0
trichlorogallane
Trichlorogallium

Chemical & Physical Properties

[ Density]:
2.47

[ Boiling Point ]:
201.03ºC

[ Melting Point ]:
77.9ºC

[ Molecular Formula ]:
Cl3Ga

[ Molecular Weight ]:
176.082

[ Flash Point ]:
-26 °F

[ Exact Mass ]:
173.832138

[ LogP ]:
1.68770

[ Vapour Pressure ]:
33900mmHg at 25°C

[ Stability ]:
Stability Stable, but reacts violently with water.

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
LW9100000
CHEMICAL NAME :
Gallium(3+) chloride
CAS REGISTRY NUMBER :
13450-90-3
LAST UPDATED :
199701
DATA ITEMS CITED :
10
MOLECULAR FORMULA :
Cl3-Ga
MOLECULAR WEIGHT :
176.07
WISWESSER LINE NOTATION :
GA G3

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
316 mg/m3/3H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
306 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
47 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Parenteral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1408 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
36975 ug/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Mammal - dog
DOSE/DURATION :
41 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
245 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
43 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value

MUTATION DATA

TYPE OF TEST :
DNA repair
TEST SYSTEM :
Bacteria - Bacillus subtilis
DOSE/DURATION :
2350 ug/disc
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 264,163,1991

Safety Information

[ Symbol ]:

GHS02, GHS05, GHS07, GHS08, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H224-H304-H314-H336-H411

[ Supplemental HS ]:
Reacts violently with water.

[ Precautionary Statements ]:
P210-P261-P273-P280-P301 + P310-P305 + P351 + P338

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US)

[ Hazard Codes ]:
C: Corrosive;

[ Risk Phrases ]:
R14;R34

[ Safety Phrases ]:
26-27-28-36/37/39-45

[ RIDADR ]:
UN 3260

[ WGK Germany ]:
3

[ RTECS ]:
LW9100000

[ Packaging Group ]:
II

Synthetic Route

Precursor & DownStream

Precursor

  • gallium
  • Chlorine
  • Trimethyl-Gallium
  • Hydrochloric acid
  • Gallium(III) hydride.
  • Gallate(1-),tetrachloro-, gallium(1+) (1:1), (T-4)-
  • (GaCl3)2(4-bis(trimethylsilyl)amino-1,2,3,4,5-triazadiphosphole)
  • Silver chloride

DownStream

  • dichloro-(2,4,6-trimethylphenyl)gallane
  • tris[2,4,6-tri(propan-2-yl)phenyl]gallane
  • chlorogallium,tritert-butylsilicon
  • gallium
  • Gallate(1-),tetrachloro-, gallium(1+) (1:1), (T-4)-
  • DIETHYLGALLIUM CHLORIDE
  • gallium triflate
  • ditert-butylphosphane,gallium
  • chloro-bis(2,4,6-tritert-butylphenyl)gallane

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Related Compounds

  • gallium trichloride-pyridine (1/1)
  • Gallium, dimethyl-1H-pyrazol-1-yl-
  • GALLIUM PERCHLORATE, HYDRATED
  • GALLIUM TRIPHENYL
  • Gallium,tris(2,4-pentanedionato-kO,kO')-, (OC-6-11)- (9CI)
  • gallium-69
  • [3,3-difluoro-1-(4-nitro-1H-pyrazol-3-yl)cyclobutyl]methanamine
  • rac-[(1R,3R)-2,2-dimethyl-3-[3-(trifluoromethyl)-1H-pyrazol-4-yl]cyclopropyl]methanamine
  • 3-(2,5-dimethyl-1H-pyrrol-3-yl)-1,1-difluoropropan-2-amine
  • 2,2-dimethyl-1-(4,5,6,7-tetrahydro-1H-indazol-3-yl)cyclopropan-1-amine
  • 2-(2-amino-1H-imidazol-5-yl)benzene-1,4-diol
  • (3R)-3-amino-1-bromopentan-2-one hydrobromide
  • 5-{3H,4H,5H,6H,7H-imidazo[4,5-c]pyridin-4-yl}-2-methylpyridine
  • 1'-Cyclopropyl-3,5,6,7-tetrahydrospiro[imidazo[4,5-c]pyridine-4,3'-pyrrolidine]
  • 4-{3H,4H,5H,6H,7H-imidazo[4,5-c]pyridin-4-yl}-1,3-dimethyl-1H-pyrazole
  • 4-Methoxy-3',5',6',7'-tetrahydrospiro[cyclohexane-1,4'-imidazo[4,5-c]pyridine]
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