Germane, bromide (1:4)

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Names

[ CAS No. ]:
13450-92-5

[ Name ]:
Germane, bromide (1:4)

[Synonym ]:
EINECS 236-612-1
tetrabromogermane
Germanium(IV) bromide
Germanium tetrabromide
Germane, bromide (1:4)
MFCD00016115

Chemical & Physical Properties

[ Density]:
3.13 g/mL at 25 °C(lit.)

[ Boiling Point ]:
186.5 °C(lit.)

[ Melting Point ]:
26.1 °C(lit.)

[ Molecular Formula ]:
Br4Ge

[ Molecular Weight ]:
396.290

[ Flash Point ]:
186.5°C

[ Exact Mass ]:
393.627991

[ LogP ]:
3.00160

[ Index of Refraction ]:
1.6269

[ Stability ]:
Stable. Incompatible with water, strong oxidizing agents.

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
LY5220000
CHEMICAL NAME :
Germanium bromide
CAS REGISTRY NUMBER :
13450-92-5
LAST UPDATED :
199701
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
Br4-Ge
MOLECULAR WEIGHT :
392.23
WISWESSER LINE NOTATION :
.GE..E4

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
56 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#02624

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
C

[ Risk Phrases ]:
R14:Reacts violently with water. R34:Causes burns. R37:Irritating to the respiratory system.

[ Safety Phrases ]:
S26-S27-S36-S45

[ RIDADR ]:
UN 3260 8/PG 2

[ WGK Germany ]:
3

[ RTECS ]:
LY5220000

[ Packaging Group ]:
II

[ Hazard Class ]:
8

Synthetic Route

Precursor & DownStream

Precursor

  • Germanium
  • Bromine
  • Germanium chloride
  • Hydrogen bromide
  • Iodine monobromide
  • Dibromomethane
  • Bromotrichloromethane
  • Bromoform

DownStream

  • methyl 2-methyl-3-tribromogermylpropanoate
  • tribromo-(2,3,4,5,6-pentafluorophenyl)germane
  • dibromo-bis(2,3,4,5,6-pentafluorophenyl)germane
  • Triphenylgermanium bromide, 95%
  • phenyltribromogermane
  • Germane,dibromodiphenyl-
  • dibromo(diphenyl)stannane
  • Bromine
  • dibromo(dibutyl)germane

Related Compounds

  • magnesium,ethynyl(triphenyl)germane,bromide
  • germane,gold (1:4)
  • germane,lithium
  • germane,platinum (1:3)
  • germane,platinum (1:2)
  • germane,nickel (1:2)
  • N-(benzo[d][1,3]dioxol-5-ylmethyl)-2-((1-(2-methoxyphenyl)-4-methyl-1H-pyrazolo[3,4-d]pyridazin-7-yl)thio)acetamide
  • (2E)-N-[(2E)-5-ethyl-1,3,4-thiadiazol-2(3H)-ylidene]-2-[(methylsulfonyl)imino]-2,3-dihydro-1,3-benzothiazole-6-carboxamide
  • 2-(4-((4-ethylphenyl)sulfonyl)piperazin-1-yl)-6-methyl-N-phenylpyrimidin-4-amine
  • 2-(4-((4-ethylphenyl)sulfonyl)piperazin-1-yl)-N,N,6-trimethylpyrimidin-4-amine
  • 4-ethyl-N-(4-((4-((4-methoxyphenyl)amino)-6-methylpyrimidin-2-yl)amino)phenyl)benzenesulfonamide
  • N-(4-ethylphenyl)-2-(5-methoxy-4-oxo-2-(piperidin-1-ylmethyl)pyridin-1(4H)-yl)acetamide
  • 2-(2-((4-acetylpiperazin-1-yl)methyl)-5-methoxy-4-oxopyridin-1(4H)-yl)-N-(3-fluorophenyl)acetamide
  • 2-(2-((4-acetylpiperazin-1-yl)methyl)-5-methoxy-4-oxopyridin-1(4H)-yl)-N-(4-methoxyphenyl)acetamide
  • 2-(2-((4-acetylpiperazin-1-yl)methyl)-5-methoxy-4-oxopyridin-1(4H)-yl)-N-(2,3-dihydrobenzo[b][1,4]dioxin-6-yl)acetamide
  • 2-(2-((4-acetylpiperazin-1-yl)methyl)-5-methoxy-4-oxopyridin-1(4H)-yl)-N-(2-(trifluoromethyl)phenyl)acetamide
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