platinum tetrachloride
Suppliers
Names
[ CAS No. ]:
13454-96-1
        
[ Name ]:
 platinum tetrachloride
        
[Synonym ]:
                
                Platinum (IV) chloride
                
                
            
                
                Platinum(4+) tetrachloride
                
                
            
                
                PLATINUM CHLORIDE
                
                
            
                
                MFCD00011182
                
                
            
                
                (SP-4-1)-Platinumchloride
                
                
            
                
                Tétrachlorure de Platine (4+)
                
                
            
                
                PLATINIC CHLORIDE
                
                
            
                
                Platinum(IV) chloride
                
                
            
                
                platinum (IV)-chloride
                
                
            
                
                tetrachloroplatinum
                
                
            
                
                EINECS 236-645-1
                
                
            
                
                Platinum(2+) chloride (1:2)
                
                
            
                
                platinumchloride(ptcl4)
                
                
            
                
                Platinumchloride1
                
                
            
                
                Pt(IV) chloride
                
                
            
                
                platinum tetrachloride
                
                
            
                
                platinum(iv)tetrachloride
                
                
                
                
    
Chemical & Physical Properties
[ Density]:
4.303 g/mL at 25 °C(lit.)
            
[ Melting Point ]:
370 °C (dec.)(lit.)
            
[ Molecular Formula ]:
Cl4Pt
            
[ Molecular Weight ]:
336.896
            
[ Exact Mass ]:
334.840210
            
[ LogP ]:
2.75550
            
[ Water Solubility ]:
587 g/L (25 ºC)
            
MSDS
Toxicological Information
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
 - TP2275500
 
- CHEMICAL NAME :
 - Platinum (IV) chloride
 
- CAS REGISTRY NUMBER :
 - 13454-96-1
 
- LAST UPDATED :
 - 199712
 
- DATA ITEMS CITED :
 - 33
 
- MOLECULAR FORMULA :
 - Cl4-Pt
 
- MOLECULAR WEIGHT :
 - 336.89
 
- WISWESSER LINE NOTATION :
 - .PT..G4
 
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
 - Standard Draize test
 
- ROUTE OF EXPOSURE :
 - Administration onto the skin
 
- SPECIES OBSERVED :
 - Rodent - rabbit
 
- TYPE OF TEST :
 - LD50 - Lethal dose, 50 percent kill
 
- ROUTE OF EXPOSURE :
 - Oral
 
- SPECIES OBSERVED :
 - Rodent - rat
 
- DOSE/DURATION :
 - 276 mg/kg
 
- TOXIC EFFECTS :
 - Details of toxic effects not reported other than lethal dose value
 
- TYPE OF TEST :
 - TDLo - Lowest published toxic dose
 
- ROUTE OF EXPOSURE :
 - Intratesticular
 
- DOSE :
 - 26951 ug/kg
 
- SEX/DURATION :
 - male 1 day(s) pre-mating
 
- TOXIC EFFECTS :
 - Reproductive - Paternal Effects - spermatogenesis (incl. genetic material, sperm morphology, motility, and count) Reproductive - Paternal Effects - testes, epididymis, sperm duct
 
- TYPE OF TEST :
 - TDLo - Lowest published toxic dose
 
- ROUTE OF EXPOSURE :
 - Subcutaneous
 
- DOSE :
 - 26951 ug/kg
 
- SEX/DURATION :
 - male 1 day(s) pre-mating
 
- TOXIC EFFECTS :
 - Reproductive - Paternal Effects - spermatogenesis (incl. genetic material, sperm morphology, motility, and count) Reproductive - Paternal Effects - testes, epididymis, sperm duct
 
- TYPE OF TEST :
 - Sex chromosome loss and nondisjunction
 
- TYPE OF TEST :
 - DNA inhibition
 
MUTATION DATA
- TYPE OF TEST :
 - Mutation in mammalian somatic cells
 
- TEST SYSTEM :
 - Rodent - hamster Ovary
 
- DOSE/DURATION :
 - 21 umol/L
 
- REFERENCE :
 - MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 151,293,1985 *** REVIEWS *** ACGIH TLV-TWA 0.002 mg(Pt)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 0.002 mg(Pt)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,213,1971 OSHA PEL (Gen Indu):8H TWA 0.002 mg(Pt)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 0.002 mg(Pt)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 0.002 mg(Pt)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 0.002 mg(Pt)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-ARAB Republic of Egypt:TWA 0.002 mg(Pt)/m3 (dust) JAN 1993 OEL-AUSTRALIA:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-BELGIUM:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-DENMARK:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-FINLAND:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-GERMANY:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-HUNGARY:STEL 0.002 mg(Pt)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-SWITZERLAND:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV
 
Safety Information
[ Symbol ]:
                
                
                GHS05, GHS06
            
[ Signal Word ]: 
Danger
            
[ Hazard Statements ]:
 H301-H314-H317
            
[ Precautionary Statements ]:
 P280-P301 + P310-P305 + P351 + P338
            
[ Personal Protective Equipment ]:
 Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges
            
[ Hazard Codes ]:
 C:Corrosive
            
[ Risk Phrases ]:
 R22;R34;R42/43
            
[ Safety Phrases ]:
 S26-S27-S36/37/39-S45-S24-S22
            
[ RIDADR ]: 
UN 2923 8/PG 3
            
[ WGK Germany ]: 
3
            
[ RTECS ]: 
TP2275500
            
[ Packaging Group ]:
 III
            
[ Hazard Class ]:
8
            
[ HS Code ]:
 2843900020
            
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2843900020
Articles
Chem. Commun. (Camb.) 49(3) , 249-51, (2013)
Copper chloropyrophosphate frameworks have been synthesised with a wide variety of complex inorganic anions trapped in a large, flexible, one-dimensional pore, with anions including chloride, bromide,...
Org. Lett. 8(23) , 5349-52, (2006)
[Structure: see text] PtCl4-catalyzed cyclization reactions of homopropargyl azide derivatives to pyrrole rings were investigated. Using ethanol as solvent with 2,6-di-tert-butyl-4-methylpyridine as t...
Gifu Shika Gakkai Zasshi 17(2) , 575-81, (1990)
The induction of mutation by cadmium chloride (CdCl2), platinum tetrachloride (PtCl4), and rhodium trichloride (RhCl3.3H2O) was measured utilizing the hypoxanthine-guanine phosphoribosyl transferase (...