Diphosphoryl tetrachloride

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Names

[ CAS No. ]:
13498-14-1

[ Name ]:
Diphosphoryl tetrachloride

[Synonym ]:
diphosphoryldichloride
Diphosphoryl tetrachloride
Diphosphoryl Chloride
Pyrophosphoryl chloride
diphosphoric acid tetrachloride
MFCD00061542
diphosphoryl choride
Diphosphoric tetrachloride
EINECS 236-824-4
pyrophosphoryl tetrachloride
Pyrophosphoric tetrachloride

Chemical & Physical Properties

[ Density]:
2.0±0.1 g/cm3

[ Boiling Point ]:
90 °C12 mm Hg(lit.)

[ Melting Point ]:
<-50ºC

[ Molecular Formula ]:
Cl4O3P2

[ Molecular Weight ]:
251.758

[ Flash Point ]:
101°C/10mm

[ Exact Mass ]:
249.807678

[ PSA ]:
62.99000

[ LogP ]:
1.13

[ Index of Refraction ]:
1.486

[ Storage condition ]:
−20°C

MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Supplemental HS ]:
Reacts violently with water.

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C:Corrosive;

[ Risk Phrases ]:
R14;R34

[ Safety Phrases ]:
S26-S36/37/39-S45

[ RIDADR ]:
UN 3264 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
8

Synthetic Route

Precursor & DownStream

Precursor

  • Water
  • phosphoryl trichloride
  • Phosphorus pentachloride
  • dichlorophosphoric acid
  • tetraphosphorus
  • oxygen
  • Chlorine
  • Silver oxide
  • dinitrogen trioxide
  • Phosphorus trichloride

DownStream

  • phosphoryl trichloride
  • diaminophosphinic acid
  • phosphoric acid triamide
  • phosphoryl bromide dichloride
  • Phosphoryl bromide
  • Hydrochloric acid
  • ethyl dihydrogen phosphate
  • Phosphoric acid
  • Diphosphate

Articles

Tetrahedron 49 , 4015, (1993)


More Articles


Related Compounds

  • diphosphoryl tetrafluoride
  • molybdenum tetrachloride dimethoxyethane complex
  • osmium tetrachloride
  • Xylylene tetrachloride
  • rhenium tetrachloride oxide
  • TUNGSTEN TETRACHLORIDE
  • 3',4'-dimethyl-alpha-Pyrrolidinovalerophenone
  • 2-(2-Ethylhydrazin-1-yl)pyridine-4-carboxamide
  • Indapyrophenidone
  • 2-(Pyrrolidin-1-yl)-1-(thiophen-2-yl)butan-1-one
  • Fmoc-(2r,3s)-2,3-methanoleucine
  • N-[(2-Hydroxy-1-naphthalenyl)-2-naphthalenylmethyl]acetamide
  • 2,6-Difluoro-4-morpholinobenzoic acid
  • tert-Butyl (3S,4S)-3-amino-4-phenoxypyrrolidine-1-carboxylate
  • (3R,4S)-1-Methyl-4-phenethylpyrrolidin-3-amine
  • (3S,4R)-1-Methyl-4-(5-methylthiophen-2-yl)pyrrolidin-3-amine
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