Diphosphoryl tetrachloride

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Names

[ CAS No. ]:
13498-14-1

[ Name ]:
Diphosphoryl tetrachloride

[Synonym ]:
diphosphoryldichloride
Diphosphoryl tetrachloride
Diphosphoryl Chloride
Pyrophosphoryl chloride
diphosphoric acid tetrachloride
MFCD00061542
diphosphoryl choride
Diphosphoric tetrachloride
EINECS 236-824-4
pyrophosphoryl tetrachloride
Pyrophosphoric tetrachloride

Chemical & Physical Properties

[ Density]:
2.0±0.1 g/cm3

[ Boiling Point ]:
90 °C12 mm Hg(lit.)

[ Melting Point ]:
<-50ºC

[ Molecular Formula ]:
Cl4O3P2

[ Molecular Weight ]:
251.758

[ Flash Point ]:
101°C/10mm

[ Exact Mass ]:
249.807678

[ PSA ]:
62.99000

[ LogP ]:
1.13

[ Index of Refraction ]:
1.486

[ Storage condition ]:
−20°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Supplemental HS ]:
Reacts violently with water.

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C:Corrosive;

[ Risk Phrases ]:
R14;R34

[ Safety Phrases ]:
S26-S36/37/39-S45

[ RIDADR ]:
UN 3264 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
8

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Water
  • phosphoryl trichloride
  • Phosphorus pentachloride
  • dichlorophosphoric acid
  • tetraphosphorus
  • oxygen
  • Chlorine
  • Silver oxide
  • dinitrogen trioxide
  • Phosphorus trichloride

DownStream

  • phosphoryl trichloride
  • diaminophosphinic acid
  • phosphoric acid triamide
  • phosphoryl bromide dichloride
  • Phosphoryl bromide
  • Hydrochloric acid
  • ethyl dihydrogen phosphate
  • Phosphoric acid
  • Diphosphate

Articles

Tetrahedron 49 , 4015, (1993)


More Articles

Related Compounds

  • diphosphoryl tetrafluoride
  • molybdenum tetrachloride dimethoxyethane complex
  • osmium tetrachloride
  • Xylylene tetrachloride
  • rhenium tetrachloride oxide
  • TUNGSTEN TETRACHLORIDE
  • benzyl N-(2-bromo-6-methylphenyl)carbamate
  • Tert-butyl 2-amino-3-(1-methylcyclobutyl)propanoate
  • benzyl 3-(hydroxymethyl)-4H,5H,6H,7H-[1,2]oxazolo[4,5-c]pyridine-5-carboxylate
  • Tert-butyl 4-(but-3-en-1-yl)-4-cyanopiperidine-1-carboxylate
  • 4-fluoro-1-phenyl-3-(pyrrolidin-3-yl)-1H-pyrazole
  • {9-Thia-2-azaspiro[5.5]undecan-3-yl}methanol
  • N-(3-Cyano-2-pyrazinyl)methanesulfonamide
  • 4-[1-(2-Aminoethyl)cyclopropyl]-2-ethoxyphenol
  • 2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-3-(1,2,4-thiadiazol-5-yl)propanoic acid
  • 3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-4-nitronaphthalene-2-carboxylic acid
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