Diphosphoryl tetrachloride

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Names

[ CAS No. ]:
13498-14-1

[ Name ]:
Diphosphoryl tetrachloride

[Synonym ]:
diphosphoryldichloride
Diphosphoryl tetrachloride
Diphosphoryl Chloride
Pyrophosphoryl chloride
diphosphoric acid tetrachloride
MFCD00061542
diphosphoryl choride
Diphosphoric tetrachloride
EINECS 236-824-4
pyrophosphoryl tetrachloride
Pyrophosphoric tetrachloride

Chemical & Physical Properties

[ Density]:
2.0±0.1 g/cm3

[ Boiling Point ]:
90 °C12 mm Hg(lit.)

[ Melting Point ]:
<-50ºC

[ Molecular Formula ]:
Cl4O3P2

[ Molecular Weight ]:
251.758

[ Flash Point ]:
101°C/10mm

[ Exact Mass ]:
249.807678

[ PSA ]:
62.99000

[ LogP ]:
1.13

[ Index of Refraction ]:
1.486

[ Storage condition ]:
−20°C

MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Supplemental HS ]:
Reacts violently with water.

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C:Corrosive;

[ Risk Phrases ]:
R14;R34

[ Safety Phrases ]:
S26-S36/37/39-S45

[ RIDADR ]:
UN 3264 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
8

Synthetic Route

Precursor & DownStream

Precursor

  • Water
  • phosphoryl trichloride
  • Phosphorus pentachloride
  • dichlorophosphoric acid
  • tetraphosphorus
  • oxygen
  • Chlorine
  • Silver oxide
  • dinitrogen trioxide
  • Phosphorus trichloride

DownStream

  • phosphoryl trichloride
  • diaminophosphinic acid
  • phosphoric acid triamide
  • phosphoryl bromide dichloride
  • Phosphoryl bromide
  • Hydrochloric acid
  • ethyl dihydrogen phosphate
  • Phosphoric acid
  • Diphosphate

Articles

Tetrahedron 49 , 4015, (1993)


More Articles


Related Compounds

  • diphosphoryl tetrafluoride
  • molybdenum tetrachloride dimethoxyethane complex
  • osmium tetrachloride
  • Xylylene tetrachloride
  • rhenium tetrachloride oxide
  • TUNGSTEN TETRACHLORIDE
  • 2-(4-(N-((3-(furan-3-yl)pyrazin-2-yl)methyl)sulfamoyl)phenoxy)acetamide
  • 5-methyl-N-((3-(thiophen-2-yl)pyrazin-2-yl)methyl)isoxazole-3-carboxamide
  • N-((3-(thiophen-2-yl)pyrazin-2-yl)methyl)thiophene-3-carboxamide
  • 2-(thiophen-2-yl)-N-((3-(thiophen-2-yl)pyrazin-2-yl)methyl)acetamide
  • 1-methyl-2-oxo-N-((3-(thiophen-2-yl)pyrazin-2-yl)methyl)-1,2-dihydropyridine-3-carboxamide
  • 3-(dimethylamino)-N-((3-(thiophen-2-yl)pyrazin-2-yl)methyl)benzamide
  • 2-ethoxy-N-((3-(thiophen-2-yl)pyrazin-2-yl)methyl)benzamide
  • 4-propyl-N-((3-(thiophen-2-yl)pyrazin-2-yl)methyl)-1,2,3-thiadiazole-5-carboxamide
  • 1-(4-Bromothiophen-2-yl)-4-methyl-2,6,7-trioxabicyclo[2.2.2]octane
  • 1-(5-Bromothiophen-2-yl)-4-methyl-2,6,7-trioxabicyclo[2.2.2]octane
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