sec-Butylbenzene

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Names

[ CAS No. ]:
135-98-8

[ Name ]:
sec-Butylbenzene

[Synonym ]:
Benzene, sec-butyl-
s-butylbenzene
MFCD00009329
EINECS 205-227-0
Butan-2-ylbenzol
UNII:B70I0RSX3J
Benzene, (1-methylpropyl)-
benzene, s-butyl-
butan-2-ylbenzene
sec-Butylbenzene
2-Phenylbutane
Benzene, methylpropyl-

Chemical & Physical Properties

[ Density]:
0.9±0.1 g/cm3

[ Boiling Point ]:
173.3±0.0 °C at 760 mmHg

[ Melting Point ]:
-75 °C

[ Molecular Formula ]:
C10H14

[ Molecular Weight ]:
134.218

[ Flash Point ]:
45.6±0.0 °C

[ Exact Mass ]:
134.109543

[ LogP ]:
4.09

[ Vapour Pressure ]:
1.7±0.1 mmHg at 25°C

[ Index of Refraction ]:
1.490

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
CY9100000
CHEMICAL NAME :
Benzene, sec-butyl-
CAS REGISTRY NUMBER :
135-98-8
BEILSTEIN REFERENCE NO. :
1903902
LAST UPDATED :
199710
DATA ITEMS CITED :
8
MOLECULAR FORMULA :
C10-H14
MOLECULAR WEIGHT :
134.24
WISWESSER LINE NOTATION :
2Y1&R

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,36,1986
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,36,1986 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
2240 uL/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 28,313,1974
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
>16 mL/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 28,313,1974 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X4539 No. of Facilities: 19 (estimated) No. of Industries: 2 No. of Occupations: 2 No. of Employees: 52 (estimated)

Safety Information

[ Symbol ]:

GHS02, GHS07, GHS09

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226-H315-H411

[ Precautionary Statements ]:
P273-P391-P403 + P235-P501

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
T: Toxic;F: Flammable;

[ Risk Phrases ]:
R10

[ Safety Phrases ]:
S23-S24/25-S45-S36/37-S16-S7

[ RIDADR ]:
UN 2709 3/PG 3

[ WGK Germany ]:
3

[ RTECS ]:
CY9100000

[ Packaging Group ]:
III

[ Hazard Class ]:
3

Synthetic Route

Precursor & DownStream

Precursor

  • 2-Bromobutane
  • benzene
  • but-1-en-2-ylbenzene
  • 1-Butene
  • 2-Iodobutane
  • phenylmagnesium bromide
  • trans-2-Phenyl-2-butene
  • 2-Chlorobutane
  • Iodobenzene
  • ISOPROPYLMAGNESIUM CHLORIDE

DownStream

  • 1,3,5-Tris(1-methylpropyl)benzene
  • 1,3-Di-sec-butylbenzene
  • benzene
  • 1-sec-Butyl-4-nitrobenzene
  • Phenyl ethyl ketone
  • Methylbenzylalcohol
  • Benzenemethanol, a-ethyl-a-methyl-
  • 1-SEC-BUTYL-2-NITROBENZENE
  • (1-Phenylcyclohexyl) hydroperoxide

Articles

Metabolites of three structural isomers of butylbenzene in the bile of rainbow trout.

Bull. Environ. Contam. Toxicol. 44(3) , 487-93, (1990)

Biodegradation of alkyl derivatives of aromatic hydrocarbons and cell surface properties of a strain of Pseudomonas stutzeri.

Chemosphere 90(2) , 471-8, (2013)

Pseudomonas stutzeri strain 9 was isolated from petroleum-contaminated soil. The main purpose of this study was to investigate how the long-term contact of this strain with diesel oil influences its s...


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Related Compounds

  • sec-butylbenzene
  • sec-Butylbenzene
  • di-sec-butylbenzene
  • SEC-BUTYLBENZENE-D14
  • (S)-sec-butylbenzene
  • 1,3-Di-sec-butylbenzene