tungsten(vi) oxychloride

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Names

[ CAS No. ]:
13520-78-0

[ Name ]:
tungsten(vi) oxychloride

[Synonym ]:
tungsten (VI) oxychloride
Tungsten oxytetrachloride
EINECS 236-863-7
tungsten(vi) chloride oxide
trans-tungsten(VI) oxotetrachloride
Tungsten chloride oxide(WCl4O)
MFCD00011465
tungsten tetrachloride oxide
tetrachloride(oxo)tungsten(VI)
TUNGSTEN OXIDE CHLORIDE
tungsten(VI) oxytetrachloride
Tungsten(VI) chloride oxide,Tungsten(VI) oxide chloride
Wolfram(VI) tetrachlorideoxide
TUNGSTEN OXYCHLORIDE

Chemical & Physical Properties

[ Density]:
11.920

[ Boiling Point ]:
337ºC

[ Melting Point ]:
211ºC(lit.)

[ Molecular Formula ]:
Cl4OW

[ Molecular Weight ]:
341.65100

[ Exact Mass ]:
339.82100

[ PSA ]:
17.07000

[ LogP ]:
2.63920

[ Appearance of Characters ]:
red hygroscopic crystals

[ Water Solubility ]:
decomposed by H2O; soluble CS2, benzene [KIR83] [HAW93]

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314-H335

[ Precautionary Statements ]:
P280-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
26-37/39

[ RIDADR ]:
UN 3262

[ WGK Germany ]:
3

[ Packaging Group ]:
III

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Trimethyl Methoxysilane
  • hexachlorotungsten
  • Thionyl chloride
  • Sodium tungstate dihydrate
  • chloropicrin
  • Hexaphenylcyclotrisiloxane
  • SULFUR DIOXIDE

DownStream

  • methanol,oxotungsten
  • ethanol,oxotungsten
  • Tungsten dichloride dioxide
  • dichloromethylidene(oxo)tungsten
  • Chlorotrimethylsilane
  • oxotungsten(IV) chloride
  • Chlorine

Related Compounds

  • Tungsten(VI) oxychloride (Wolfram(VI) dichloride dioxide
  • tungsten(VI) sulfide tetrachloride
  • tungsten(VI)(4-methylphenoxide)4-dichloride
  • Tungsten(VI) oxide
  • tungsten(VI) pentafluoride pentafluorotellurate(VI)
  • TUNGSTEN (VI) ETHOXIDE
  • 1-(2,2-Dimethylcyclobutyl)ethan-1-amine hydrochloride
  • Tert-butyl 3-(1-amino-3-methylcyclohexyl)-3-hydroxyazetidine-1-carboxylate
  • {1-[3-(difluoromethyl)-1-methyl-1H-pyrazol-4-yl]cyclobutyl}methanol
  • 3-[(4-Fluoropyridin-2-yl)methyl]pyrrolidin-3-ol
  • Tert-butyl 3-(1-amino-3-methylcyclohexyl)-3-hydroxypyrrolidine-1-carboxylate
  • methyl (2R)-2-{[(tert-butoxy)carbonyl]amino}-3-(3-methyl-3H-diazirin-3-yl)propanoate
  • 1-(1-Amino-3-methylcyclohexyl)-4,4-dimethylcyclohexan-1-ol
  • 4-[(2,3-dihydro-1H-inden-4-yl)methyl]piperidin-4-ol
  • methyl (2R)-2-amino-3-(3-methyl-3H-diazirin-3-yl)propanoate
  • 2-Chloro-6-methyl-3-(prop-2-yn-1-yl)pyridine
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