(S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine
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Names
[ CAS No. ]:
135616-36-3
[ Name ]:
(S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine
[Synonym ]:
(S,S)-2,2'-[(1,2-cyclohexanediyl)bis(nitrilomethylidyne)]bis[4,6-di-tert-butylphenol]
(S,S)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE
(1S,2S)-N,N'-bis[(3,5-di-tert-butyl-2-hydroxyphenyl)methylene]-1,2-cyclohexanediamine
(S,S)-N,N'-bis(3,5-di-t-butylsalicylidene)-1,2-cyclohexanediamine
(1S,2S)-(+)-1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)
(1S,2S)-(+)-1,2-Cyclohexanediamino-N,N'-bis(3,5-di-tert-butylsalicylidene)
(S,S)-JACOBSEN LIGAND
(1S,2S)-N,N'-bis(3',5'-di-tert-butylsalicylidene)-cyclohexane-1,2-diimine
(S,S)-JACOBSEN'S LIGAND
Phenol, 2,2'-[(1S,2S)-1,2-cyclohexanediylbis[nitrilo(E)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)-
MFCD00191801
(S,S)-(+)-N,N'-BIS(3,5-DI-T-BU-SALICYL.)
(S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine
N,N'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine
(1S,2S)-N,N′-bis-[3,5-di-tert-butylsalicylidene]-1,2-cyclohexanediamine
2,2'-{(1S,2S)-Cyclohexane-1,2-diylbis[nitrilo(E)methylylidene]}bis(4,6-di-tert-butylphenol)
2,2'-{(1S,2S)-1,2-Cyclohexanediylbis[nitrilo(E)methylylidene]}bis[4,6-bis(2-methyl-2-propanyl)phenol]
(S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine
Chemical & Physical Properties
[ Density]:
1.0±0.1 g/cm3
[ Boiling Point ]:
615.2±55.0 °C at 760 mmHg
[ Melting Point ]:
203-206ºC(lit.)
[ Molecular Formula ]:
C36H54N2O2
[ Molecular Weight ]:
546.826
[ Flash Point ]:
421.6±20.8 °C
[ Exact Mass ]:
546.418518
[ PSA ]:
65.18000
[ LogP ]:
11.18
[ Vapour Pressure ]:
0.0±1.8 mmHg at 25°C
[ Index of Refraction ]:
1.536
MSDS
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H315-H319-H335
[ Precautionary Statements ]:
P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves
[ Hazard Codes ]:
Xi: Irritant;
[ Risk Phrases ]:
R36/37/38
[ Safety Phrases ]:
S26-S36
[ RIDADR ]:
NONH for all modes of transport
[ WGK Germany ]:
3
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Articles
J. Am. Chem. Soc. 113 , 7063, (1991)
L. Deng, E.N. Jacobsen
J. Org. Chem. 57 , 4320, (1992)
Chang, S. et al.
J. Am. Chem. Soc. 58 , 6939, (1993)