(S,S)-(+)N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride
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Names
[ CAS No. ]:
135620-04-1
[ Name ]:
(S,S)-(+)N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride
[Synonym ]:
Jacobsen catalyst
JACOBSEN'S CATALYST
2,2'-{(1S,2S)-1,2-Cyclohexanediylbis[nitrilo(E)methylylidene]}bis[4,6-bis(2-methyl-2-propanyl)phenol] - trichloromanganese (1:1)
MFCD02101663
(S,S)-(+)N,N‘-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride
(S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride
Chemical & Physical Properties
[ Melting Point ]:
330-332ºC(lit.)
[ Molecular Formula ]:
C36H54Cl3MnN2O2
[ Molecular Weight ]:
708.123
[ Exact Mass ]:
706.263123
[ PSA ]:
65.18000
[ LogP ]:
0.14900
MSDS
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H315-H319-H335
[ Precautionary Statements ]:
P261-P305 + P351 + P338
[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves
[ Hazard Codes ]:
Xi: Irritant;
[ Risk Phrases ]:
R20/21/22;R36/37/38
[ Safety Phrases ]:
26-36-36/37/39
[ RIDADR ]:
NONH for all modes of transport
[ WGK Germany ]:
3
[ HS Code ]:
29310099
Articles
J. Am. Chem. Soc. 113 , 7063, (1991)
L. Deng, E.N. Jacobsen
J. Org. Chem. 57 , 4320, (1992)
W. Zhang et al.
J. Am. Chem. Soc. 112 , 2801, (1990)