(S,S)-(+)N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride

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Names

[ CAS No. ]:
135620-04-1

[ Name ]:
(S,S)-(+)N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride

[Synonym ]:
Jacobsen catalyst
JACOBSEN'S CATALYST
2,2'-{(1S,2S)-1,2-Cyclohexanediylbis[nitrilo(E)methylylidene]}bis[4,6-bis(2-methyl-2-propanyl)phenol] - trichloromanganese (1:1)
MFCD02101663
(S,S)-(+)N,N‘-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride
(S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride

Chemical & Physical Properties

[ Melting Point ]:
330-332ºC(lit.)

[ Molecular Formula ]:
C36H54Cl3MnN2O2

[ Molecular Weight ]:
708.123

[ Exact Mass ]:
706.263123

[ PSA ]:
65.18000

[ LogP ]:
0.14900

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R20/21/22;R36/37/38

[ Safety Phrases ]:
26-36-36/37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
29310099

Articles

E.N. Jacobsen et al.

J. Am. Chem. Soc. 113 , 7063, (1991)

L. Deng, E.N. Jacobsen

J. Org. Chem. 57 , 4320, (1992)

W. Zhang et al.

J. Am. Chem. Soc. 112 , 2801, (1990)


More Articles

Related Compounds

  • 6-[(Mesityloxy)methyl]-3-(4-pyridyl)[1,2,4]triazolo[3,4-b][1,3,4]thiadiazole
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  • Acetamide, 2-[[5-(2-furanyl)-4-(2-propen-1-yl)-4H-1,2,4-triazol-3-yl]thio]-N-[4-(2-phenyldiazenyl)phenyl]-
  • 2-(2-Chloropyridin-4-yl)-4-(4-fluorophenyl)thiazole
  • N-butyl-6-chloro-N-(6-methyl-1,3-benzothiazol-2-yl)pyridine-3-carboxamide
  • n-Isobutyl-3-(1,3,5-trimethyl-1h-pyrazol-4-yl)acrylamide
  • 4-[(6,7-Dimethoxy-1,2,3,4-tetrahydroisoquinolin-2-yl)methyl]-3-fluorobenzonitrile
  • Rel-tert-butyl (3aR,6aS)-hexahydropyrrolo[3,4-b]pyrrole-5(1H)-carboxylate
  • 2-Bromo-5-iodo-thieno[3,2-b]thiophene
  • 3,4,5,6-tetrachloro-N-(2-pyrazol-1-ylpyridin-3-yl)pyridine-2-carboxamide
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