1-nitro-2,2-bis(methylthio)ethylene

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Names

[ Name ]:
1-nitro-2,2-bis(methylthio)ethylene

[Synonym ]:
1,1-Bis(methylsulfanyl)-2-nitroethene
Nitroketene dimethyl mercaptal
1-nitro-2,2-bis(methylthio)ethylene
1,1-BIS(METHYLTHIO)-2-NITROETHYLENE
EINECS 237-108-4
Ethene, 1,1-bis(methylthio)-2-nitro-
MFCD00010443

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
248.6±35.0 °C at 760 mmHg

[ Melting Point ]:
125-127 °C(lit.)

[ Molecular Formula ]:
C₄H₇NO₂S₂

[ Molecular Weight ]:
165.23

[ Flash Point ]:
104.1±25.9 °C

[ Exact Mass ]:
164.991821

[ PSA ]:
96.42000

[ LogP ]:
0.99

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.575

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S37/39

[ RIDADR ]:
3335.0

[ WGK Germany ]:
3

[ Hazard Class ]:
9.0

[ HS Code ]:
2930909090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

1,1-Ethenedithiol,2-nitro-, potassium salt (1:2)
Dimethyl sulfate
methyl iodide
Carbon disulphide
nitromethane

DownStream

2-chloro-5-[[(2Z)-2-(nitromethylidene)imidazolidin-1-yl]methyl]-1,3-thiazole
2-(nitromethyl)-1,3-benzoxazole
Ratic
2-Amino-3-nitro-6-phenylpyridine
2-chloro-5-[[(2Z)-2-(nitromethylidene)imidazolidin-1-yl]methyl]pyridine
5,6-Dihydro-3-(methylamino)-2H-1,4-thiazin-2-one Oxime Hydrochloride
N-(1-methylsulfanyl-2-nitroethenyl)aniline
N-(1-methylsulfanyl-2-nitroethenyl)pyridin-3-amine
2-nitroethene-1,1-diamine
5-Pyrimidinol, hexahydro-2-(nitromethylene)- (9CI)

Customs

[ HS Code ]: 2930909090

[ Summary ]:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

Uncatalyzed one-pot synthesis of highly substituted pyridazines and pyrazoline-spirooxindoles via domino SN/condensation/aza-ene addition cyclization reaction sequence.

ACS Comb. Sci. 15(6) , 278-86, (2013)

A previously unknown class of highly substituted pyridazines and pyrazoline-spirooxinoles are easily prepared by an uncatalyzed one-pot three-component approach incorporating a domino SN/condensation/...

Efficient one-pot synthesis of spirooxindole derivatives containing 1, 4-dihydropyridine-fused-1, 3-diazaheterocycle fragments via four-component reaction. Alizadeh A, et al.

Synthesis 2010(22) , 3913-17, (2010)

Synthesis of the novel pyrimido[1,6-a]pyrimidine and imidazo[1,2-c]pyrimidine derivatives based on heterocyclic ketene aminals. Alizadeh A, et al.

Tetrahedron 68(1) , 319-22, (2012)

1-methylsulfanyl-1-methylsulfinyl-2-nitroethene
2-nitro-N,N'-bis-(2-thiazol-2-ylmethylsulfanyl-ethyl)-ethene-1,1-diamine
2-nitro-1-N,1-N'-bis[2-(1,3-thiazol-2-ylmethylsulfinyl)ethyl]ethene-1,1-diamine
1-cyano-2,2-bis(methylthio)vinyl acetate
1-nitro-2-[(2-nitrophenoxy)-propan-2-ylphosphoryl]oxybenzene
1-(1-cyano-2,2-bis(methylthio)vinyl)pyridin-1-ium iodide
4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
(4-Methyl-tetrahydro-furan-2-yl)-methanol
N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
tert-Butyl-DL-alanine
4-amino-N-[2-tert-butyl-1-(tetrahydro-2H-pyran-4-ylmethyl)-1H-benzimidazol-5-yl]-N-ethylbenzenesulfonamide
N-[3-(Aminooxy)propyl]-N-butyl-1-butanamine